Numerical stress analysis of carbon-fibre-reinforced epoxy composite single-lap joints

A numerical strategy based on a finite element method is developed in order to model the stress distribution in single-lap adhesive joints. The joints were manufactured from unidirectional carbon-fibre-reinforced epoxy composites joined by an epoxy adhesive layer. Experimental parameters are used as a reference to allow for the numerical validation of the proposed analysis. Additionally, joints with different types of defects in the lap region were modelled with both two-dimensional and three-dimensional finite elements. The models include defects that vary in format (straight or circular) and position (centred or dispersed). The influenced spew fillets in the adhesive layer were also examined. Although the computational cost is higher, the results of the three-dimensional model are more compatible with the experimental results than those of the two-dimensional model. The effect of defects in the joints was adequately modelled, and the proposed methodology can be used to accurately assess the integrity of the joints since the defect has been successfully detected.     

Synthesis and Evaluation of the Anticancer and Trypanocidal Activities of Boronic Tyrphostins

Molecules containing an (cyanovinyl)arene moiety are known as tyrphostins because of their ability to inhibit proteins from the tyrosine kinase family, an interesting target for the development of anticancer and trypanocidal drugs. In the present work, (E)‐(cyanovinyl)benzeneboronic acids were synthesized by Knoevenagel condensations without the use of any catalysts in water through a simple protocol that completely avoided the use of organic solvents in the synthesis and workup process. The in vitro anticancer and trypanocidal activities of the synthesized boronic acids were also evaluated, and it was discovered that the introduction of the boronic acid functionality improved the activity of the boronic tyrphostins. In silico target fishing with the use of a chemogenomic approach suggested that tyrosine‐phosphorylation‐regulated kinase 1a (DYRK1A) was a potential target for some of the designed compounds.     

Synthesis and characterization of flexible polyoxadiazole films through cyclodehydration of polyhydrazides

Aiming to produce flexible films of poly(4,4′-diphenylether-1,3,4-oxadiazole), POD-DPE, the synthesis of POD-DPE through thermal cyclodehydration of polyhydrazide in solutions of poly(phosphoric acid), PPA, and in film form is studied here. It was observed that POD-DPE polymer samples obtained when the cyclodehydration of polyhydrazide is performed in solutions of PPA are insoluble in the solvents normally used for film preparation. On the other hand, the cyclodehydration of polyhydrazide in film form can lead to brittle POD-DPE films due to the high temperatures required for reaction to occur. In order to obtain flexible POD-DPE films with high conversion through cyclodehydration of polyhydrazide films, it is shown here that it is very important to adjust the cyclodehydration temperature (T_c) as a function of the glass transition temperature (T_g) and the weight average molecular weight (M_w) of the polyhydrazide. In all cases analyzed, polyhydrazides were synthesized by low temperature solution polycondensation reactions and were characterized by intrinsic viscosity measurements, size exclusion chromatograpy, nuclear magnetic resonance, infrared spectroscopy and thermal analysis. Polyhydrazides with weight average molecular weights up to 74,100 g/mol were obtained. The POD-DPE films obtained were characterized by infrared spectroscopy and nuclear magnetic resonance, showing that the production of POD-DPE films is indeed possible from cyclodehydration of polyhydrazide films.     

Evaluation of Compacted Cementitious Composites for Porous Bearings

The use of porous materials as a restrictor in aerostatic bearings provides many advantages over conventional restrictors, such as small variation of temperature, high damping, high operational speeds, limited wear, and capacity to support radial, axial, and combined loading. A design of experiment (DOE) was carried out to evaluate cold‐pressed cementitious composites as an air restrictor in thrust bearings. The physical and mechanical properties such as the apparent porosity, permeability, and elastic modulus were investigated in this work, thus verifying the structural and flow characteristics of the composites for such application. The composites fabricated with low compacting pressure and small silica particles provided the material requirements for porous bearings.     

Argon Implantation in Tetrahedral Amorphous Carbon Deposited by Filtered Cathodic Vacuum Arc

The implantation of argon in tetrahedral amorphous carbon (ta-C), deposited by the filtered cathodic vacuum arc technique and concurrently bombarded with argon ions (Ar⁺), is investigated in this study. The ta-C films were prepared with a 5-ms DC-pulsed arc, a current of 190 A, and a frequency of 3 Hz, and they were deposited on a ground substrate holder. The argon atoms were implanted into the film by simultaneously bombarding the films with a beam of Ar⁺ in the 0-180 eV energy range. The concentration of argon, determined by Rutherford backscattering spectroscopy, was investigated as a function of the Ar⁺ energy. Raman scattering spectroscopy was used to investigate the structure of the films. The stress of the films depends on the Ar⁺ energy and reduces significantly as a function of the annealing temperature. A study of argon effusion, ranging from room temperature up to 1000 °C, shows that the argon atoms evolve from the films at different temperatures depending on the Ar⁺ energy. Scanning electron microscopy revealed the formation of bubbles after argon effusion. It was observed that the structural transformations that promote the relaxation of the carbon matrix and the argon effusion are different from each other.     

Anaerobic methane oxidation and aerobic methane production in an east African great lake (Lake Kivu)

We investigated CH₄ oxidation in the water column of Lake Kivu, a deep meromictic tropical lake with CH₄-rich anoxic deep waters. Depth profiles of dissolved gases (CH₄ and N₂O) and a diversity of potential electron acceptors for anaerobic CH₄ oxidation (NO₃^?, SO₄^2?, Fe and Mn oxides) were determined during six field campaigns between June 2011 and August 2014. Denitrification measurements based on stable isotope labelling experiments were performed twice. In addition, we quantified aerobic and anaerobic CH₄ oxidation, NO₃^? and SO₄^2? consumption rates, with and without the presence of an inhibitor of SO₄^2?-reducing bacteria activity. Aerobic CH₄ production was also measured in parallel incubations with the addition of an inhibitor of aerobic CH₄ oxidation. The maximum aerobic and anaerobic CH₄ oxidation rates were estimated to be 27?±?2 and 16?±?8?μmol/L/d, respectively. We observed a difference in the relative importance of aerobic and anaerobic CH₄ oxidation during the rainy and the dry season, with a greater role for aerobic oxidation during the dry season. Lower anaerobic CH₄ oxidation rates were measured in presence of molybdate in half of the measurements, suggesting the occurrence of linkage between SO₄^2? reduction and anaerobic CH₄ oxidation. NO₃^? consumption and dissolved Mn production rates were never high enough to sustain the measured anaerobic CH₄ oxidation, reinforcing the idea of a coupling between SO₄^2? reduction and CH₄ oxidation in the anoxic waters of Lake Kivu. Finally, significant rates (up to 0.37?μmol/L/d) of pelagic CH₄ production were also measured in oxygenated waters.     

Hydrometallurgical separation of aluminium,cobalt, copper and lithium from spent Li-ion batteries

A hydrometallurgical route based on leaching-crystallization steps for the separation of metals Al, Co, Cu and Li from spent Li-ion batteries was evaluated in this paper. Once dismantled for the removal of both plastic and steel cases, the anode (containing mainly Cu) of such batteries was manually separated from the cathode (which contains Al, Co and Li) for the recovery of Cu. The metal content of both anode and cathode was assessed by X-ray diffraction (XRD), X-ray fluorescence (XRF) and atomic absorption analytical methods. The cathode was firstly leached with NaOH for the selective removal of Al, followed by leaching with H₂SO₄ + H₂O₂ for the dissolution of the remaining Co and Li. The operating variables concentration of NaOH and concentration of H₂O₂ were found significant for the metal dissolution conditions investigated at basic and acid leaching operations, respectively. On the other hand, the variables temperature and concentration of H₂SO₄ showed minor effects at acid leaching step. Reaction schemes were proposed to describe basic and acid leaching operations. The recovery of Co from the acid liquor was carried out by crystallization. This hydrometallurgical route was found to be simple and adequate to separate metals for recycling purposes.