Polypropylene membranes with the double sensitivity effect

This article describes the modification of polypropylene membranes leading to the preparation of thermo‐ and pH‐sensitive structures. Poly(N‐isopropylacrylamide), poly(acrylic acid), or copolymer poly(N‐isopropylacrylamide‐co‐acrylic acid) was grafted on to the membranes' surface activated by dielectric barrier discharge plasma. The properties of the modified membranes were evaluated by means of infrared spectroscopy and contact angle measurements. The effect of modification was monitored by the determination of water flux at two temperatures (20 and 45°C) and at various pH values (2.8–8.0). The membrane separation properties were investigated for the solutions of o‐bromocresol purple. It was found that membranes grafted with copolymer were responsive to both stimuli and they could be used for separation purpose. The separation performance was tailored by alteration of pH and temperature of feed solution. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41763.     

Molecular,rheological, and thermal study of long‐chain branched polypropylene obtained by esterification of anhydride grafted polypropylene

Long‐chain branched polypropylene was prepared using reaction in the molten state in the presence of glycerol and a linear polypropylene functionalized with maleic anhydride (PPg). The concentration of glycerol in the melt was varied in the range from 0.1 to 5 wt % to obtain different levels of branching. FTIR spectroscopy results indicate that the OH groups of glycerol react with the anhydrides on the PPg chains giving place to ester groups. The presence of long‐chain branches in the molecular structure of PPg was confirmed using multiple‐detection size‐exclusion chromatography and rheology. These techniques demonstrate that the level of branching increases with glycerol concentration and that the modification of PPg produces materials with a bimodal distribution of polymer species. Moreover, some of the highly modified materials display gel‐like behavior. The materials also display thermo‐rheological complexity and enhanced activation energy at low frequencies. The crystallization study shows that both the anhydride groups in PPg and the LCBs have opposite nucleating effects. PPg presents the largest activation energy of crystallization and its value decreases with the concentration of glycerol for a given level of crystallization. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40357.     

Structural and magnetic properties of pure and Ca-doped LaCoO3 nanopowders obtained by a sol-gel route

Pure and Ca-doped LaCoO3 nanopowders were prepared by a non-alkoxidic sol-gel route using cobalt(II) acetate, lanthanum(III) nitrate and calcium(II) acetate as oxide precursors. The structural evolution and magnetic properties of the samples were studied as a function of thermal treatments in air up to 1273 K. In particular, the microstructure and composition of the systems were analyzed by X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and X-ray Photoelectron Spectroscopy (XPS). Both pure and calcium-doped samples annealing at 973 K resulted in the formation of cubic LaCoO3 (average crystallite size <30 nm). This phase was fully retained in the calcium-doped materials even after annealing at higher temperatures, whereas a transition to the rhomboedral polymorph was detected in the pure samples at 1073 K. The magnetic behavior of the nanopowders was investigated as a function of temperature and applied field using both dynamic and static susceptibility measurements. Pure lanthanum cobaltite samples underwent a transition to an ordered state at 88 K, and their magnetic properties changed as a function of thermal treatments. As concerns calcium-doped samples, they ordered ferromagnetically at 171 and 185 K depending on the annealing temperature and displayed open hysteresis loops with coercive fields as large as 1.75 T at low temperatures.     

First charge-transfer complexes between tetrathiafulvalene and 1,2,5-chalcogenadiazole derivatives: Design,synthesis, crystal structures,electronic and electrical properties

The first charge-transfer complexes of tetrathiafulvalene (1) with 1,2,5-chalcogenadiazole derivatives, i.e. with [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (2) and 3,4-dicyano-1,2,5-telluradiazole (3), were designed, prepared in the form of air and thermally stable single crystals and structurally defined by X-ray diffraction as 1·2 and 1·3₂, respectively. Starting compound 2 (effective electron acceptor with potentially broad application in the field) was synthesized by a new efficient one-pot method from 3,4-diamino-1,2,5-oxadiazole and disulfur dichloride. The electronic structure of complexes 1·2 and 1·3₂ and thermodynamics of their formation were studied by means of DFT and QTAIM calculations and UV–Vis spectroscopy. The electrical properties of single crystals of the complexes were investigated revealing semiconductor properties with an activation energy of 0.34 eV for 1·2 and 0.40 eV for 1·3₂. Polycrystalline films of the complexes displayed photoconductive effects with increased conductivity under white-light illumination.     

Wind turbine angular frequency analysis by means of computer vision techniques

The turbine synchronization phenomenon is of great interest in order to estimate the flicker produced by a wind farm. This paper proposes an initial approach to analyze the appearance of this phenomenon by the use of various image processing techniques: a method to automatically calculate the angular frequency of an unknown number of wind turbines from a video. The recorded video images were obtained at the Manzanal wind farm, province of León (Spain).     

New threshold voltage definition for undoped symmetrical DG MOSFET

A new threshold definition is proposed for symmetrical undoped double gate MOS (DGMOS). Threshold voltage is calculated using the potential model described in [1] with only two fitting parameters, the values of which do not depend on device geometry. Comparison with the results of numerical simulations and other models of V_T is presented and good accuracy of the new model is demonstrated.     

Differences between conventional and glyphosate tolerant soybeans and moisture effect in their discrimination by near infrared spectroscopy

Previous studies showed that Near Infrared Spectroscopy (NIRS) could distinguish between Roundup Ready® (RR) and conventional soybeans at the bulk and single seed sample level, but it was not clear which compounds drove the classification. In this research the varieties used did not show significant differences in major compounds between RR and conventional beans, but moisture content had a big impact on classification accuracies. Four of the five RR samples had slightly higher moistures and had a higher water uptake than their conventional counterparts. This could be linked with differences in their hulls, being either compositional or morphological. Because water absorption occurs in the same region as main compounds in hulls (mainly carbohydrates) and water causes physical changes from swelling, variations in moisture cause a complex interaction resulting in a large impact on discrimination accuracies.     

Carboxymethylcellulose/polyaniline blends. Synthesis and properties

Summary Polyaniline (PANI) as one of the conducting polymers focuses intensive research on both scientific and practical field. There are quite a lot of known hybrid materials of PANI and other polymer systems with various synthetic polymers, which results in blends with various properties. The presented research covers the blends of polyaniline with semisynthetic (carboxymethyl) cellulose (CMC). The system could lead to a new antielectrostatic material with interesting properties and seems to be applicable as an additive for packaging in both food and non-food industry. The final material was obtained using both protonated (HCl) and deprotonated form of polyaniline in its semi-oxidized form of leucoemeraldine. Blending consisted in obtaining of thin layer by slow evaporation of the solvent from a mixture of PANI and CMC. For the main investigation atomic force microscopy (AFM) in non-contact mode was used, which gave the topological information about the surface and also some structural information about the material. The described process seems to be very interesting as a route for obtaining a new hybrid natural/synthetic material with very interesting properties and a potential for application.     

Dependability issues in visual–haptic interfaces

Dependability of a system is commonly referred to its reliability, its availability and its maintenability (RAM), but when this concept is applied to user interfaces there is no common agreement on what aspects of user–system interaction are related to a satisfactory RAM level for the whole system. In particular, when dealing with haptic systems, interface dependability may become a crucial issue in medical and in military domains when life-critical systems are to be manipulated or where costly remote control operations are to be performed, like in industrial processes control or in aerospace/automotive engineering and manufacturing. This paper discusses the role of dependability in haptic user interfaces, aiming to the definition of a framework for the assessment of the usability and dependability properties of haptic systems and their possible correlations. The research is based on the analysis of a visual–haptic-based simulator targeted to maintenance activity training for aerospace industry which is taken as a case study. As a result, we propose a novel framework able to collect and then process relevant interaction data during the execution of haptic tasks, enabling to analyze dependability vs. usability correlations.     

Fusing Landsat and MODIS data to retrieve multispectral information from fire-affected areas over tropical savannah environments in the Brazilian Amazon

ABSTRACT

In this study, the combination of surface reflectance products from Terra- Moderate Resolution Imaging Spectroradiometer and Landsat-Enhanced Thematic Mapper Plus sensors are explored through the Flexible Spatiotemporal DAta Fusion (FSDAF) algorithm within the framework of forest fire studies over tropical savannah environments. Thus, 60 fusion-derived images were generated from four spectral bands [red, near-infrared, shortwave infrared (SWIR₁ and SWIR₂)] and six spectral indices [normalized difference vegetation index, normalized difference moisture index, global environment monitoring index, soil-adjusted vegetation index, normalized burn ratio (NBR), and differenced normalized burn ratio (dNBR)] over two selected study sites. For all fusion processes performed, the actual Landsat images for the corresponding dates are available, which supports validation of the blended images. Additionally, integration of blended spectral indices in the immediate post-fire evaluation and the generation of fire severity were analysed. The blended bands presented correlation and Structure Similarity Index Measure (SSIM) values that were consistently higher than 0.819 and root mean square error values of less than 0.027, which confirms good accuracy levels obtained from the model. Similar correlation and SSIM accuracy levels were observed in the blended indices assessment for both study sites, which enables its values to be well-integrated for an analysis of the immediately post-fire date. However, the fire severity mapping from fused images needs to be carefully implemented since the dNBR index is generally less accurate than other blended indices. FSDAF fusion proved to be a useful alternative to retrieving multispectral information from savannah environments affected by fires.