Ordered mesoporous Pd/SnO2 synthesized by a nanocasting route for high hydrogen sensing performance

Ordered mesoporous SnO₂ and mesoporous Pd/SnO₂ have been successfully synthesized via nanocasting method using the hexagonal mesoporous SBA-15 as template. Two different procedures, impregnation technique and direct synthesis, were utilized for the doping of Pd in the mesoporous SnO₂. The results of small angle X-ray diffraction (SAXD), nitrogen adsorption–desorption and transmission electron microscopy (TEM) demonstrate that the SnO₂ and Pd/SnO₂ display ordered mesoporous structures and high surface areas. Wide angle X-ray diffraction (WAXD) and X-ray photoelectron spectroscopy (XPS) reveal tetragonal structure of SnO₂ and the existence of Pd element. The sensing properties of mesoporous SnO₂ and mesoporous Pd/SnO₂ for H₂ were detected. The sensor utilizing mesoporous Pd/SnO₂ via direct synthesis method exhibits excellent response and recovery behavior and much higher sensitivity to H₂, compared to those using mesoporous SnO₂ and mesoporous Pd/SnO₂ via impregnation technique. It is believed that its high gas sensing performance is derived from the large surface area, high activity and well dispersion of Pd additive, as well as high porosity, which lead to highly effective surface interaction between the target gas molecules and the surface active sites.     

Microstructural topology optimization of structural-acoustic coupled systems for minimizing sound pressure level

The aim of this paper is to present a microstructural topology optimization methodology for the structural-acoustic coupled system. In the structural-acoustic system, the structure is considered to be a thin composite plate composed of periodic uniform microstructures. The discrete design variables are used in the microstructural topology optimization, and the constitutive matrix is interpolated by the power-law scheme at the micro scale. The equivalent macro material properties of the microstructure are computed through the homogenization method. The design objective is to minimize the sound pressure level (SPL) in an interior acoustic medium. The sensitivities of the SPL with respect to design variables are derived. The bi-directional evolutionary structural optimization (BESO) method is extended to solve the structural-acoustic coupled optimization problem to find the optimal material distribution of the microstructure. Numerical examples of a hexahedral box and an automobile passenger compartment are given to demonstrate the efficiency of the presented microstructural topology optimization method.     

Prediction of rank deficiency in partition of unity-based methods with plane triangular or quadrilateral meshes

In the partition of unity (PU)-based methods, the global approximation is built by multiplying a partition of unity by local approximations. Within this framework, high-order approximations are achieved by directly adopting high-order polynomials as local approximations, and therefore nodes along sides or inside elements, which are usually adopted in the conventional finite element methods, are no more required. However, the PU-based approximation constructed in this way may suffer from rank deficiency due to the linear dependence of the global degrees of freedom. In this paper, the origin of the rank deficiency in the PU-based approximation space is first dissected at an element level, and then an approach to predict the rank deficiency for a mesh is proposed together with the principle of the increase of rank deficiency. Finally, examples are investigated to validate the present approach. The current work indicates such a fact that the rank deficiency is an unrelated issue to the nullity of the global matrix. It can be resolved in its own manner.     

Broadband dielectric microwave microscopy on micron length scales

We demonstrate that a near-field microwave microscope based on a transmission line resonator allows imaging in a substantially wide range of frequencies, so that the microscope properties approach those of a spatially resolved impedance analyzer. In the case of an electric probe, the broadband imaging can be used in a direct fashion to separate contributions from capacitive and resistive properties of a sample at length scales on the order of one micron. Using a microwave near-field microscope based on a transmission line resonator we imaged the local dielectric properties of a focused ion beam milled structure on a high-dielectric-constant Ba(0.6)Sr(0.4)TiO(3) thin film in the frequency range from 1.3 to 17.4 GHz. The electrostatic approximation breaks down already at frequencies above approximately 10 GHz for the probe geometry used, and a full-wave analysis is necessary to obtain qualitative information from the images.     

Identification of Breast Cancer Prognosis Markers via Integrative Analysis

In breast cancer research, it is of great interest to identify genomic markers associated with prognosis. Multiple gene profiling studies have been conducted for such a purpose. Genomic markers identified from the analysis of single datasets often do not have satisfactory reproducibility. Among the multiple possible reasons, the most important one is the small sample sizes of individual studies. A cost-effective solution is to pool data from multiple comparable studies and conduct integrative analysis. In this study, we collect four breast cancer prognosis studies with gene expression measurements. We describe the relationship between prognosis and gene expressions using the accelerated failure time (AFT) models. We adopt a 2-norm group bridge penalization approach for marker identification. This integrative analysis approach can effectively identify markers with consistent effects across multiple datasets and naturally accommodate the heterogeneity among studies. Statistical and simulation studies demonstrate satisfactory performance of this approach. Breast cancer prognosis markers identified using this approach have sound biological implications and satisfactory prediction performance.     

The influence of oleic acid on the hydration and mechanical properties of portland cement

To investigate the effects of OA on the portland cement using oleic acid （OA） as grinding aid and the effects of OA on the portland cement, we characterized the different perfermances of the cement, discussed the characteristics of properties. The results reveal that the OA can reduce the water requirement of normal consistency. With the content of OA added, setting time was extended. The OA can significantly improve the rheological properties of cement-based materials, while the compressive strength decreases.