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101.
Sainan Luo Tao Yuan Luke Soule Jiafeng Ruan Yahui Zhao Dalin Sun Junhe Yang Meilin Liu Shiyou Zheng 《Advanced functional materials》2020,30(5)
Ion‐insertion capacitors show promise to bridge the gap between supercapacitors of high power densities and batteries of high energy densities. While research efforts have primarily focused on Li+‐based capacitors (LICs), Na+‐based capacitors (SICs) are theoretically cheaper and more sustainable. Owing to the larger size of Na+ compared to Li+, finding high‐rate anode materials for SICs has been challenging. Herein, an SIC anode architecture is reported consisting of TiO2 nanoparticles anchored on a sheared‐carbon nanotubes backbone (TiO2/SCNT). The SCNT architecture provides advantages over other carbon architectures commonly used, such as reduced graphene oxide and CNT. In a half‐cell, the TiO2/SCNT electrode shows a capacity of 267 mAh g?1 at a 1 C charge/discharge rate and a capacity of 136 mAh g?1 at 10 C while maintaining 87% of initial capacity over 1000 cycles. When combined with activated carbon (AC) in a full cell, an energy density and power density of 54.9 Wh kg?1 and 1410 W kg?1, respectively, are achieved while retaining a 90% capacity retention over 5000 cycles. The favorable rate capability, energy and power density, and durability of the electrode is attributed to the enhanced electronic and Na+ conductivity of the TiO2/SCNT architecture. 相似文献
102.
Ryan Murphy Yucun Zhou Lei Zhang Luke Soule Weilin Zhang Yu Chen Meilin Liu 《Advanced functional materials》2020,30(35)
Reversible solid oxide cells based on ceramic proton conductors have potential to be the most efficient system for large‐scale energy storage. The performance and long‐term durability of these systems, however, are often limited by the ionic conductivity or stability of the proton‐conducting electrolyte. Here new family of solid oxide electrolytes, BaHfxCe0.8?xY0.1Yb0.1O3?δ (BHCYYb), which demonstrate a superior ionic conductivity to stability trade‐off than the state‐of‐the‐art proton conductors, BaZrxCe0.8?xY0.1Yb0.1O3?δ (BZCYYb), at similar Zr/Hf concentrations, as confirmed by thermogravimetric analysis, Raman, and X‐ray diffraction analysis of samples over 500 h of testing are reported. The increase in performance is revealed through thermodynamic arguments and first‐principle calculations. In addition, lab scale full cells are fabricated, demonstrating high peak power densities of 1.1, 1.4, and 1.6 W cm?2 at 600, 650, and 700 °C, respectively. Round‐trip efficiencies for steam electrolysis at 1 A cm?2 are 78%, 72%, and 62% at 700, 650, and 600 °C, respectively. Finally, CO2? H2O electrolysis is carried out for over 700 h with no degradation. 相似文献
103.
Luke Ryan Il Yong Kim 《International journal for numerical methods in engineering》2019,118(7):371-394
The ever-present drive for increasingly high-performance designs realized on shorter timelines has fostered the need for computational design generation tools such as topology optimization. However, topology optimization has always posed the challenge of generating difficult, if not impossible to manufacture designs. The recent proliferation of additive manufacturing technologies provides a solution to this challenge. The integration of these technologies undoubtedly has the potential for significant impact in the world of mechanical design and engineering. This work presents a new methodology which mathematically considers additive manufacturing cost and build time alongside the structural performance of a component during the topology optimization procedure. Two geometric factors, namely, the surface area and support volume required for the design, are found to correlate to cost and build time and are controlled through the topology optimization procedure. A novel methodology to consider each of these factors dynamically during the topology optimization procedure is presented. The methodology, based largely on the use of the spatial gradient of the density field, is developed in such a way that it does not leverage the finite element discretization scheme. This work investigates a problem that has not yet been explored in the literature: direct minimization of support material volume in density-based topology optimization. The entire methodology is formulated in a smooth and differentiable manner, and the sensitivity expressions required by gradient based optimization solvers are presented. A series of example problems are provided to demonstrate the efficacy of the proposed methodology. 相似文献
104.
Flow regulation and water abstractions may change the complex relationship between river hydraulics, morphology, and riparian vegetation. As a result, rivers are likely to decrease their dynamics, increase the amount of vegetation, and modify their habitat structure. Flood events provide a natural mechanism for removal of invasive vegetation and recreation of natural floodplain habitats. This work aims at evaluating and quantifying how gravel‐bed braided rivers naturally control vegetation encroachment through morphological processes and the impact of both naturally occurring and induced avulsions. Flume experiments were conducted in a 24‐m‐long x 1.6‐m‐wide channel filled with well‐sorted sand and constant longitudinal gradient at 0.01 m/m. Once a braided network developed, the flume was seeded with Eruca sativa at a density of 1.5 seeds/cm2 and grown until an approximate height of 1.1 cm. Experiments evaluated low‐, medium‐, and large‐flood events and documented morphological changes and impacts to vegetation at four intervals during the experiments. High‐resolution images captured approximately 3 m above the flume were used to produce accurate Structure‐from‐Motion‐derived topography and orthoimagery (average errors 2 mm). Vegetation dynamics were observed to be highly variable and depend on local morphological changes and bank erosion. Discharge is the first‐order control on vegetation removal, but our results show that occurrence of avulsions significantly increases vegetation removal. The experiments highlight that a relatively small amount of sediment relocation can be an effective tool to induce avulsions and reduce vegetation encroachment on regulated rivers. 相似文献
105.
Tuning the Molecular Weight of the Electron Accepting Polymer in All‐Polymer Solar Cells: Impact on Morphology and Charge Generation 下载免费PDF全文
Rukiya Matsidik Shyamal K. K. Prasad Luke A. Connal Amelia C. Y. Liu Lars Thomsen Justin M. Hodgkiss Christopher R. McNeill 《Advanced functional materials》2018,28(18)
Molecular weight is an important factor determining the morphology and performance of all‐polymer solar cells. Through the application of direct arylation polycondention, a series of batches of a fluorinated naphthalene diimide‐based acceptor polymer are prepared with molecular weight varying from Mn = 20 to 167 kDa. Used in conjunction with a common low bandgap donor polymer, the effect of acceptor molecular weight on solar cell performance, morphology, charge generation, and transport is explored. Increasing the molecular weight of the acceptor from Mn = 20 to 87 kDa is found to increase cell efficiency from 2.3% to 5.4% due to improved charge separation and transport. Further increasing the molecular weight to Mn = 167 kDa however is found to produce a drop in performance to 3% due to liquid–liquid phase separation which produces coarse domains, poor charge generation, and collection. In addition to device studies, a systematic investigation of the microstructure and photophysics of this system is presented using a combination of transmission electron microscopy, grazing‐incidence wide‐angle X‐ray scattering, near‐edge X‐ray absorption fine‐structure spectroscopy, photoluminescence quenching, and transient absorption spectroscopy to provide a comprehensive understanding of the interplay between morphology, photophysics, and photovoltaic performance. 相似文献
106.
Rasch PJ Tilmes S Turco RP Robock A Oman L Chen CC Stenchikov GL Garcia RR 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2008,366(1882):4007-4037
We provide an overview of geoengineering by stratospheric sulphate aerosols. The state of understanding about this topic as of early 2008 is reviewed, summarizing the past 30 years of work in the area, highlighting some very recent studies using climate models, and discussing methods used to deliver sulphur species to the stratosphere. The studies reviewed here suggest that sulphate aerosols can counteract the globally averaged temperature increase associated with increasing greenhouse gases, and reduce changes to some other components of the Earth system. There are likely to be remaining regional climate changes after geoengineering, with some regions experiencing significant changes in temperature or precipitation. The aerosols also serve as surfaces for heterogeneous chemistry resulting in increased ozone depletion. The delivery of sulphur species to the stratosphere in a way that will produce particles of the right size is shown to be a complex and potentially very difficult task. Two simple delivery scenarios are explored, but similar exercises will be needed for other suggested delivery mechanisms. While the introduction of the geoengineering source of sulphate aerosol will perturb the sulphur cycle of the stratosphere signicantly, it is a small perturbation to the total (stratosphere and troposphere) sulphur cycle. The geoengineering source would thus be a small contributor to the total global source of 'acid rain' that could be compensated for through improved pollution control of anthropogenic tropospheric sources. Some areas of research remain unexplored. Although ozone may be depleted, with a consequent increase to solar ultraviolet-B (UVB) energy reaching the surface and a potential impact on health and biological populations, the aerosols will also scatter and attenuate this part of the energy spectrum, and this may compensate the UVB enhancement associated with ozone depletion. The aerosol will also change the ratio of diffuse to direct energy reaching the surface, and this may influence ecosystems. The impact of geoengineering on these components of the Earth system has not yet been studied. Representations for the formation, evolution and removal of aerosol and distribution of particle size are still very crude, and more work will be needed to gain confidence in our understanding of the deliberate production of this class of aerosols and their role in the climate system. 相似文献
107.
Jackiw Luke B.; Arbuthnott Katherine D.; Pfeifer Jeffrey E.; Marcon Jessica L.; Meissner Christian A. 《Canadian Metallurgical Quarterly》2008,40(1):52
This study examined whether findings from research on the cross-race effect (CRE) in eyewitness memory with Caucasian-Black samples can be generalised to Caucasian-First Nations pairings in a lineup identification task. This study used a novel approach to investigate the CRE, using six targets, as well as simultaneous lineups that included both target-present and target-absent arrays. This study also addressed the efficacy of the contact hypothesis as it applies to these populations. A significant CRE was discovered. Furthermore, both Caucasian and First Nations participants were more likely to choose from the lineup when attempting to recognise First Nations faces than when attempting to recognise Caucasian faces. Contact with the other race had no effect on recognition accuracy of that race. Potential implications and directions for future research are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
108.
Edirisinghe PD Moore JF Skinner-Nemec KA Lindberg C Giometti CS Veryovkin IV Hunt JE Pellin MJ Hanley L 《Analytical chemistry》2007,79(2):508-514
A novel analytical method based on laser desorption postionization mass spectrometry (LDPI-MS) was developed to investigate the competence and sporulation factor-a pentapeptide of amino acid sequence ERGMT-within intact Bacillus subtilis biofilms. Derivatization of the neat ERGMT peptide with quinoline- and anthracene-based tags was separately used to lower the peptide ionization potential and permit direct ionization by 7.87-eV vacuum ultraviolet radiation. The techniques of mass shifting and selective ionization of the derivatized peptide were combined here to permit detection of ERGMT peptide within intact biofilms by LDPI-MS, without any prior extraction or chromatographic separation. Finally, imaging MS specific to the derivatized peptide was demonstrated on an intact biofilm using LDPI-MS. The presence of ERGMT in the biofilms was verified by bulk extraction/LC-MS. However, MALDI imaging MS analyses were unable to detect ERGMT within intact biofilms. 相似文献
109.
Arain MA Quetschke V Gleason J Williams LF Rakhmanov M Lee J Cruz RJ Mueller G Tanner DB Reitze DH 《Applied optics》2007,46(12):2153-2165
We describe an adaptive optical system for use as a tunable focusing element. The system provides adaptive beam shaping via controlled thermal lensing in the optical elements. The system is agile, remotely controllable, touch free, and vacuum compatible; it offers a wide dynamic range, aberration-free focal length tuning, and can provide both positive and negative lensing effects. Focusing is obtained through dynamic heating of an optical element by an external pump beam. The system is especially suitable for use in interferometric gravitational wave interferometers employing high laser power, allowing for in situ control of the laser modal properties and compensation for thermal lensing of the primary laser. Using CO(2) laser heating of fused-silica substrates, we demonstrate a focal length variable from infinity to 4.0 m, with a slope of 0.082 diopter/W of absorbed heat. For on-axis operation, no higher-order modes are introduced by the adaptive optical element. Theoretical modeling of the induced optical path change and predicted thermal lens agrees well with measurement. 相似文献
110.
Hofmann CE Vesseur EJ Sweatlock LA Lezec HJ García de Abajo FJ Polman A Atwater HA 《Nano letters》2007,7(12):3612-3617
We report the observation of plasmonic modes of annular resonators in nanofabricated Ag and Au surfaces that are imaged by spectrally resolved cathodoluminescence. A highly focused 30 keV electron beam is used to excite localized surface plasmons that couple to collective resonant modes of the nanoresonators. We demonstrate unprecedented resolution of plasmonic mode excitation and by combining these observations with full-field simulations find that cathodoluminescence in plasmonic nanostructures is most efficiently excited at positions corresponding to antinodes in the modal electric field intensity. 相似文献