Gas atomization of cobalt ferrite-phosphate melts

A rapidly solidified (Co, Fe)₃O₄ spinel was formed in a cobalt-iron-phosphate glass matrix by gas atomization of melts of composition 37.5% mol % CoO, 37.5%Fe₂O₃, 25% P₂O₅; and 40% CoO, 40% Fe₂O₃, 20% P₂O₅, and the material has been characterized using size analysis, X-ray diffraction, Mössbauer spectroscopy, and scanning electron microscopy with energy dispersive X-ray spectroscopy.In the 20 mol % P₂O₅ composition, atomized powder 50–100m in diameter contained 33 wt % (Co, Fe)₃O₄. The ferrite crystallized as randomly oriented, faceted dendrites parallel to 100, and the growth was apparently diffusion controlled. Unlike the ferrite, where iron is in both tetrahedral and octahedral coordination, the iron in the glassy matrix was predominantly in distorted octahedral coordination. Overall particle size distributions were broad (15–700m), with 50 wt % smaller than 200m. The maximum in the size distribution shifted from 150 to 80m on increasing the atomizing pressure from 7 to 20 bar (100 to 300 psi). Calculations have shown that the cooling rates obtained with oxide melts vary strongly with droplet size, and less strongly with melt temperature.     

Null values in nested relational databases

Summary The desire to extend the applicability of the relational model beyond traditional data-processing applications has stimulated interest in nested or non-first normal form relations in which the attributes of a relation can take on values which are sets or even relations themselves. In this paper, we study the role of null values in the nested relational model using an open world assumption. We extend the traditional theory and study the properties of extended operators for nested relations containing nulls. The no-information, unknown, and non-existent interpretation of nulls are discussed and the meaning of empty set is clarified. Finally, contrary to several previous results, we determine that the traditional axiomatization of functional and multivalued dependencies is valid in the presence of nulls.Currently with the Air Force Institute of Technology, AFIT/ENG, Wright-Patterson AFB, OH 45433, USAResearch partially supported by an IBM Faculty Development A ward and NSF grant DCR-8507224     

Van der Pauw measurement of metal fibre orientation in a plastic-metal composite

Stainless steel fibres in ABS plastic form a composite with an anisotropic resistivity. Samples are rectangular shapes with uniform thickness. By assuming two principal resistivities and by using van der Pauw's technique, we find ² = _{x y} . For rectangular samples, field theory determines _y / _x and hence fibre direction. Results for three sample geometries agree with the theoretical predictions of the fibre patterns and with X-ray data. Samples formed by a centre-sprue feed are the best for fabricating large, uniform samples, while samples with a large length-to-width ratio have the most uniform metal density and fibre orientation. Resistivity was also measured by the more-common two-probe technique. Results correlate well to van der Pauw data, with 95% confidence.     

High-temperature properties of the Bi-Sr-Ca-Cu-O system: Simultaneous occurrence of melting, oxygen desorption, and a metal-insulator transition

We have investigated the temperature dependence of the electrical transport and the thermogravimetric properties, from -200°C to +1000, of the Bi-Sr-Ca-Cu-O high-temperature superconductor. We conclude that this system has a cooperative, simultaneous-melting/oxygen desorption/metal-insulator transition that occurs near 900°C. We speculate on its nature and on its relationship to phenomena found in other high-T _c superconductors.     

Plastic deformation in highly cross-linked rubber-modified epoxy resins

Plastic yielding behaviour of three different cross-link density rubber-modified epoxy resins, at different rubber levels and temperature, were investigated. All the systems studied show decrease in Young's modulus,E, and yield stress, _Y, with increasing temperature and rubber content. The deformation process was analysed using both Bowden and Argon theories. Molecular parameters from each. theory were then compared with chemical structures of the epoxy systems.     

Rapid software integration using structured methods

In this paper we discuss an approach to organizing the integration of 110,000 lines of C, SQL, Assembler, and microcode distributed over a network of 36 processors of four types so that it could be accomplished in six months. The software runs on a test system architecture consisting of a LAN-based workstation group and a set of VME-based embedded processors. By using structured methodology, parallelism in the integration process was achieved. The necessary stub tools were identified and developed before integration began. The principles followed and experiences of integrating the system are discussed.     

A boundary element method for two dimensional linear elastic fracture analysis

A boundary element method is developed for the analysis of fractures in two-dimensional solids. The solids are assumed to be linearly elastic and isotropic, and both bounded and unbounded domains are treated. The development of the boundary integral equations exploits (as usual) Somigliana's identity, but a special manipulation is carried out to regularize certain integrals associated with the crack line. The resulting integral equations consist of the conventional ordinary boundary terms and two additional terms which can be identified as a distribution of concentrated forces and a distribution of dislocations along each crack line. The strategy for establishing the integral equations is first outlined in terms of real variables, after which complex variable techniques are adopted for the detailed development. In the numerical implementation of the formulation, the ordinary boundary integrals are treated with standard boundary element techniques, while a novel numerical procedure is developed to treat the crack line integrals. The resulting numerical procedure is used to solve several sample problems for both embedded and surface-breaking cracks, and it is shown that the technique is both accurate and efficient. The utility of the method for simulating curvilinear crack propagation is also demonstrated.     

High-speed techniques for estimating t1, t2, and density images

This work presents methods for estimating relaxation times T1 and T2 and proton density using a real time digital video processor. This device performs each mathematical step of the fitting algorithms in one video frame interval (1/30 s). Two-point fits of T1 and T2 may be generated in approximately 15 video frame intervals or about 0.5 s; generation of a T2 image from four acquired images requires about 30 video frame intervals or about 1 s. The hardware is common to many commercial MR scanners and requires no array processor. Such high-speed techniques can expedite the clinical use of computed images and facilitate the implementation of image synthesis.     

Galvanic corrosion over a semi-infinite, planar surface

We derive the governing equations for the galvanic coupling of two dissimilar materials in a planar surface wherein the transport phenomena in the liquid phase are controlled by ionic migration or diffusion. The problem statement corresponds to two semi-infinite materials located in the same plane and coupled along a single boundary, resulting in a two-dimensional analysis. A single dimensionless group arises in the analyses of the corrosion problems, which greatly simplifies the presentation of numerical results and subsequent implementation. An example application of this work is presented that demonstrates how the results can be used to set requirements for protective films (e.g., paint) utilized for reducing corrosion rates.     

Role of Macrophages and RhoA Pathway in Atherosclerosis

The development, progression, or stabilization of the atherosclerotic plaque depends on the pro-inflammatory and anti-inflammatory macrophages. The influx of the macrophages and the regulation of macrophage phenotype, inflammatory or anti-inflammatory, are controlled by the small GTPase RhoA and its downstream effectors. Therefore, macrophages and the components of the RhoA pathway are attractive targets for anti-atherosclerotic therapies, which would inhibit macrophage influx and inflammatory phenotype, maintain an anti-inflammatory environment, and promote tissue remodeling and repair. Here, we discuss the recent findings on the role of macrophages and RhoA pathway in the atherosclerotic plaque formation and resolution and the novel therapeutic approaches.