A series of nanocomposites prepared by melt‐blending of cloisite‐based organoclays with poly(ethylene‐vinylacetate) (EVA) and neutralized poly (ethylene‐methacrylic acid) (EMA) copolymers were investigated via DSC, small‐angle X‐ray scattering (SAXS), and rheological techniques. SAXS results indicated partial clay exfoliation in all samples. In both EMA and EVA systems, the nominal melting temperature Tm and bulk crystallinity are not significantly affected by the presence of organoclays, suggesting that clay particles are predominantly confined in the amorphous phase. In rheological measurements (above Tm), the EVA‐clay system demonstrated a solid‐like rheological behavior under the small‐strain oscillatory shear, yet it was able to yield and flow under a steady shear, which is the characteristic of physical crosslinking. In contrast, the EMA‐clay system exhibited a melt‐like rheological behavior, where the influence of organoclay on the thermorheological behavior of the EMA composite was quite minimal. We propose that the carbonyl groups of vinylacetate in EVA interact with the clay surface, resulting in a strong physically crosslinking like interaction in the melt. On the other hand, the interaction between EMA and clay is weak because of repulsion between carboxyl anions and negatively charged clay surface. 相似文献
Relationships between the macroscopic deformation behaviour and microstructure of a pure (PBT-b-PTMO) block copolymer and a polymer nanocomposite (PBT-b-PTMO + 0.2 wt% SWCNT) were investigated by simultaneous small- and wide-angle X-ray scattering (SAXS and WAXS) during tensile deformation using synchrotron radiation. The Young's modulus was found to be 15% higher for the nanocomposite than for the pure block copolymer as well as the yield strength, while the elongation-to-break was less than a half. This different behaviour can be explained by taking into account the different structural features revealed by SAXS and WAXS and thus considering that SWCNT act as anchors in the nanocomposite, sharing the applied stress with the PBT crystals and partially preventing the flexible, non-crystallisable PTMO chains to elongate. 相似文献
Geometric inverse kinematics procedures that divide the whole problem into several subproblems with known solutions, and make use of screw motion operators have been developed in the past for 6R robot manipulators. These geometric procedures are widely used because the solutions of the subproblems are geometrically meaningful and numerically stable. Nonetheless, the existing subproblems limit the types of 6R robot structural configurations for which the inverse kinematics can be solved. This work presents the solution of a novel geometric subproblem that solves the joint angles of a general anthropomorphic arm. Using this new subproblem, an inverse kinematics procedure is derived which is applicable to a wider range of 6R robot manipulators. The inverse kinematics of a closed curve were carried out, in both simulations and experiments, to validate computational cost and realizability of the proposed approach. Multiple 6R robot manipulators with different structural configurations were used to validate the generality of the method. The results are compared with those of other methods in the screw theory framework. The obtained results show that our approach is the most general and the most efficient.
This correspondence presents a novel hierarchical clustering approach for knowledge document self-organization, particularly for patent analysis. Current keyword-based methodologies for document content management tend to be inconsistent and ineffective when partial meanings of the technical content are used for cluster analysis. Thus, a new methodology to automatically interpret and cluster knowledge documents using an ontology schema is presented. Moreover, a fuzzy logic control approach is used to match suitable document cluster(s) for given patents based on their derived ontological semantic webs. Finally, three case studies are used to test the approach. The first test case analyzed and clustered 100 patents for chemical and mechanical polishing retrieved from the World Intellectual Property Organization (WIPO). The second test case analyzed and clustered 100 patent news articles retrieved from online Web sites. The third case analyzed and clustered 100 patents for radio-frequency identification retrieved from WIPO. The results show that the fuzzy ontology-based document clustering approach outperforms the K-means approach in precision, recall, F-measure, and Shannon's entropy. 相似文献
Logos are one of the most important graphic design forms that use an abstracted shape to clearly represent the spirit of a community. Among various styles of abstraction, a particular golden-ratio design is frequently employed by designers to create a concise and regular logo. In this context, designers utilize a set of circular arcs with golden ratios (i.e., all arcs are taken from circles whose radii form a geometric series based on the golden ratio) as the design elements to manually approximate a target shape. This error-prone process requires a large amount of time and effort, posing a significant challenge for design space exploration. In this work, we present a novel computational framework that can automatically generate golden ratio logo abstractions from an input image. Our framework is based on a set of carefully identified design principles and a constrained optimization formulation respecting these principles. We also propose a progressive approach that can efficiently solve the optimization problem, resulting in a sequence of abstractions that approximate the input at decreasing levels of detail. We evaluate our work by testing on images with different formats including real photos, clip arts, and line drawings. We also extensively validate the key components and compare our results with manual results by designers to demonstrate the effectiveness of our framework. Moreover, our framework can largely benefit design space exploration via easy specification of design parameters such as abstraction levels, golden circle sizes, etc. 相似文献
The safety of patients and the quality of medical care provided to them are vital for their wellbeing. This study establishes a set of RFID (Radio Frequency Identification)-based systems of patient care based on physiological signals in the pursuit of a remote medical care system. The RFID-based positioning system allows medical staff to continuously observe the patient's health and location. The staff can thus respond to medical emergencies in time and appropriately care for the patient. When the COVID-19 pandemic broke out, the proposed system was used to provide timely information on the location and body temperature of patients who had been screened for the disease. The results of experiments and comparative analyses show that the proposed system is superior to competing systems in use. The use of remote monitoring technology makes user interface easier to provide high-quality medical services to remote areas with sparse populations, and enables better care of the elderly and patients with mobility issues. It can be found from the experiments of this research that the accuracy of the position sensor and the ability of package delivery are the best among the other related studies. The presentation of the graphical interface is also the most cordial among human-computer interaction and the operation is simple and clear. 相似文献
There are two methods applied for three-dimensional digital image correlation method to measure three-dimensional displacement. One is to measure the spatial coordinates of measuring points by analyzing the images. Then, the displacement vectors of these points can be calculated using the spatial coordinates of these points obtained at different stages. The other is to calibrate the parameters for individual measuring points locally. Then, the local displacements of these points can be measured directly. This study proposes a simple local three-dimensional displacement measurement method. Without any complicated distortion correction processes, this method can be used to measure small displacement in the three-dimensional space through a simple calibration process. A laboratory experiment and field experiment are carried out to prove the accuracy of this proposed method. Laboratory test errors of one-dimensional experiment are similar to the accuracy of the XYZ table; the error in Z-direction is only 0.0025% of the object distance. The measurement error of laboratory test is about 0.0033% of the object distance for local three-dimensional displacement measurement test. Test and analysis results of field test display that in-plane displacement error is only 0.12 mm, and the out-of-plane error is 1.1 mm for 20 m × 30 m measuring range. The out-of-plane error is only about 10 PPM of the object distance. These test and analysis results show that this proposed method can achieve very high accuracy under small displacement for both of laboratory and field tests. 相似文献