Contribution à l'étude de la détermination des conditions de formation des haloformes

In recent years the presence of haloforms has been observed by some researchers in waters of various origins.The aim of this study is to determine the conditions in which chloroform is formed by chlorination of aqueous solutions of some organic compounds.The first part of this work was carried out by chlorination of synthetic basic solutions of acetone and thus enabled us to determine the reagent concentrations needed to obtain the maximum quantity of chloroform.We studied next the effect of chlorination on organic material solutions (humic acids and phenols), in the course of an oxidation treatment; the results obtained by chlorination of aqueous solutions of humic substances show that the quantity of chloroform produced passes through a maximum value which depends on the time of ozonisation. Similar results were obtained for the chlorination of phenol solutions during oxidation by the u.v. + H₂O₂ system. These results may be explained by the partial degradation of the molecules which leads in the formation of reactional intermediate precursors of the haloform reaction. We undertook at the same time the study of a rapid test allowing us to detect the presence of haloform reaction precursors in a certain sample of water.     

Settlements and deformations of industrial structure built on weak soils

Conclusions 1. In engineering-geologic explorations, it is necessary to investigate the engineering-geologic morphology to a depth of 15–18 m: lenses and interlayers of weak soils - unevenly compacted silty-sand fills, peat, slime, etc.2. Open unwatering of pits in the vicinity (10–15 m) of existing structures is impermissible, since it leads to removal of fine soil fractions because of piping, and to large and impermissible deformations of the load-bearing elements of the structures. In such cases, deep groundwater lowering by means of wellpoints should be used.In the case described in this article, the industrial structure underwent a mean settlement of about 20 cm, a tilt of 0.015, and a wall deflection of 0.002. By using deep groundwater lowering, such deformations could have been prevented.3. The development of settlements with time was due to the presence of weak soils - peat lenses and thin slime interlayers - in the foundation bed of the shop.4. An effective means for stopping the settlement of the industrial structure was the construction, under the walls, of two rows of cast-in-place piles with cantilever beams to which the wall loads were transmitted.Scientific-Research Institute of Foundations. GIPROLESKhIM. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 1, pp. 5–7, January–February, 1975.     

Dynamic analysis and optimal feedback control synthesis applied to biological waste treatment

The dynamics and optimal feedback control of biological waste treatment processes are examined. Modern feedback control theory is applied and results are obtained for both proportional and proportional plus integral control. A dynamic mathematical model of the system is developed by employing a Monod kinetic model, which is modified to account for endogenous metabolism, and a complete mixing flow model in the growth chamber. The feedback control is implemented via the flow rate so as to maintain desired effluent concentrations. External disturbances which cause changes in substrate concentration and/or cell concentration are considered and optimal control effort is applied. Results are also presented for impulse and step changes in the influent substrate concentration. It is found that by changing the values of the weighting factors in the objective function, it is possible to obtain good control of either the effluent substrate concentration or cell concentration.     

The development of macrolayer thickness of water in the pool boiling regime

ABSTRACT

The main purpose of this study is to analyse the phenomenon of pool boiling in water over a horizontally placed copper tube heater of 28?mm diameter. The experiment has been carried out to observe the bubble growth and departure characteristics for the heat flux range up to 40,000?W/m². The entire process is being recorded by a digital camera at different time intervals. The measured parameters have been used to determine the initial layer thickness, macro layer thickness and critical heat flux and validated with models proposed in the literature.     

Free vibration of a clamped-free circular cylindrical shell partially filled with liquid—Part I: Theoretical analysis

Theoretical analyses are presented for the linear free vibration of a clamped-free cylindrical shell partially filled with an incompressible, inviscid liquid. For the vibration of the shell itself, the dynamic version of the Donnell equations was used and the problem was solved with the modified Galerkin procedure, taking the effect of the axisymmetric deformation due to the static liquid pressure into consideration. Concerning the vibration relevant to the liquid motion, the solution for the velocity potential was assumed as a sum of two sets of linear combinations of the suitable harmonic function, the unknown parameters of which were imposed to satisfy both boundary conditions along the wetted shell wall and the free liquid surface in a sense of appropriate series expansions. The procedure stated in the foregoing leads to a determinantal equation for the determination of the natural frequencies of the present shell-liquid system. To compare with the experimental results which will be stated in a companion paper,¹⁴ detailed numerical results will be presented in another companion paper¹³ on the free vibration characteristics of the two test cylinders partially filled with water.     

Results of evaluation of the strength of concrete placed in the shafts of cast-in-place piles

Conclusions 1. Application of the method of underwater concreting with the use of a container is inexpedient in connection with the presence of a large number of flaws detected in the shafts of cast-in-place piles formed by this method; concreting of holes by the VAT method is preferable.2. The strength of concrete in the shafts of cast-in-place piles increases, reaching a maximum at a depth of 0.4–0.5 the length of the shaft. Variation in strength along the shaft is explained primarily by the percentage of coarse aggregate contained in the concrete.3. The quality of pile concrete should be monitored during all stages of pile installation, and, primarily during the stage of concreting, i.e., when there is a chance of correcting an observed defect.All-Union Institute for the Design and Planning of Health Resorts. Scientific-Research Institute of Foundations and Underground Structures. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 5, pp. 14–17, September–October, 1976.     

A digital wind gust recorder

The instrument was a byproduct of an undergraduate final year project on wind power which was carried out by the Department of Mechanical Engineering of the University of Liverpool.The windmill test site was on an exposed, rocky island where there was no history of weather recording but a long tradition of violent winds.Field experience during the winter months suggested that corrosion fatigue arising from wind buffeting and salt spray would rank equally with maximum wind pressure as criteria of failure and if modern materials, so convenient for forming aerodynamic surfaces, were to be used then limited life concepts would need to be considered. This called for more knowledge of wind variations at the test site. A complete wind spectrum taken on chart recording instruments would have been ideal but since such such refined devices were not available the instrument to be described was designed.The only wind measuring instrument which was available was a rotating cup anemometer. This supplied an alternating voltage proportional to its rotational speed. It also operated a gear driven microswitch which could give an integrated “miles of wind” reading on an electromagnetic counter.Briefly the e.m.f. generated by the anemometer (Fig. 1) was matched against a pre-set voltage corresponding to the required gust velocity. When this was exceeded an appropriate counter was operated. Only the rising e.m.f. was significant. The subsequent fall was ignored. Initially three stages were incorporated which reported the gusts rising through forty, fifty and sixty knots, respectively. These recorded on separate counters. All basic settings were based on pitot-static speed determinations in a wind tunnel.     

Heavy metals in maternal and cord blood

Heavy metal concentrations have been determined in maternal and cord blood samples collected from mothers in the age group 20-25 years with full-term neonates (37-40 weeks). The concentrations of Pb, Cd, Cu and Zn were found to be low in cord blood as compared to mother's blood and the ratio between cord blood and maternal blood for the respective elements was found to be approximately 0.80, 0.86, 0.47 and 0.40. On the other hand, the concentrations of Fe and Mg in the mother's blood were found to be lower than those in the cord blood. Prenatal exposure to lead in Mumbai, though low (5.1 microg/dl), is approximately 2-3 times higher than that observed in Canada or Italy. A strong correlation (r = 0.79) between the maternal and cord blood lead levels has been observed during the present study.     

Seismic methods for study of soil building properties

Bulletin of Engineering Geology and the Environment - Information about distribution of elastic wave propagation velocities Vp, Vs in the subsurface zone of a soil mass can be obtained rapidly and...     

Long-term geophysical observations on the inguri dam rock foundation

Bulletin of Engineering Geology and the Environment - It has been found that during construction of the dam, prior to the filling of the reservoir, compaction and loading of the rocks under the...