Recently, (Ga1-xZnx)(N1-xOx) has gained widespread attention as a comparatively high efficiency photocatalyst for visible-light-driven overall water splitting. Despite significant gains in efficiency over the past several years, a majority of the photogenerated carriers recombine within bulk powders. To improve the photocatalytic activity, we used an epitaxial casting method to synthesize single-crystalline, high surface area (Ga1-xZnx)(N1-xOx) nanotubes with ZnO compositions up to x=0.10. Individual nanotubes showed improved homogeneity over powder samples due to a well defined epitaxial interface for ZnO diffusion into GaN. Absorption measurements showed that the ZnO incorporation shifts the absorption into the visible region with a tail out to 500 nm. Gas chromatography (GC) was used to compare the solar water splitting activity of (Ga1-xZnx)(N1-xOx) nanotubes (x=0.05–0.10) with similar composition powders. Cocatalyst decorated samples were dispersed in aqueous solutions of CH3OH and AgO2CCH3 to monitor the H+ reduction and H2O oxidation half reactions, respectively. The nanotubes were found to have approximately 1.5–2 times higher photocatalytic activity than similar composition powders for the rate limiting H+ reduction half reaction. These results demonstrate that improvements in homogeneity and surface area using the nanotube geometry can enhance the photocatalytic activity of GaN:ZnO for solar water splitting. 相似文献
The remote West Australian town of Broome has a unique photography heritage that sheds new light on the complexities of photography and intercultural relations. During the early twentieth century thriving Japanese communities were established in this region around the lucrative pearling industry. These Japanese communities also helped to develop a fascinating photography culture in Broome. Photography was not simply a business opportunity for the Japanese or a means of documenting people and events; it was a medium through which hierarchised social relations were produced, redefined, and challenged. This article examines photographs by these Japanese residents as an important site of cross-cultural communication and interpretation. These photographs of Anglo-Australian, Japanese, and Aboriginal residents of Broome enrich the study of cross-cultural photographic encounters, and emphasise the dynamic and dispersed qualities of Australian photographic practice and history. Here national histories of photography are usefully conceptualised as the products of imbricated social, economic, and cultural relations that operate across regional, national, and international realms. 相似文献
Electricity consumption is influenced by number of adults and children and their relationship at household level. Household income also plays a critical role on expenditure on electricity. Accordingly, this article presents a joint probability model of electricity demand based on occupants’ age grades and household income levels. A bottom-up strategy is developed using a micro level database of 70 Australian households. A neural regression-generalization technique is devised to estimate electricity demand using back-propagation and cognitive mapping. The aggregated result is then validated against 2012 Australian national census. Accordingly, the model is improved based on a top-down review. The results show per capita electricity demand by adult and child at 0.408 kW (69 kWh/week) and 0.226 kW (38 kWh/week), respectively. The equivalent dollar values are $13.6/week and $7.6/week in 2012. At macro level, the model reveals per capita demand by all individuals at 0.324 kW (54.35 kWh/week) equivalent to dollar value of $10.87/week, across Australia. The results also show higher percentage of per capita demand for adults in high and medium income classes, and the otherwise for low income class. Ratio of child’s demand over adult’s demand is highest among the low income households, and lowset among the middle income households, while best balance between adult and child per capita demand belongs to the high income.
We report on the effect of gold nanoparticle (Au NP) dispersion in a chiral nematic liquid crystal (LC). Polarized optical microscopy and X-ray diffraction measurements evidence the insurgence of an order change in the LC host. Moreover, a comparative analysis based on dielectric and voltammetric spectroscopies performed on pure LC and on Au NP-doped LC shows that Au NP’s presence besides affecting LC order influences its electric properties: ion conductivity results importantly reduced, and beyond a threshold value of the applied field electrophoresis phenomena are induced. 相似文献
For the past several decades, pipeline incidents have resulted in highly publicized accounts of property damage, environmental harm, neighborhood destruction, serious injury, and death. 相似文献
Two obligate intracellular parasites, Trypanosoma cruzi, the agent of Chagas disease, and Toxoplasma gondii, an agent of toxoplasmosis, upregulate the mevalonate pathway of their host cells upon infection, which suggests that this host pathway could be a potential drug target. In this work, a number of compounds structurally related to WC‐9 (4‐phenoxyphenoxyethyl thiocyanate), a known squalene synthase inhibitor, were designed, synthesized, and evaluated for their effect on T. cruzi and T. gondii growth in tissue culture cells. Two fluorine‐containing derivatives, the 3‐(3‐fluorophenoxy)‐ and 3‐(4‐fluorophenoxy)phenoxyethyl thiocyanates, exhibited half‐maximal effective concentration (EC50) values of 1.6 and 4.9 μm , respectively, against tachyzoites of T. gondii, whereas they showed similar potency to WC‐9 against intracellular T. cruzi (EC50 values of 5.4 and 5.7 μm , respectively). In addition, 2‐[3‐ (phenoxy)phenoxyethylthio]ethyl‐1,1‐bisphosphonate, which is a hybrid inhibitor containing 3‐phenoxyphenoxy and bisphosphonate groups, has activity against T. gondii proliferation at sub‐micromolar levels (EC50=0.7 μm ), which suggests a combined inhibitory effect of the two functional groups. 相似文献
In the Na+/taurocholate cotransporting polypeptide (NTCP), the clinically relevant S267F polymorphism occurs at a “rheostat position”. That is, amino acid substitutions at this position (“S267X”) lead to a wide range of functional outcomes. This result was particularly striking because molecular models predicted the S267X side chains are buried, and thus, usually expected to be less tolerant of substitutions. To assess whether structural tolerance to buried substitutions is widespread in NTCP, here we used Rosetta to model all 19 potential substitutions at another 13 buried positions. Again, only subtle changes in the calculated stabilities and structures were predicted. Calculations were experimentally validated for 19 variants at codon 271 (“N271X”). Results showed near wildtype expression and rheostatic modulation of substrate transport, implicating N271 as a rheostat position. Notably, each N271X substitution showed a similar effect on the transport of three different substrates and thus did not alter substrate specificity. This differs from S267X, which altered both transport kinetics and specificity. As both transport and specificity may change during protein evolution, the recognition of such rheostat positions may be important for evolutionary studies. We further propose that the presence of rheostat positions is facilitated by local plasticity within the protein structure. Finally, we note that identifying rheostat positions may advance efforts to predict new biomedically relevant missense variants in NTCP and other membrane transport proteins. 相似文献
This study investigates the components of a constant injection rate resin transfer molding system and discusses critical issues of each component from an experimental view. Also included are temperature and pressure data of independently designed mold flow experiments performed at The Dow Chemical Company. The experiments in this study included isothermal one-dimensional flow with line gating and end venting, isothermal two-dimensional flow with converging flow and center venting, and two different resin systems. Accurate and precise permeability measurements of the fiber preform continue to be the core of the issue. Deformation, contour, or overlap of the fiber preform can cause minor variation in local permeability, which, when compared with the bulk permeability, can vary the injection pressures up to an order of magnitude. Further, local dimensional changes in the fiber preform (i.e., overlap, contour, or edge-effect) can form a channel for racetracking of the resin during injection. The inability to accurately predict a priori the extent of racetracking reduces modeling efforts to a demonstration of the flow trend. 相似文献