A Thienothiophene-Based Cation Treatment Allows Semitransparent Perovskite Solar Cells with Improved Efficiency and Stability

Perovskite surface treatment with additives has been reported to improve charge extraction, stability, and/or surface passivation. In this study, treatment of a 3D perovskite ((FAPbI₃)_1−x(MAPbBr₃)_x) layer with a thienothiophene-based organic cation (TTMAI), synthesized in this work, is investigated. Detailed analyses reveal that a 2D (n = 1) or quasi-2D layer does not form on the PbI₂-rich surface 3D perovskite. TTMAI-treated 3D perovskite solar cells (PSCs) fabricated in this study show improved fill factors, providing an increase in their power conversion efficiencies (PCEs) from 17% to over 20%. It is demonstrated that the enhancement is due to better hole extraction by drift-diffusion simulations. Furthermore, thanks to the hydrophobic nature of the TTMAI, PSC maintains 82% of its initial PCE under 15% humidity for over 380 h (the reference retains 38%). Additionally, semitransparent cells are demonstrated reaching 17.9% PCE with treated 3D perovskite, which is one of the highest reported efficiencies for double cationic 3D perovskites. Moreover, the semitransparent 3D PSC (TTMAI-treated) maintains 87% of its initial efficiency for six weeks (>1000 h) when kept in the dark at room temperature. These results clearly show that this study fills a critical void in perovskite research where highly efficient and stable semitransparent perovskite solar cells are scarce.     

Recent advances in plant-based compounds for mitigation of mycotoxin contamination in food products: current status,challenges and perspectives

There are numerous strategies to control the growth of mycotoxigenic fungi and reduce mycotoxins in food, including physical, chemical and biological treatments. However, consumers prefer organic food and natural inhibitors because they are biodegradable and safe for human and animal health. This review summarises the current advances in plant-based compounds to mitigate contamination of food products by mycotoxigenic fungi and their toxins. In addition, a clear understanding of the roles of plant-based extracts in food products, their mechanisms of action and challenges and perspectives in mycotoxin degradation are presented. Essential oils and plant-based extracts are complex mixtures of major and minor chemical compounds with antimicrobial and antioxidant properties. In general, the mechanisms of antifungal activity of plant-based compounds are attributed to the reduction of the ergosterol content, disruption of cell membrane integrity, enhancing of membrane ion leakage and permeability, disruption to the organisation of mitochondrial structure, interference in enzymatic reactions of cell wall synthesis, disturbance of oxidative balance, inhibition of carbohydrate metabolism, suppression of mycotoxin biosynthetic genes and alterations in the molecular structure of mycotoxins.     

Advances and Perspectives in Tissue Culture and Genetic Engineering of Cannabis

For a long time, Cannabis sativa has been used for therapeutic and industrial purposes. Due to its increasing demand in medicine, recreation, and industry, there is a dire need to apply new biotechnological tools to introduce new genotypes with desirable traits and enhanced secondary metabolite production. Micropropagation, conservation, cell suspension culture, hairy root culture, polyploidy manipulation, and Agrobacterium-mediated gene transformation have been studied and used in cannabis. However, some obstacles such as the low rate of transgenic plant regeneration and low efficiency of secondary metabolite production in hairy root culture and cell suspension culture have restricted the application of these approaches in cannabis. In the current review, in vitro culture and genetic engineering methods in cannabis along with other promising techniques such as morphogenic genes, new computational approaches, clustered regularly interspaced short palindromic repeats (CRISPR), CRISPR/Cas9-equipped Agrobacterium-mediated genome editing, and hairy root culture, that can help improve gene transformation and plant regeneration, as well as enhance secondary metabolite production, have been highlighted and discussed.     

Optimization of mechanical properties of in situ polymerized poly(methyl methacrylate)/alumina nanoparticles nanocomposites using Taguchi approach

Polymer Bulletin - Alumina nanoparticles are among important metal oxides with specific properties but chemically incompatible with an organic matrix such as poly(methyl methacrylate) (PMMA). In...     

FIVE-SPOT INJECTION/PRODUCTION WELL LOCATION DESIGN BASED ON FRACTURE GEOMETRICAL CHARACTERISTICS IN HEAVY OIL FRACTURED RESERVOIRS DURING MISCIBLE DISPLACEMENT: AN EXPERIMENTAL APPROACH

Mapping fracture characteristics by using seismic acquisition and processing is important not only to identify sweet spots, but also to optimize production, especially for unconventional heavy oil reservoirs. In this experimental work we used five-spot micromodels initially saturated with heavy oil to find the optimum well locations during first-contact miscible displacement. The experiments were performed at a fixed injection rate on fractured micromodels with various patterns. The optimum location for injection/production wells was found in the pattern where fractures make an angle of 45° with the mean flow direction. Moreover, oil recovery was increased with the density, length, level of scattering, and discontinuity of fractures. The analysis of the experimentally measured recovery curve revealed that there are three distinct stages for each displacement. The efficiency of the first stage was found to be dominated by dispersion and diffusion. However, the recovery of the second stage was significantly affected by the fracture orientation. The displacement efficiency of the third stage was controlled by solvent dispersion, which is at maximum for the pattern with higher density, length, scattering, and discontinuity of fractures. Saturation monitoring showed that the fracture geometrical characteristics strongly affected the splitting, spreading, and shielding of the produced fingers and solvent front shape and consequently affected the recovery factor. As a result, five-spot micromodels can be used to investigate the optimum location of injection/production wells during miscible displacements in fractured heavy oil reservoirs.     

Effect of chemical solvents on the technological characteristics of hemp fibre/polypropylene composites

The effects of different chemical solvents on the technological properties of hemp fibre-reinforced polypropylene composites were evaluated in this experimental work. Composite profiles consisting of hemp fibre and polypropylene at 50% weight ratios, with 2% of coupling agent were fabricated using melt compounding followed by injection moulding. The composite specimens were then immersed in CH₃COOH, HNO₃, H₂SO₄, NaOH, NH₃, and C₆H₅NH₂ for different time intervals. Then, the weight loss and mechanical strength of samples were measured. Results indicated that the chemical reagents had significant effect on the weight loss of the composites. The weight loss ratio of the control samples was lower than that of those samples exposure to the chemical solvents. The tensile strength and modulus, and impact strength of composite specimens decreased after exposure to the chemical solvents. The highest mechanical reduction was observed in the case of NaOH. SEM micrographs showed that the extent of degradation increased in composites when they are exposed to chemical solvents.     

Multi-Stimuli Dually-Responsive Intelligent Woven Structures with Local Programmability for Biomimetic Applications

This work focuses on multi-stimuli-responsive materials with distinctive abilities, that is, color-changing and shape-memory. Using metallic composite yarns and polymeric/thermochromic microcapsule composite fibers, processed via a melt-spinning technique, an electrothermally multi-responsive fabric is woven. The resulting smart-fabric transfers from a predefined structure to an original shape while changing color upon heating or applying an electric field, making it appealing for advanced applications. The shape-memory and color-changing features of the fabric can be controlled by rationally controlling the micro-scale design of the individual fibers in the structure. Thus, the fibers’ microstructural features are optimized to achieve excellent color-changing behavior along with shape fixity and recovery ratios of 99.95% and 79.2%, respectively. More importantly, the fabric's dual-response by electric field can be achieved by a low voltage of 5 V, which is smaller than the previously reported values. Above and beyond, the fabric is able to be meticulously activated by selectively applying a controlled voltage to any part of the fabric. The precise local responsiveness can be bestowed upon the fabric by readily controlling its macro-scale design. A biomimetic dragonfly with the shape-memory and color-changing dual-response ability is successfully fabricated, broadening the design and fabrication horizon of groundbreaking smart materials with multiple functions.