卧牛山煤矿组合支撑体系可靠性评估与加固维护技术研究

钢筋混凝土与砖砌体组合结构是我国20世纪中期建设的煤矿结构中的一种常用型式,随着服役年限的不断增加,越来越多的质量问题逐渐暴露。本文结合徐州卧牛山煤矿皮带廊支撑体系可靠性检测,分析该类结构的常见弊病,提供加固维护建议以供同类型结构参考。     

快速城镇化地区的城市设计探索

一、项目背景 城镇化是一个地区经济社会发展水平的重要标志,也是促进经济社会结构转型和现代化进程的重要手段。近年来,河北省城镇化进程快速推进,城镇体系不断完善,城镇经济的支撑作用日渐明显。但总体来看,城镇化水平仍然偏低,不仅落后于沿海发达省份,而且低于全国平均水平,成为影响河北省现代化进程的主要因素之一。     

环同济现代建筑设计产业创新集群支撑体系研究

立足于上海市环同济现代建筑设计产业集群的案例分析,根据波特的"钻石模型"理论,将创新集群的支撑体系演化成为三个主要组成部分,并对其结构与细部特征进行探讨。在此基础上,从集群支撑体系的视角,分析现阶段集群发展亟需突破的瓶颈,并从九个方面对政府未来的作为空间提出设想。     

Single‐Crystalline Dodecahedral and Octodecahedralα‐Fe2O3 Particles Synthesized by a Fluoride Anion–Assisted Hydrothermal Method

Despite significant advances in iron oxide nanoparticles, it is still a challenge to synthesize regular polyhedral single‐crystalline α‐Fe₂O₃ particles because the surface energies of several low‐index planes are fairly similar. In the work presented here, well‐dispersed and single‐crystalline dodecahedral and octodecahedral α‐Fe₂O₃ particles are synthesized by a facile hydrothermal method with the aid of F^? anions. The crystalline structure of the polyhedral particles is disclosed by various characterization techniques. The dodecahedral particles are of hexagonal bipyramidal shape and enclosed by twelve equivalent (101) planes. The octodecahedral particles are formed by adding six equivalent (111) planes on the two tips of a dodecahedral particle, that is, they are enclosed by twelve (101) planes and six (111) planes. The existence of F^? anions plays a crucial role in the control of polyhedral particle shape. The function of F^? anions in the shape formation of the polyhedral particles is proposed as follows: 1) A high concentration of exposed Fe³⁺ cations induces preferential adsorption of F^? anions on the (100) plane and leads to the slowest growth along the [100] direction. When the concentration of F^? anions is higher than 24 mM , a stable speed ratio of growth along the [001] and [100] directions results in the exposure of (101) planes. 2) With a lower concentration of F^? anions, six symmetrical (111) planes with low concentration of exposed Fe³⁺ cations are present at the tops of a dodecahedral particle to form an octodecahedron. Furthermore, the dodecahedral and octodecahedral α‐Fe₂O₃ particles show much stronger magnetism than the previously reported α‐Fe₂O₃ nanostructures, having coercivities of 4986 Oe and 6512 Oe, respectively. Such high coercivities are attributed to a large local magnetic anisotropy, which might be induced by the polyhedron with equivalent crystallographic planes and/or the presence of F^? anions.     

CC2431芯片在盲节点定位中的应用

CC2431是在CC2430之后推出的,带硬件定位引李的芯片,适合于各种ZigBee相关的无线网络节点.本文首先对盲节点的定位原理进行介绍,然后对CC2431芯片进行介绍并时其定位引李在盲节,4定位中的功能做出了相应的设计应用.     

物联网的由来与发展趋势

近来,物联网成为炙手可热的名词,许多人预言物联网将彻底改变人们的生活方式,带动万亿级的产业发展,成为信息化发展的新的推动力量。但是究竟什么是物联网,它离我们还有多远,仍是众说纷纭,见仁见智。本文试图通过分析物联网和互联网的关系,从人类现代信息化发展的历史角度,用结构化模型的方式,对物联网的概念给予辨析,并提出物联网的未来演进路径。     

Solvothermal synthesis and characterization of Pd–Rh alloy hollow nanosphere catalysts for formic acid oxidation

Pd–Rh alloy hollow nanospheres deposited on multiwalled carbon nanotubes (MWCNTs) were synthesized in our study. Initially, Cu nanoparticles were attached onto the MWCNT surface through solvothermal reaction, and then Pd-based alloy hollow nanospheres were formed using Cu nanoparticles as sacrificial template. Electrochemical activity and stability for the oxidation of formic acid were studied by cyclic voltammetry and chronoamperometry. The results reveal that the alloy hollow nanostructures have high electrochemical activity and good stability for the oxidation of formic acid, which might make them good candidates for direct formic acid fuel cells.     

聚氨酯/SiO_2复合材料的制备及性能研究

采用预聚体法以聚己二酸乙二醇酯二醇(PEA)、2,4-甲苯二异氰酸酯(TDI-100)和气相二氧化硅(SiO2)为原料,3,5-二甲硫基甲苯二胺(E-300)为扩链剂制备了聚氨酯/气相二氧化硅(PU/SiO2)复合材料,并利用SEM、电子万能试验机和DSC等手段对复合材料进行了分析与测试。结果表明,气相SiO2粒子在PU基体中分散良好;PU/SiO2复合材料比纯聚氨酯材料具有更优的耐撕裂性能和拉伸性能,耐热性能也提高。当气相SiO2的添加质量分数为3%时,复合材料的综合性能最好;且当扩链系数为0.80时,材料耐撕裂强度提高29.45%,拉伸强度提高33.74%。     

地下水连通介质结构分析——以寨底地下河系统实验基地示踪试验为例

对寨底地下河系统北部区域进行示踪试验,确认了北部区域的地下水分水岭边界。进一步对示踪试验数据进行详细分析,推测得到从投放点G06到排泄点G16、G20之间的地下水连通介质结构,其中G06～G16段以管道介质为主并发育一条支道和一个以上溶潭,G16～G20段含水介质则以裂隙为主。最后依据投放量、最大检测浓度等建立相对浓度系数概念,并用于分析比较G06至G16、G16至G20两段不同含水介质条件下的地下水流的径流集中程度。     

特殊地质区域海底隧道长期稳定性研究

根据F4风化槽强风化花岗岩的三轴流固耦合试验以及三轴流变试验成果,建立Mohr-Coulomb模型来描述风化槽岩石的弹塑性硬化及塑性流动行为,采用Nelder-Mead最优化方法得到力学模型各参数。应用三轴流变试验建立强风化花岗岩的非线性流变模型并拟合相关流变参数,在此基础上将流固耦合流变模型编制Creep子程序嵌入到ABAQUS软件。通过现场反演证明试验所得模型与参数可以很好地描述实际的情况。根据反演的围岩力学参数,模拟海底隧道F4风化槽段(ZK8+900m)隧道结构的长期稳定性,为海底隧道的设计和运营管理提供理论依据。