应力与电子辐照耦合下透明聚酰亚胺的制备与性能

以4,4’-[1,4-苯基双(氧)]双[3-(三氟甲基)苯胺]、六氟二酐作为单体,通过掺杂的方法引入 1-乙基-3-甲基咪唑双三氟甲基磺酰亚胺离子液体,采用一步法高温缩聚法制备了一种透明聚酰亚胺材料。这类透明聚酰亚胺薄膜具有优异的光学、机械和热学性能,其截止波长低于 320 纳米,500 纳米的透光率为 89.4 %;拉伸强度为 81.5 兆帕,断裂伸长率为 105 %,弹性模量为 1818 兆帕;初始热分解温度为 407 摄氏度。具有拉伸形变的透明聚酰亚胺薄膜在能量为 1 MeV,注量为 2×10¹⁴ cm^-2、2×10¹⁵ cm^-2、1×10¹⁶ cm^-2的电子辐照下,在 500 纳米处的透光率下降率均不超过 10 %,在空间光学器件领域具有潜在的应用前景。     

Discovery of Five New Ethylene-Forming Enzymes for Clean Production of Ethylene in E. coli

Ethylene is an essential platform chemical with a conjugated double bond, which can produce many secondary chemical products through copolymerisation. At present, ethylene production is mainly from petroleum fractionation and cracking, which are unsustainable in the long term, and harmful to our environment. Therefore, a hot research field is seeking a cleaner method for ethylene production. Based on the model ethylene-forming enzyme (Efe) {"type":"entrez-protein","attrs":{"text":"AAD16440.1","term_id":"4323597","term_text":"AAD16440.1"}}AAD16440.1 (6vp4.1.A) from Pseudomonas syringae pv. phaseolicol, we evaluated five putative Efe protein sequences using the data derived from phylogenetic analyses and the conservation of their catalytic structures. Then, pBAD expression frameworks were constructed, and relevant enzymes were expressed in E. coli BL21. Finally, enzymatic activity in vitro and in vivo was detected to demonstrate their catalytic activity. Our results show that the activity in vitro measured by the conversion of α-ketoglutarate was from 0.21–0.72 μmol ethylene/mg/min, which varied across the temperatures. In cells, the activity of the new Efes was 12.28–147.43 μmol/gDCW/h (DCW, dry cellular weight). Both results prove that all the five putative Efes could produce ethylene.     

Improving Lipid Production of Yarrowia lipolytica by the Aldehyde Dehydrogenase-Mediated Furfural Detoxification

Yarrowia lipolytica, the non-conventional yeast capable of high lipogenesis, is a microbial chassis for producing lipid-based biofuels and chemicals from renewable resources such as lignocellulosic biomass. However, the low tolerance of Y. lipolytica against furfural, a major inhibitory furan aldehyde derived from the pretreatment processes of lignocellulosic biomass, has restricted the efficient conversion of lignocellulosic hydrolysates. In this study, the furfural tolerance of Y. lipolytica has been improved by supporting its endogenous detoxification mechanism. Specifically, the endogenous genes encoding the aldehyde dehydrogenase family proteins were overexpressed in Y. lipolytica to support the conversion of furfural to furoic acid. Among them, YALI0E15400p (FALDH2) has shown the highest conversion rate of furfural to furoic acid and resulted in two-fold increased cell growth and lipid production in the presence of 0.4 g/L of furfural. To our knowledge, this is the first report to identify the native furfural detoxification mechanism and increase furfural resistance through rational engineering in Y. lipolytica. Overall, these results will improve the potential of Y. lipolytica to produce lipids and other value-added chemicals from a carbon-neutral feedstock of lignocellulosic biomass.     

汽车悬架用弹簧钢55SiCr制备技术的研究进展

悬架弹簧钢是汽车悬架系统的重要部件,研发高性能汽车悬架弹簧钢制备技术对于推动特殊钢材料的国产化有着重要的意义。从洁净度控制、组织性能调控和表面脱碳控制3个方面介绍近年来汽车悬架弹簧钢55SiCr制备技术的最新进展。在洁净度控制上,对弹簧钢中夹杂物的控制方向、脱氧工艺、精炼渣和耐火材料等相关研究进行介绍。在组织性能调控中,重点介绍作者所在研究所在悬架弹簧钢55SiCr热处理工艺改进与优化上的探索,比较了淬火-回火、等温淬火和淬火-配分工艺对悬架弹簧钢55SiCr力学性能的影响。表面脱碳控制的相关研究表明,在进行热处理或热加工的过程中,应尽量避免在低于弹簧钢奥氏体/铁素体转变温度(约800℃)附近停留,虽然较高的温度有利于避免全脱碳,但是出于晶粒粗化、能耗和氧化等方面的考虑,热处理温度不宜高于1 100℃。     

一种gshare分支预测器的低功耗设计方法

功耗与性能在高端嵌入武计算系统中都是非常重要的设计指标。基于深度流水处理器中所使用的动态分支预测器的微结构特点，提出了一种利用分页技术来有效的降低gshare分支预测器的功耗的设计方法，详细分析了分支预测器的大小、分页数以及功耗、面积之间的内在关系。     

集成在ERP采购管理中的数据挖掘技术

设计实现一个可扩展的、开放的集成在ERP采购管理系统中的数据挖掘系统.采用DM与DB/DW紧耦合方式构建,使用基于约束的交互式数据挖掘技术,将计算模型和工具分离,通过人机界面和知识推理接受用户决策需求并输出决策结果.     

基于简化CKF/降维CKF混合滤波的非线性对准技术研究?

为了降低非线性对准的计算量而不损失对准精度,针对容积卡尔曼滤波( CKF)采样点数与状态维数成正比、计算量较大的问题,提出了基于简化CKF/降维CKF混合滤波的非线性对准方法。利用大失准角模型和基于线性观测方程的简化CKF算法进行水平对准;使用大方位失准角模型和降维CKF完成精对准。仿真结果表明,该方法摆脱了CKF算法的“维数灾难”和降维CKF对准应用条件限制,能够完成任意失准角下的初始对准并获得较高对准精度,具有重要的工程应用价值。     

基于相似性分析的电子装备可靠性定量评估模型

基于影响相似产品可靠性的主要因素,应用AHP方法建立相似产品的可靠性量化模型。其利用相似产品的可靠性数据进行可靠性评估通过收集相似产品可用的寿命数据和特征数据、分析相似产品的主要失效模式和失效机理、对新旧产品的性能和特性进行对比并建立新旧产品的相似性对比矩阵,以及确定新产品可靠性等步骤实现。     

基于地磁传感器的引信自测初速技术研究

计时定距线膛炮武器系统测速方法大多采用炮口测速线圈,但存在系统复杂、成本高、易干扰感应装定信号等不足。为此,提出将现已成熟的地磁传感器技术引入引信设计中,在弹丸出炮口后效期后,由地磁传感器多次测量弹丸旋转周期,通过引信电路内置单片机及超高速A/D进行信号采集、数据处理及弹道解算等操作,将弹丸平均旋转周期换算为实际初速。采用上述原理可在简化武器系统的同时,降低对现役防空武器系统的技术改造难度及成本。     

"操控杆"的非线性化研究

为了解决"操控杆"这一类线性部件应用于控制领域时所存在的缺陷,而将其非线性化,并就非线性化过程中所产生的问题进行分析并解决,使其具有工程实用性.