Track and Trace Future,Present, and Past Product and Money Flows with a Resource-Event-Agent Model

In this article the authors present a reference model for the registration of economic data that enables the tracking and tracing of product and money flows in the registered data. The model is grounded in the Resource-Event-Agent (REA) ontology, which has its origin in accounting and provides the conceptual foundation for the International Organization for Standardization (ISO) open-edi transaction standard. The use of the reference model is illustrated with an example database that demonstrates the different usage scenarios covered by the model.     

Pesticides in the atmosphere across Canadian agricultural regions

The Canadian Atmospheric Network for Currently Used Pesticides (CANCUP) was the first comprehensive, nationwide air surveillance study of pesticides in Canada. This paper presentsthe atmospheric occurrence and distribution of pesticides including organochlorine pesticides (OCPs), organophosphate pesticides (OPPs), acid herbicides (AHs), and neutral herbicides (NHs) during the spring to summer of 2004 and 2005 across agricultural regions in Canada. Atmospheric concentrations of pesticides varied within years and time periods, and regional characteristics were observed including the following: (i) highest air concentrations of several herbicides (e.g., mecoprop, triallate, and ethalfluralin) were found at Bratt's Lake, SK, a site in the Canadian Prairies; (ii) the west-coast site at Abbotsford, BC, had the maximum concentrations of diazinon; (iii) the fruit and vegetable growing region in Vineland, ON, showed highest levels for several insecticides including chlorpyrifos, endosulfan, and azinphos-methyl; (iv) high concentrations of atrazine and metolachlor were measured at St. Anicet, QC, a corn-growing region; (v) the Kensington site in PEI, Canada's largest potato-producing province, exhibited highest level of dimethoate. Analysis of particle- and gas-phase fractions of air samples revealed that most pesticides including OCPs, OPPs, and NHs exist mainly in the gas phase, while AHs exhibit more diversity in particle-gas partitioning behavior. This study also demonstrated that stirred up soil dust does not account for pesticides that are detected in the particle phase. The estimated dry and wet deposition fluxes indicate considerable atmospheric inputs for some current-use pesticides (CUPs). This data set represents the first measurements for many pesticides in the atmosphere, precipitation, and soil for given agricultural regions across Canada.     

Two classes of anionic surfactants and their significance in hot water processing of oil sands

In hot water flotation of bitumen from Athabasca oil sands, two types of primary oil recovery response to sodium hydroxide addition are identified. Natural carboxylate surfactants can promote bitumen separation and flotation under certain process conditions, while a second, more polar, class of natural anionic surfactants can promote separation and flotation under different process conditions. As a result, some oil sands exhibit two recovery peaks as a function of sodium hydroxide addition. The phenomena are explained in terms of different sodium hydroxide additions required to reach critical surfactant concentrations specific to each surfactant class. The concept provides a means for interpreting a wide range of processibility phenomena.     

Continuous analysis of dissolved gaseous mercury and mercury volatilization in the upper St. Lawrence River: exploring temporal relationships and UV attenuation

The formation and volatilization of dissolved gaseous mercury (DGM) is an important mechanism by which freshwaters may naturally reduce their mercury burden. Continuous analysis of surface water for diurnal trends in DGM concentration (ranging from 0 to 60.4 pg L(-1); n=613), mercury volatilization (ranging from 0.2 to 1.1 ng m(-2) h(-1); n=584), and a suite of physical and chemical measurements were performed during a 68 h period in the St. Lawrence River near Cornwall (Ontario, Canada) to examine the temporal relationships governing mercury volatilization. No lag-time was observed between net radiation and OGM concentrations (highest cross-correlation of 0.817), thus supporting previous research indicating faster photoreduction kinetics in rivers as compared to lakes. A significant lag-time (55-145 min; maximum correlation = 0.625) was observed between DGM formation and mercury volatilization, which is similar to surface water Eddy diffusion times of 42-132 min previously measured in the St. Lawrence River. A depth-integrated DGM model was developed using the diffuse integrated vertical attenuation coefficients for UVA and UVB (K(dI UVA) = 1.45 m(-1) K(dI UVB)= 3.20 m(-1)) Low attenuation of solar radiation was attributed to low concentrations of dissolved organic carbon (mean = 2.58 mg L(-1) and particulate organic carbon (mean = 0.58 mg L(-1) in the St. Lawrence River. The depth-integrated DGM model developed found that the top 0.3 m of the water column accounted for only 26% of the total depth-integrated DGM. A comparison with volatilization data indicated that a large portion (76% or 10.5 ng m(-2) of the maximum depth-integrated DGM (13.8 ng m(-2))is volatilized over a 24 h period. Therefore, at least 50% of all DGM volatilized was produced at depths below 0.3 m. These results highlight the importance of solar attenuation in regulating DGM formation with depth. The results also demonstrate both the fast formation of DGM in rivers and the importance of understanding DGM dynamics with depth as opposed to surface waters.     

Spatial insolation models for photovoltaic energy in Canada

Spatial models of global insolation and photovoltaic electricity generation potential for Canada were developed. The main objective was to provide Canadians with an easily accessible, reliable tool for rapidly estimating the monthly and yearly electricity production potential of grid-connected photovoltaic systems anywhere in the country, and for assessing the dependence of production on location, time of year and array orientation. Monthly mean daily insolation data from 144 meteorological stations across Canada were used, along with data from an additional eight stations in Alaska to improve the models in that region. Several photovoltaic array orientations were considered, including South-facing arrays with latitude and vertical tilts and a sun-tracking orientation. Partial thin plate smoothing splines as implemented in ANUSPLIN were used to generate the spatial insolation models. The models were based on geographic position and a transform of monthly mean precipitation, the latter variable being a surrogate for cloudiness which affects surface insolation. Photovoltaic electricity generation (in kW h per kilowatt of photovoltaic installed power capacity) was estimated for each month and for the entire year from the insolation models by assuming international standard values for the performance ratio of photovoltaic systems. The yearly average root mean square predictive error (RTGCV) on the mean daily global insolation ranges between 0.75 (vertical tilt) and 1.43 MJ/m² (sun-tracking orientation) (or about 4.7–9.0 kW h/kW in terms of PV potential), or from 5.6% to 6.9% of the mean. Ultimately insolation and photovoltaic potential were mapped over the country at a 300 arc seconds (～10 km) resolution. The maps are available on a Natural Resources Canada Website. This is an important new tool to help Canadians gain an overall perspective of Canada’s photovoltaic potential, and allow estimation of potential photovoltaic system electricity production at any chosen location.     

Variation in peak growing season net ecosystem production across the canadian arctic

Tundra ecosystems store vast amounts of soil organic carbon, which may be sensitive to climatic change. Net ecosystem production, NEP, is the net exchange of carbon dioxide (CO(2)) between landscapes and the atmosphere, and represents the balance between CO(2) uptake by photosynthesis and release by decomposition and autotrophic respiration. Here we examine CO(2) exchange across seven sites in the Canadian low and high Arctic during the peak growing season (July) in summer 2008. All sites were net sinks for atmospheric CO(2) (NEP ranged from 5 to 67 g C m(-2)), with low Arctic sites being substantially larger CO(2) sinks. The spatial difference in NEP between low and high Arctic sites was determined more by CO(2) uptake via gross ecosystem production than by CO(2) release via ecosystem respiration. Maximum gross ecosystem production at the low Arctic sites (average 8.6 μmol m(-2) s(-1)) was about 4 times larger than for high Arctic sites (average 2.4 μmol m(-2) s(-1)). NEP decreased with increasing temperature at all low Arctic sites, driven largely by the ecosystem respiration response. No consistent temperature response was found for the high Arctic sites. The results of this study clearly indicate there are large differences in tundra CO(2) exchange between high and low Arctic environments and this difference should be a central consideration in studies of Arctic carbon balance and climate change.     

Tropospheric H2 budget and the response of its soil uptake under the changing environment

Molecular hydrogen (H₂) is an indirect greenhouse gas present at the trace level in the atmosphere. So far, the sum of its sources and sinks is close to equilibrium, but its large-scale utilization as an alternative energy carrier would alter its atmospheric burden. The magnitude of the emissions associated with a future H₂-based economy is difficult to predict and remains a matter of debate. Previous attempts to predict the impact that a future H₂-based economy would exert on tropospheric chemistry were realized by considering a steady rate of microbial-mediated soil uptake, which is currently responsible of ~ 80% of the tropospheric H₂ losses. Although soil uptake, also known as dry deposition is the most important sink for tropospheric H₂, microorganisms involved in the activity remain elusive. Given that microbial-mediated H₂ soil uptake is influenced by several environmental factors, global change should exert a significant effect on the activity and then, assuming a steady H₂ soil uptake rate for the future may be mistaken. Here, we present an overview of tropospheric H₂ sources and sinks with an emphasis on microbial-mediated soil uptake process. Future researches are proposed to investigate the influence that global change would exert on H₂ dry deposition and to identify microorganisms involved H₂ soil uptake activity.     

Total gaseous mercury in Quebec (Canada) in 1998

The main objectives of this paper were to report total gaseous mercury (TGM) concentrations at four stations along the St. Lawrence River in 1998 and to give some insights regarding their fate. The TGM network stretches from latitudes 45 degrees N to 50 degrees N. TGM and ozone concentrations (used as complementary pollutant) were presented. The median TGM concentrations throughout the network varied from 1.62 to 1.79 ng/m3. Sites close to Montreal had larger TGM concentrations. Montreal surroundings appeared to be a source of TGM. The TGM concentrations were maximum in wintertime and minimum in summertime throughout the sites. However, the diurnal variations were site specific. St. Anicet and L'Assomption were more variable in terms of large concentrations, whereas Mingan and Villeroy were more variable in terms of low concentrations. Ozone and TGM concentrations were positively correlated at some sites (Villeroy, Mingan and St. Anicet) whereas they were not at L'Assomption (closest site to Montreal). Local TGM and ozone precursor sources would affect the correlation.