A SOCIOLOGICAL PERSPECTIVE ON THE REORDERING PROBLEM IN MULTIPATH ROUTING

The term multipath routing means using multiple paths concurrently to transport data over network. The main problem of this routing scheme is the difference among the delays of selected paths, which causes reordering of a single flow's packets. In this paper, this problem is analyzed through a sociological perspective. We show that reordering problem is not inherently related to multipath routing, rather caused by the dominant capitalist view of the problem. then, the problem is addressed through a Marxism perspective. We theoretically prove that by this perspective, there exists a routing scheme that minimizes latency and also the requirement of buffering at receiver.     

Mapping the regional extent of tropical forest regeneration stages in the Brazilian Legal Amazon using NOAA AVHRR data

The study aimed to map several stages of tropical forest regeneration across the Brazilian Legal Amazon using 1.1 km NOAA AVHRR data. Regenerating forest extent was defined using an unsupervised classification of AVHRR channels 1, 2 and 3 and the Global Environment Monitoring Index (GEMI). A method for discriminating four forest regeneration stages was then developed, based on relationships between AVHRR channels 1, 2 and 3 and forest age. This method was applied to AVHRR data to map forests associated with Stages I (early colonization phase, open canopy, < 5 years), II (closed, singlelayered canopy, 5-9 years), III (closed canopy with structural development, 9-20 years) and IV (closed multilayered canopy, > 20 years). The maps provided new regional estimates of regenerating forest for the Legal Amazon and indicated that, over the period 1991 to 1994, approximately 35.8% (157 973 km2) of the total deforested area of 440 186 km2 (estimated for 1992) supported regenerating forest, with 48% of these forests aged at less than 5 years. The study concluded that AVHRR data has an important role in mapping and monitoring tropical forest regeneration. The datasets generated provide valuable input to models of regional carbon flux. For example, Grace et al . (1995a, b) reported net annual CO2 absorption 8.5 2.0 moles m 2 for mature forests in south-west Amazonia suggesting     

Time horizons in rats foraging for food in temporally separated patches.

An important tenet of optimal foraging theory is that foragers compare prey densities in alternative patches to determine an optimal distribution of foraging behavior over time. A critical question is over what time period (time horizon) this integration of information and behavior occurs. Recent research has indicated that rats do not compare food density in a depleting patch with that in a rich patch delayed by an hour or more (Timberlake, 1984). In the present research we attempted to specify over what time period a future rich patch would affect current foraging. The effect of future food was measured by early entry into the rich patch (anticipation) and by a decrease in food obtained in the depleting patch (suppression). The rats showed anticipation of a rich patch up to an hour distant, but suppressed current feeding only if the rich patch was 16 min distant or less. The suppression effect appeared mediated by competition for expression between anticipatory entries into the rich patch and continued foraging in the depleting patch. These results suggest that optimal foraging is based on a variety of specific mechanisms rather than a general optimizing algorithm with a single time horizon. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Click‐ligation of coumarin to polyether polyols for polyurethane foams

A simple strategy for the synthesis and functionalization of polyurethanes is described. Anionic ring‐opening polymerization was combined with ‘click’ chemistry to synthesize polyols with fluorescent properties. This route allows the incorporation of a wide range of functionalities in the polyols with an easy, clean and highly selective process compatible with several types of functional groups. The proposed strategy opens the way to the production, in a cost‐effective way, of ‘smart’ polyurethanes with non‐conventional properties like fire retardancy, antimite properties, antibacterial properties, etc. Alkynyl groups were introduced into the polyol chains by the controlled addition of glycidyl propargyl ether as co‐monomer during a conventional anionic ring‐opening copolymerization with propylene oxide. Subsequently 4‐azidomethyl‐7‐methoxycoumarin molecules were introduced onto the alkynyl‐polyether polyols by copper‐catalysed cycloaddition reactions to produce end‐functionalized polyols. The chemical structure of the novel polyols was characterized using infrared spectroscopy, nuclear magnetic resonance spectroscopy, gel permeation chromatography with triple detection and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectroscopy. These characterization techniques confirmed the presence of a considerable amount of functional groups in the structure of the polyols. Finally, various fluorescent rigid foams, based on the functionalized polyols, were synthesized. Copyright © 2012 Society of Chemical Industry     

RNRA and neutron threshold analyses of thick lithium coatings deposited by sputter evaporation

Li coatings on various substrates have numerous applications: Boron neutron capture therapy, super conducting tokamak, etc.Unfortunately the main difficulty using Li is its reactivity in air and diffusion into metals. It is the only metal that reacts with nitrogen at room temperature and it tarnishes and oxidizes rapidly in air.In this work, we investigate how to profile thick Li layers (50 μm) deposited on SiO₂ substrates by a method based on plasma sputtering, involving both DC sputtering and evaporation simultaneously.A thick Li layer (≈10 μm) was covered with a thin stainless steel layer to prevent oxidation during transfer of the sample from the sputtering chamber and the accelerator. Li coatings were investigated by RNRA and neutron threshold reaction to obtain interdiffusion profiles of the different components and their concentration. The depth profile using the ⁷Li(p,γ)⁸Be^∗ resonance nuclear reaction occurring at 440 keV allows us to obtain Li concentration versus depth up to 50 μm.Preliminary results indicate that homogeneous Li layers can be obtained and protected against air, even though it diffuses into the encapsulated layers.     

Synthesis and structural characteristics of highly graphitized carbon nanofibers produced from the catalytic decomposition of ethylene: Influence of the active metal (Co, Ni, Fe) and the zeolite type support

In order to study the influence of the metal phase in the carbon yield and structural characteristics of carbon nanofibers (CNFs) synthesized by CVD over supported catalysts, different catalysts were prepared using iron, cobalt and nickel as active metal and zeolites Y and mordenite as support. The results showed that the metal precursor produced a great influence on the catalytic activity, fact that could be explained in according to the different solubility of carbon in the metals or in the differences in the diffusion and segregation of carbon through the metal particles. Characterization data of the solid carbon products revealed unique structures and textural properties as well as crystalline conditions on function of metal used. Additionally, support-metal interaction was evaluated, where experiments with similar nickel load over Y and mordenite zeolites were carried out, finding higher carbon yields and more ordered structures when Y zeolite was used.     

Factors explaining why people join, remain in, or leave a scholarly society: The Canadian Psychological Association.

Both theory and subject matter experts were used to generate items for a survey designed to increase understanding of why psychologists join, remain in, or leave the Canadian Psychological Association (CPA). The subject matter experts included current, former, and nonmember psychologists. 2,200 questionnaires were distributed by e-mail, and 275 were sent by surface mail. The response rates were 20% and 29% for e-mail and surface mail, respectively. Principal components analysis of the survey items resulted in 5 factors: outcomes, advocacy, organizational justice, annual convention, and professional recognition. Discriminant function analysis results showed that, on the basis of these factors, the authors were able to correctly classify respondents as current vs former members, and current vs never been members. Current members, former members, and psychologists who never joined CPA were found to differ significantly on their rating of most factors. The factors relevant for retaining members differ from those that attract psychologists to join CPA. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Bubble growth and collapse in pre-fermented doughs during freezing,thawing and final proving

The formation of large bubbles was observed by MRI during freezing. This was attributed to the compression of gases in a structure that cannot globally deform (due to the frozen “shell”), the consecutive rupture of dough films and the coalescence of neighbouring bubbles. The fraction occupied by these large bubbles was consistent with the hypothesis of thermal contraction, though this was not the only mechanism in play. Conversely medium-sized bubbles initially present in the dough did not grow during freezing, suggesting that maximum stress was dependent on location.These large bubbles were suspected to contribute greatly to dough collapse just after thawing since they were still present in the thawed dough, but in an elongated form. Collapse was related to delayed expansion during the second fermentation stage. The longer the duration of the first fermentation stage, the more collapsed the dough structure became just after thawing and the coarser the dough structure was at the end of the second fermentation period.     

Dilute-gas properties of the monatomic gases and their mixtures from the MSK potential

The three-parameter MSK potential is used to calculate the dilute-gas properties of the monatomic gases and their mixtures. The parameters are fitted to data of the second virial coefficient and the Joule-Thomson coefficient; the calculations of all other thermophysical properties are predictions. For mixtures, universal combination rules for the potential parameters are used. It is shown that a consistent representation of the gas data of the monatomic systems is possible.     

Postflame reaction chemistry of dichloromethane: variations in equivalence ratio and temperature

We report on the destruction pathways and byproduct formation of dichloromethane (CH₂Cl₂) in conditions typical of incinerator postflame regions (injection temperature = 900–1200 K; equivalence ratio = 0.6, 0.9, 1.0, 1.1; residence time = 0.28–0.35 s). This is the first study to independently vary equivalence ratio and temperature, and evaluate their impacts on byproduct yield and destruction efficiency. We inject 750 ppm CH₂Cl₂ into postflame combustion products and measure byproducts with extractive FTIR spectroscopy. We use a detailed chemical kinetic mechanism and reaction rate analysis to predict the changes in reaction pathways as a function of equivalence ratio. The predictions for major products and several intermediate species compare well with experiments; the largest disparities are an underprediction of phosgene (CCl₂O) and an overprediction of methyl chloride (CH₃Cl). Both the experiment and the numerical predictions show increased destruction at lower equivalence ratios. However, the experiments reveal increased levels of stable chlorinated organics at lower equivalence ratios, opposite to the numerical prediction. We discuss reasons for this discrepancy and implications of these results for designing control strategies to promote full conversion to HCl and to reduce chlorinated byproduct emissions.