Effects of physical refining on contents of waxes and fatty alcohols of refined olive oil

Changes in the contents of waxes and fatty alcohols during deodorization/physical refining of bleached olive oil were studied. Experiments were carried out with 1.85% acidity oil, which was physically refined in a discontinuous deodorizer of 250-kg maximum capacity using nitrogen as stripping gas instead of steam. The variables studied were load and temperature of oil in the deodorizer as well as N₂ flow. Analyses of waxes and alcohols were carried out at different operation times. The maximum content of wax was always observed when the oil reached the deodorization temperature. The variation in the wax content depended on temperature and N₂ flow. Wax decomposition started and continued during the operating time, and a progressive decrease, which was pronounced between 3 and 4 h, was observed. Small changes in waxes were observed between 4 and 5 h. Total content of fatty alcohols diminished throughout the operating time, and changes did not depend on the variables studied.     

The effect of reaction conditions on montmorillonite-catalysed peptide formation

Oligomerization of glycine (gly) and diglycine (gly₂) on montmorillonite was performed as cyclic, drying-wetting process at temperatures below 100°C, under varying reaction conditions. The influence of substrate/clay ratio, temperature and pH was found to be different for amino acid (AA) dimerization, cyclic anhydride (CA) formation and peptide chain elongation. High temperatures and neutral pH favour CA formation over diglycine production. An AA/catalyst ratio of 0.2 mmol/g leads to optimal yields. This supports the assumption that amino acid dimerization and CA formation take place at the edges of clay particles. Peptide chain elongation, starting from gly₂, produces higher yields at higher temperatures and neutral pH.     

Experimental and theoretical analysis of the operation of a natural gas cogeneration system using a polymer exchange membrane fuel cell

This paper reports experimental and numerical results of an investigation of five identical cogeneration systems using PEM (Polymer Exchange Membrane) fuel cells and running on natural gas. The natural gas is reformed locally to produce hydrogen. The accuracy of numerical results is validated by comparison with experimental data and the system performances are analysed in terms of electrical, thermal and total efficiencies. It appears that the energetic performances are low, particularly at low current. Simple solutions for enhancing the system electrical performances by modifying control laws are proposed.     

Personalized identification of abdominal wall hernia meshes on computed tomography

An abdominal wall hernia is a protrusion of the intestine through an opening or area of weakness in the abdominal wall. Correct pre-operative identification of abdominal wall hernia meshes could help surgeons adjust the surgical plan to meet the expected difficulty and morbidity of operating through or removing the previous mesh. First, we present herein for the first time the application of image analysis for automated identification of hernia meshes. Second, we discuss the novel development of a new entropy-based image texture feature using geostatistics and indicator kriging. Third, we seek to enhance the hernia mesh identification by combining the new texture feature with the gray-level co-occurrence matrix feature of the image. The two features can characterize complementary information of anatomic details of the abdominal hernia wall and its mesh on computed tomography. Experimental results have demonstrated the effectiveness of the proposed study. The new computational tool has potential for personalized mesh identification which can assist surgeons in the diagnosis and repair of complex abdominal wall hernias.     

An effective approach for maintenance of pre-large-based frequent-itemset lattice in incremental mining

Incremental mining has attracted the attention of many researchers due to its usefulness in online applications. Many algorithms have thus been proposed for incrementally mining frequent itemsets. Maintaining a frequent-itemset lattice (FIL) is difficult for databases with large numbers of frequent itemsets, especially huge databases, due to the storage of links of nodes in the lattice. However, generating association rules from a FIL has been shown to be more effective than traditional methods such as directly generating rules from frequent itemsets or frequent closed itemsets. Therefore, when the number of frequent itemsets is not huge (i.e., they can be stored in the lattice without excessive memory overhead), the lattice-based approach outperforms approaches which mine association rules from frequent itemsets/frequent closed itemsets. However, incremental algorithms for building FILs have not yet been proposed. This paper proposes an effective approach for the maintenance of a FIL based on the pre-large concept in incremental mining. The building process of a FIL is first improved using two proposed theorems regarding the paternity relation between two nodes in the lattice. An effective approach for maintaining a FIL with dynamically inserted data is then proposed based on the pre-large and the diffset concepts. The experimental results show that the proposed approach outperforms the batch approach for building a FIL in terms of execution time.     

新版Auto CAD计算机辅助设计在我公司氯碱设计中的应用

随着计算机技术及外围设备的提高和完善 ,计算机辅助设计和计算机辅助工程技术得到了日益广泛应用 ,绘图技术也得到了很大的发展 ,并已成为工程制图发展的必然趋势。我公司应用美国ＡＵＴＯＤＥＳＫ公司推出的新版ＡｕｔｏＣＡＤ2 0 0 2中文版本 ,是当前国际上最为先进和流行的绘图软件之一 ,具有以下增强功能。1　新增设计中心图库 ,在绘图过程中 ,可边绘图 ,边自动将所绘单元图储存在设计中心库中 ,这样可重复和快速使用相同或相近单元图 ,或在绘制新图时 ,可从中心库中随时提取相同或相近单元图形来绘制新图。其次 ,在绘图过程中 ,也可把…     

Studies of the electrodeposition of palladium from baths based on [Pd(NH3)2X2] salts. I. [Pd(NH3)2Cl2] baths

Spectroscopic techniques are used to confirm the chemistry of solutions of [Pd(NH₃)₂Cl₂] in aqueous NH₄Cl at various pH. In addition, potential sweep and step methods at rotating and stationary disc electrodes (both vitreous carbon and freshly plated palladium) are used to investigate palladium deposition from a standard electroplating bath, [Pd(NH₃)₂Cl₂] in NH₄Cl/NH₃ (pH 8.9). The relative importance of oxygen reduction, hydrogen absorption and hydrogen evolution as competing cathode reactions under various conditions is defined and the advantage of strong convection for high rate plating is demonstrated.     

Statistical prediction of fracture parameters of concrete and implications for choice of testing standard

This article shows how the fracture energy of concrete, as well as other fracture parameters such as the effective length of the fracture process zone, critical crack-tip opening displacement and the fracture toughness, can be approximately predicted from the standard compression strength, maximum aggregate size, water-cement ratio, and aggregate type (river or crushed). A database, consisting of 238 test data, is extracted from the literature and tabulated, and approximate mean prediction formulae calibrated by this very large data set are developed. A distinction is made between (a) the fracture energy, G_f, corresponding to the area under the initial tangent of the softening stress-separation curve of cohesive crack model, which governs the maximum loads of structures and is obtained by the size effect method (SEM) or related methods (Jenq-Shah two-parameter method and Karihaloo's effective crack model, ECM) and (b) the fracture energy, G_F, corresponding to the area under the complete stress-separation curve, which governs large postpeak deflections of structures and is obtained by the work-of-fracture method (WFM) proposed for concrete by Hillerborg. The coefficients of variation of the errors in the prediction formulae compared to the test data are calculated; they are 17.8% for G_f and 29.9% for G_F, the latter being 1.67 times higher than the former. Although the errors of the prediction formulae taking into account the differences among different concretes doubtless contribute significantly to the high values of these coefficients of variation, there is no reason for a bias of the statistics in favor of G_f or G_F. Thus, the statistics indicate that the fracture energy based on the measurements in the maximum load region is much less uncertain than that based on the measurement of the tail of the postpeak load-deflection curve. While both G_f and G_F are needed for accurate structural analysis, it follows that if the testing standard should measure, for the sake of simplicity, only one of these two fracture energies, then G_f is preferable.     

Étude expérimentale du mélange réactif au sein d'un réacteur torique ondulé (RTO)

Reactive mixing in a wavy torus reactor (WTR) has been examined experimentally. Its performances are compared to these of two other reactors: a plane torus reactor (PTR) and a baffled stirred tank reactor (BSTR). hydrodynamics of mixing has been studied using a plug flow model with axial dispersion for the WTR and PTR. The effect of axial dispersion on the kinetic of a chemical reaction was then analysed for the WTR, PTR and BSTR. Mixing times were slightly longer for the WTR due to a weaker axial dispersion. We also noticed an improvement of the convertion rate for low dissipated power.     

Al ionic radius influence on molecular dynamics simulations ofγ-Al2O3

Molecular dynamics (MD) simulations of-Al₂O₃, using a pairwise additive interaction potential of Pauling's type with four different radii for aluminum atoms, were analysed in order to determine the influence of the radius on the modification of coordination numbers of A1 relative to the ideal structure, at two different temperatures of 300 and 1500 K. It is found that the best choice is the radius of penta-coordinated aluminum, reproducing structural and vibrational properties of the compound in excellent agreement with experimentally observed properties.