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71.
Catalytic Hydrocracking of a Bitumen‐Derived Asphaltene over NiMo/γ‐Al2O3 at Various Temperatures
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Hydrocracking of a bitumen‐derived asphaltene over NiMo/γ‐Al2O3 was investigated in a microbatch reactor at varying temperatures. The molar kinetics of asphaltene cracking reaction was examined by fitting the experimental data. Below a defined temperature, the molar reaction showed the first‐order kinetic feature while at higher temperatures secondary reactions such as coke formation became significant, causing deviation of the reaction behavior from the proposed first‐order kinetic model. Selectivity analysis proved that dominant products varied from gases to liquids to gases with increasing temperature, shifting the dominant reaction from C–S bonds cleavage to C–C bonds cleavage. 相似文献
72.
73.
Wang Qibin Zhao Bo Ma Hongbo Chang Jiantao Mao Gang 《Journal of Mechanical Science and Technology》2019,33(6):2561-2571
Journal of Mechanical Science and Technology - Real-time monitoring and rapid evaluation of bearing operating conditions, especially for the reliability evaluation and remaining useful life (RUL)... 相似文献
74.
Maimaitiaili Tayier Yunfeng Zhao Dengle Duan Rongge Zou Yunpu Wang Roger Ruan 《木材化学与工艺学杂志》2020,40(3):190-199
AbstractLignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the SBET, Vt, and Vmec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni2+ or Fe3+). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%. 相似文献
75.
76.
Mohan B. Ponnuchamy G. Mohan Muralikrishna Venkateswara Rao Mannava G. Srinivas Reddy 《Ceramics International》2018,44(13):15019-15023
Nanocrystalline nickel oxide (NiO) was prepared from nickel hydroxide by Spark plasma sintering (SPS) and the mechanisms involved in the densification of NiO were studied. Reverse precipitated nickel hydroxide powders were SPS processed at 400, 600 and 700?°C with 70?MPa pressure. Pure NiO with 12?nm crystallite size formed after 400?°C sintering process. However NiO grains had grown to 18 and 38?nm after 600 and 700?°C sintering respectively. NiO pellets prepared using 600 and 700?°C SPS sintering schedules had relative densities of 83% and 94% respectively. Two displacement rate regimes were observed during densification of NiO in both 600 and 700?°C sintering processes. Decomposition of nickel hydroxide and particle sliding of NiO led to first displacement rate maximum while inverse Hall-Petch based plastic deformation facilitated densification during the constant second displacement rate regime. No densification occurred during sintering holding times indicating the limited role that diffusion played during densification. 相似文献
77.
Li Lei Limin Li Shasha Wang Gaoyang Zhao Yoshifumi Oshima Yang Ren Lei Zhao Lihua Jin Yao Wang Chengshan Li Pingxiang Zhang 《Journal of the European Ceramic Society》2018,38(14):4694-4700
Highly (100)-oriented Ce1-x(Y0.2Zr0.8)xOδ (CYZO) films were prepared on biaxially textured NiW substrates by a chemical solution deposition approach using metal inorganic salts as starting materials. It has been found that both the preferential orientation and surface roughness of CYZO films decrease gradually with increasing of the doping percentage of Y3+ and Zr4+ ions. The epitaxial growth relationship of (220)CYZO//(200)NiW and [00?l]CYZO//[001]NiW was demonstrated by XRD texture measurement as well as atomic resolution STEM observation. XRD, Raman and XPS spectra results indicate that Y3+ and Zr4+ ions were indeed introduced into CeO2 lattice to substitute Ce4+ ions and form cubic fluorite CYZO solid solution. Moreover, CeO2 buffer layer can be endowed a strong enough capability to prevent element diffusion through co-doping of yttrium and zirconium, provided that an optimal doping ratio of them is adopted. This will provide a new approach to fabricating strong-barrier single buffer layer for coated conductor. 相似文献
78.
The cracks in the workpiece specimens can reduce the fatigue life of any machine components. Since the residual stress has a considerable amount of influence on determining crack formation over the machined surface, it is very essential to analyze the residual stress developed in any machining process. However, it is a very tedious process to compute the residual stress over the machined surface. In the present study, an endeavor has been made to measure and analyze the residual stress of machined silicon steel as a workpiece using the EDM process with different energy distribution. The nano-indentation method was used to compute the residual stress produced over the machined surface. From the experimental results, it was found that the uniform energy distribution has produced higher compressive residual stress owing to the tiny and uniform spark energy distribution. It has also been observed that the tool electrode has a considerable amount of influence on determining development of residual stress in the EDM process. 相似文献
79.
Research funding has been seen as one of the most important resource in the reward system of science. And usage of publications denotes an interesting perspective of user behavior in scientific communication. This study aims to address the relationship between funding and Usage Count, which is a new metrics item established on the platform of Web of Science. Full records of 300,010 articles published in 2013 were downloaded in October 2015, and divided into six disciplines, including information science library science, education educational research, economics, computer science, materials science, and chemistry. Seven indicators were proposed to measure the impact, including Funding rate, Citation per paper, Usage rate, Usage per paper, Citation difference, Usage difference, and Conversion rate. It concluded funding has impact on usage and citation, and funded papers attract more usage, but varying in different disciplines. Usage Count can be used in the extension of citation metrics but with limits. This study originally engages with usage metrics and detected that there is positive correlation between usage and funding. 相似文献
80.
To minimize the mass and increase the bearing failure load of composite doublelap bolted joints, a three-step optimization strategy including feasible region reduction,
optimization model decoupling and optimization was presented. In feasible region
reduction, the dimensions of the feasible design region were reduced by selecting dominant
design variables from numerous multilevel parameters by sensitivity analyses, and the
feasible regions of variables were reduced by influence mechanism analyses. In model
decoupling, the optimization model with a large number of variables was divided into
various sub-models with fewer variables by variance analysis. In the third step, the
optimization sub-models were solved one by one using a genetic algorithm, and the
modified characteristic curve method was adopted as the failure prediction method. Based
on the proposed optimization method, optimization of a double-lap single-bolt joint was
performed using the ANSYS® code. The results show that the bearing failure load increased
by 13.5% and that the mass decreased by 8.7% compared with those of the initial design of
the joint, which validated the effectiveness of the three-step optimization strategy. 相似文献