The monitoring of synthetic dyes in foods is very important due to their potential harmfulness to human beings. Herein, a carbon-paste electrode (CPE) that is chemically modified with gold nanoparticles (nAu) was fabricated and used for the determination of Sunset yellow (SY) and Tartrazine (Tz). Cyclic and differential pulse voltammetry (CV and DPV) results revealed two well-resolved anodic peaks for SY and Tz with remarkably increase in oxidation signals of these colourants. Based on this, a novel electrochemical method was developed for the simultaneous determination of SY and Tz. High sensitivity and selectivity, sub-micromolar detection limit, high reproducibility and regeneration of the electrode surface by simple polishing make the nAu-CPE electrode very suitable for the determination of SY and Tz in commercially available soft drinks. The detection limits was 3.0 × 10−8 and 2.0 × 10−9 mol l−1 for SY and Tz, respectively, which are remarkably lower than those reported previously for SY and Tz using other modified electrodes. 相似文献
In this study, the impact of TiN as a sintering aid on the relative density and microstructure of TiB2 ceramic was investigated. Monolithic TiB2 and TiB2 doped with 5?wt% TiN were sintered at 1900?°C for 7?min dwell time under the pressure of 40?MPa by spark plasma. The addition of TiN affected the microstructure of TiB2-based sample considerably depicting the finer grains in the as-sintered ceramic. X-ray diffraction evaluation indicated that no interaction occurred between the initial materials. However, detail investigation by the map analysis and energy dispersive spectroscopy results revealed the formation of in-situ nano-sized hBN secondary phase in the TiN-doped TiB2. In addition, TiN played a remarkable role on increasing the relative density of TiN-doped TiB2 ceramic producing a nearly fully dense ceramic with relative density of 99.9% in comparison with the monolithic ceramic having 96.7% relative density. 相似文献
Since ZnO nanoparticles increase the electrical conductivity of the polypyrrole (PPy) coatings, an investigation was carried out to evaluate the effect of ZnO nanoparticles loading on the corrosion protection performance of PPy coatings on AA2024 Al alloy in 3.5% NaCl solution. At first, some measurements were carried out to find the best experimental conditions containing the electrodeposition method, electrosynthesis solvent composition, and ZnO nanoparticles’ concentration for preparing the optimum PPy coating on Al alloy2024. Three different methods of electrodeposition, namely: cyclic voltammetry, galvanostatic, and potentiostatic techniques were analyzed. The anti-corrosion performance of the PPy coatings was evaluated by electrochemical impedance spectroscopy and Tafel polarization methods. The PPy prepared by potentiostatic method exhibited the best performance against corrosion of Al alloy2024 in 3.5% NaCl solution. Then, different mixtures of H2O/ethanol were tested as electrosynthesis solvents for preparation of PPy coatings on the alloy by optimized electrodeposition mode (i.e., potentiostatic). In evaluation of the prepared coatings, the pure water was introduced as the optimum solvent in electrodeposition of PPy. The investigation of different ZnO nanoparticles’ concentrations proved that the PPy coating containing 0.025% ZnO nanoparticles was the optimum coating against the corrosion of Al alloy in NaCl solution. Finally, the long-term evaluation of the corrosion protection performance of the coatings revealed that the optimum coating provided suitable protection against corrosion up to 14 days after immersion.
Today's strict environmental laws pose significant challenges for coating's formulators to look for eco-friendly products. Powder coatings, particularly polyester/epoxy blends have demonstrated their ability as alternatives to traditional solvent-borne coatings. Recently, the use of nanoparticles such as nano-CaCO3 (nCaCO3) has been suggested as a beneficial strategy towards powder coating application with improved properties. Here, we study the effect of nCaCO3 on morphology, cure behavior, adhesion and hardness of polyester/epoxy systems. The nanoparticles shape, size and dispersion state were investigated through X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) methods. Furthermore, isothermal cure characterization of the neat and filled systems was performed using a torque rheometer. The most important finding based on the rheological studies was the catalytic effect of nCaCO3 on cure reaction of polyester/epoxy, leading to the shorter curing time. Moreover, the kinetic analyses of rheograms revealed a marked decrease in the activation energy of the cure process upon raising nCaCO3 content. Interestingly, pull-off adhesion and hardness tests showed that the hardness and adhesion strength were dramatically increased by the addition of nCaCO3 into the polyester/epoxy system compared to pure blend resin. Therefore, considering the strong competition in powder coating market, the use of nCaCO3 as a commercial and inexpensive nanofiller is necessary not only to reduce the dwell time which has benefits in terms of the energy consumption and economics, but also to improve the performance of final polyester/epoxy coating. 相似文献
Methylaluminoxane (MAO)-activated chromium (III) complexes of tridentate SNS ligands of the form (RSCH2–CH2)2NH (R = alkyl, aryl) have been prepared and tested for the trimerization of ethylene to 1-hexene. The effect of ethylene pressure,
Al/Cr ratio and S donor substitution on 1-C6 selectivity and productivity has been examined. It is shown that when the substitution
on S is pentyl group it will lead to the highest productivity, 174200 g 1-C6/g Cr h, due to the synergistic effect of this
group. 相似文献
A highly deacetylated (97.5%) chitosan in 50% acetic acid was electrospun at moderate temperatures (25-70 °C) in the presence of a low content of polyethylene oxide (10 wt% PEO) to beadless nanofibers of 60-80 nm in diameter. A systematic quantitative analysis of the solution properties such as surface tension, conductivity, viscosity and acid concentration was conducted in order to shed light on the electrospinnability of this polysaccharide. Rheological properties of chitosan and PEO solutions were studied in order to explain how PEO improves the electrospinnability of chitosan. Positive charges on the chitosan molecule and its chain stiffness were considered as the main limiting factors for electrospinability of neat chitosan as compared to PEO, since surface tension and viscosity of the respective solutions were similar. Various blends of chitosan and PEO solutions with different component ratios were prepared (for 4 wt% total polymer content). A significant positive deviation from the additivity rule in the zero shear viscosity of chitosan/PEO blends was observed and believed to be a proof for strong hydrogen bonding between chitosan and PEO chains, making their blends electrospinnable. The impact of temperature and blend composition on the morphology and diameter of electrospun fibers was also investigated. Electrospinning at moderate temperatures (40-70 °C) helped to obtain beadless nanofibers with higher chitosan content. Additionally, it was found that higher chitosan content in the precursor blends led to thinner nanofibers. Increasing chitosan/PEO ratio from 50/50 to 90/10 led to a diameter reduction from 123 to 63 nm. Producing defect free nanofibrous mats from the electrospinning process and with high chitosan content is particularly promising for antibacterial film packaging and filtration applications. 相似文献
In this investigation, a theoretical study is performed to analyze the dynamic behavior of particles across flame propagation through a two-phase mixture consisting of micro-iron particles and air. In the first step for calculation of the particle velocity profile, the Lagrangian approach of particle motion is employed, and then thermophoretic, gravitational and buoyancy forces are taken into consideration. In order to simulate the temperature profile for the thermophoretic force, it is assumed that the flame structure consists of three zones: preheat, reaction, and post flame (burned). It should be noted that the radiative heat-transfer equation is employed to describe the thermal radiation exchanged between the burned zone and the preheat zone. In the resumption, a control volume above the leading edge of the combustion zone is considered and the change in the particle number density in this volume is obtained via the balance of particle mass fluxes passing through it. The results show that the induced thermal radiation plays a significant role in increasing the mixture temperature all over the preheat zone, and that the particle velocity profile and the concentration distribution of particles as a function of distance from the leading edge of the combustion zone also have considerable consistency with published experimental data. 相似文献