流程加工CAN测控网络的应用层协议研究

为提高CAN测控网络的适应性和通信效率,以CAN2.0A技术规范为基础,针对流程加工测控网络的特点,设计面向流程加工领域的CAN总线应用层协议ProCAN。在明确流程加工概念及范围的基础上,分析流程加工测控系统结构模型的特征,提出通信报文的类型,定义标准数据帧仲裁域与数据域的编码格式,并讨论ProCAN协议的通信模式、通信状态、通信异常及长报文误帧重传控制。利用OPNET网络仿真软件进行实验,结果表明,ProCAN协议能实现报文通信,并且具有延时短、实时性强、可靠性高的特点,尤其当网络负载较大时,效果更为明显。     

结晶梯恩梯生产工艺的研究

讨论了结晶梯恩梯的制造工艺、六硝基芪用量、络合物的形成与稳定性，以及六硝基芪质量等影响结晶梯恩梯质量的因素。     

丙烯腈悬浮床催化水合制备丙烯酰胺的催化剂研究

考察了丙烯腈悬浮床水合制备丙烯酰胺的各种催化剂性能，研究了雷尼铜（Ｒａｎｅｙ Ｃｕ）催化剂的三种影响因素：铜铝成分的比例、冷却成型方式和添加组分的影响及催化剂的再生性能。结果表明：喷雾法制备的雷尼铜［Ａｌ∶Ｃｕ＝５２∶４８（质量比）］催化剂比普通雷尼铜催化剂活性高１０％，强度高２４％，并具有良好的再生性能，适于作为悬浮床催化剂     

微波辐射下HPA快速催化合成丁酸异戊酯

在微波辐射下，以杂多酸HPA为催化剂，快速合成丁酸异戊酯，确定了酯化的优化条件。实验结果表明，醇酸物质的量比为1．9，催化剂用量为反应物料的1．O％，微波功率为800w，反应时间为20min，酯收率超过96％。     

一类非线性输出反馈系统的自适应输出调节问题

本文讨论一类非线性系统的全局鲁棒输出调节问题.假定被控非线性系统的系统输入方向未知,且产生参考或扰动信号的外部系统含未知参数,这为控制律的设计带来了挑战.文章使用自适应控制方法和内模原理,解决了一类相对阶为1的非线性输出反馈系统的输出调节问题,并将结果应用于处理Lorenz系统的渐近跟踪问题.     

Effect of particle size on the surface oxidation and flotation behavior of galena particles in lime system

ABSTRACT

In this research, the effect of particle size on the surface oxidation and flotation behavior of galena in the lime system was studied. Coarse (?0.074 + 0.038 mm), intermediate (?0.038 + 0.025 mm) and fine (?0.025 mm) galena particles were used in the experiment. The dissolution tests, flotation tests, and sorption tests were accomplished. Through further analysis by XPS, the effect of particle size and lime was observed. The decrease of mineral particle sizes increased the adsorption ratio of collector and the dissolution of galena, while the hydrophilic product OH^?/Ca(OH)⁺ produced by dissolution occupied the dominant position, which led to the minerals hydrophilic.     

具有自适应噪声边界的Tube可达集鲁棒预测控制

针对过程噪声设定边界与真实噪声边界失配的有界干扰离散线性不确定系统,提出一种具有自适应噪声边界的Tube可达集鲁棒模型预测控制方法.首先,该算法引入基于MIT规则的自适应集员滤波在线估计系统状态和噪声边界.其次,基于估计值,通过迭代自适应集员滤波的时间更新部分计算出预测时域内闭环不确定系统状态的可达集.最后,用可达集代替不变集并根据Tube鲁棒模型预测控制策略,给出了实际不确定系统的控制律,确保系统状态鲁棒渐近稳定,并收敛于终端干扰不变集.仿真结果验证了该控制方法的有效性.     

Crystalline morphology and isothermal crystallization kinetics of poly(ethylene terephthalate)/clay nanocomposites

A poly(ethylene terephthalate) (PET)/montmorillonite clay nanocomposite was synthesized via in situ polymerization. Microscopic studies revealed that in an isothermal crystallization process, some crystallites in the nanocomposite initially were rod‐shaped and later exhibited three‐dimensional growth. The crystallites in the nanocomposite were irregularly shaped, rather than spherulitic, being interlocked together without clear boundaries, and they were much smaller than those of neat PET. With Avrami analysis, the isothermal crystallization kinetic parameters (the Avrami exponent and constant) were obtained. The rate constants for the nanocomposite demonstrated that clay could greatly increase the crystallization rate of PET. The results for the Avrami exponent were consistent with the observation of the rodlike crystallites in the PET/clay nanocomposite during the initial stage. Wide‐angle X‐ray scattering and Fourier transform infrared studies showed that, in comparison with neat PET, the crystal lattice parameters and crystallinity of the nanocomposite did not change significantly, whereas more defects may have been present in the crystalline regions of the nanocomposite because of the presence of the clay. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1381–1388, 2004     

基于FPGA的10G以太网并行CRC设计

为了解决10G以太网通信链路中大规模数据并行CRC校验的实时处理问题,提出了一种基于级联结构的并行CRC校验方法。通过传统CRC编码结构推导出任意延拓序列的CRC校验方法,设计了针对任意延拓序列的CRC校验模块。在校验算法实现中针对传统异或逻辑进行了并行电路改进,降低了电路处理时延。搭建了实验环境对所设计模块进行了验证,实验结果表明,该方法可以有效满足10G以太网接入系统CRC校验要求。     

一种无人机生成平滑航迹方法的研究与实现

无人机在未来战场中占有重要地位,航迹规划直接影响其作战能力。针对无人机航迹规划算法中存在的问题,提出一种生成平滑航迹的方法。该方法解决了直角拐弯、航迹不平滑、规划航迹与实际航迹不一致的问题。最后,通过VC++6.0+mapX5.0编程实现,结果表明了该方法的优势。