Etching behavior of CVD zinc selenide in inorganic acid solutions

Chemical interaction between polished surfaces of polycrystalline zinc selenide and inorganic acid solutions of various concentrations has been studied.     

Micromechanism of corrosion fracture of the plates of heat exchangers

We have studied the micromechanism of corrosion fracture of heat-transfer plates of a heat exchanger. The operation of heat exchangers under conditions of contamination of the plates with a sediment from water leads to their local corrosion under the sediment. The conditions of operation of the heat exchangers being equal, heat-transfer plates made of AiSi316Ti steel worked 2.36 times as long as those of AiSi304L steel. The corrosion fracture of plates under the sediment began from pitting initiation near nonmetallic inclusions of a certain nature. Afterwards, these pittings built up into corrosion spots by the mechanism of stress corrosion and hydrogen embrittlement. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 1, pp. 110–116, January–February, 2007.     

A New Generation of Magnetic Roll Separators Based on Rare-Earth Magnets for Concentration and Purification of Weakly Magnetic Materials

Magnetic roll separators on rare-earth magnets are suitable for removing iron impurities from various materials. The advantages of these magnetic separators over traditional ones are demonstrated. __________ Translated from Steklo i Keramika, No. 5, p. 33, May, 2005.     

Refractory Ceramics Based on Local Materials

A technology for producing ShA and ShB refractories uses high-melting clays from the Rostov Region and high-alumina technogenic waste. The effect of the chamotte-to-clay ratio, the granulometric composition, and the additive introduction method on the properties of products is investigated.__________Translated from Steklo i Keramika, No. 1, pp. 15 – 16, January, 2005.     

Synthesis,characterization and properties of functionalized styrene–maleimide copolymers

New functionalized styrene–maleimide copolymers were prepared by free radical copolymerization of styrene (St) and N‐4‐carboxybutylmaleimide (NBMI) in chloroform, using 2,2′‐azobisisobutyronitrile (AIBN) as initiator. Monomer and copolymer characterization was carried out by ¹H‐ and ¹³C‐NMR. Copolymer composition was determined by elemental analysis and Fourier‐transform infrared (FTIR) spectroscopy. The glass transition temperature (from DSC) and the thermogravimetric analysis (TGA) of the copolymers were consistent with the thermal behavior and stability observed for alternating St–maleimide copolymers. St–NBMI copolymers crosslinked with divinylbenzene (DVB) were also synthesized and their cation exchange properties evaluated in order to assess the capacity of the new copolymers to bind metallic ions. Copyright © 2005 Society of Chemical Industry     

Direct synthesis of copper faujasite

Copper containing faujasite has been successfully prepared for the first time using a direct synthesis method. Faujasite type zeolite can be prepared in the presence of copper species by tuning the synthesis conditions. Ammonium hydroxide was used to form a copper complex that was later mixed with the reacting gel. Sodium is required to obtain copper faujasite. The complete elimination of sodium ions from the starting gel produces amorphous material. Crystallization took place at 358 K for 11 days. Crystallization temperature of 373 K produces ANA type zeolite as an impurity. Increasing by two times the amount of copper complex added to the reacting gel increases the crystallization time of Cu-FAU from 11 to 20 days (the crystallization rate decreases). The copper containing faujasite obtained was characterized by XRD, FESEM, EDX, EPR, FT-IR, TPR, and BET. According to the XRD pattern only FAU type zeolite was obtained. According to TPR experiments, the reduction temperature for Cu²⁺ ions present in Cu-FAU prepared by direct synthesis was 70 K more than for Cu-FAU prepared by ion-exchange. This difference can be due to the different location of the copper ions in the supercages or in the sodalite cages of the faujasite.     

Location of structural sections from within a highly distorted complex line drawing

Complex and highly distorted line drawings are produced by subjects attempting the Rey Complex Figure test, a clinical test of neuropsychological assessment. However, the marking scheme conventionally employed can be subjective and unreliable. In this paper, the first stages in automating this scoring system are investigated using a robust technique to locate a reduced set of scoring sections and a knowledge-based system that employs spatial metrics and fuzzy approximation techniques. Testing the technique using clinical data produced encouraging results that support the argument that this is a feasible approach for implementing a fully automated system, and that in its current state, can be immediately applied in a semi-automated system.