排烟高位收水冷却塔设计

本文介绍了排烟高位收水冷却塔探索过程.结合庐江神皖合肥庐江发电厂工程介绍了排烟高位收水冷却塔的斜支柱布置、玻璃钢烟道筒壁支持体系、中央竖井及烟道支架结构及排烟高位收水冷却塔防腐设计.     

关于高压电气设备带电检测信息化管理的研究

随着电力系统的发展,对发电、输电、供电和用电的可靠性要求越来越高,高压电气设备状态检测也尤显重要.建立了一种智慧仪器仪表在线检测智能运检平台,制定统一的数据传输规范,实现检测数据终端分析、检测结果线上管理,全面提升电力设备带电检测试验工作水平,支撑泛在电力物联网重要战略部署.     

基于关联分析的变电站附属设备差异化运维

针对变电站附属设施缺陷分析手段欠缺、运维策略粗放、简单周期化的问题,研究基于关联分析的变电站附属设备差异化运维技术,基于现有的变电站附属设备管理系统搜集的缺陷历史数据,从变电站、附属设备类型、厂家、型号和投运年限、季节等维度对变电站附属设备进行关联分析,实现附属设备的状态评估,提出附属设备差异化运维方案,从而提升运维人员决策的预见性和全局性.     

微米级P-Si@a-TiO2负极材料的制备及电化学性能

以微米级Al-Si合金粉为原料,采用去合金法和溶胶-凝胶法制备了无定形TiO2包覆珊瑚状多孔Si结构的复合材料(记为P-Si@a-TiO2),通过XRD、XPS、SEM和TEM对复合材料的结构和形貌进行了表征,分析并揭示了TiO2层的制备机理及包覆层厚度对复合材料电化学性能的影响.结果表明,珊瑚状多孔Si结构和适当厚度的包覆层可以有效缓冲材料的体积膨胀,提高电极的循环稳定性.当TiO2包覆层约为10 nm时,对材料的改性效果最佳.此时的P-Si@a-TiO2的电极电势差仅为0.321 V,在1.0 A/g电流密度下循环50次后具有1357.4 mA·h/g的放电比容量,展现出优越的电化学性能.     

多能互补电网中的储能出力协同优化控制策略∗

经过多年发展,除燃煤发电外,风力发电、光伏发电、抽水储能发电取得长足的发展,但输出功率不稳、出力大小不一,致使风光抽水储能发电并没有实现完全并网.对多能互补电网的储能出力情况进行研究,通过分析不同发电系统的特点,以系统出力作为研究对象,利用粒子群算法,给出多能互补电网出力协同优化控制策略,提高多能互补发电效率,具有非常好的实际指导意义.     

25Cr2Ni4MoV钢转子轴颈损伤修复工艺研究

汽轮发电机运行过程中,转子轴颈磨损拉伤的情况较为普遍,采用微弧冷焊技术可以实现对损伤部位的修复。针对25Cr2Ni4MoV材料转子,通过焊接工艺试验和试样性能检测,得到一种可靠的微弧冷焊工艺;并通过对焊缝无损检测标准和焊后尺寸恢复工艺的研究,形成了一套完善的轴颈损伤修复工艺方案。     

国内弧焊设备电磁兼容性研究进展

焊弧设备的电磁兼容性问题日益突出，受到越来越多的关注。针对我国的实际情况，对国内弧焊设备的研究现状进行了综合分析，同时指出了今后的研究方向。     

4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-1,3,5-triazine modified carbon paste electrode for trace Cu(Ⅱ) determination by differential pulse volt-ammetry

A differential pulse voltammetric method was developed for the sensitive and selective determination of Cu(Ⅱ) at 4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-l,3,5-triazine modified carbon paste electrode in 0.05 mol/L KHC8H4O4 solution (pH = 4.02). The oxidation peak of Cu(Ⅱ) was observed at 0.065 V(vs Ag/AgCl) by scanning the potential in positive direc-tion. The analysis procedure consisted of an open circuit accumulation step in stirred sample solution. It was followed by medium exchange to a clean solution and subsequently an anodic potential scan was affected to obtain the voltammetric peak. The current was proportional to the concentration of the Cu(Ⅱ) ion in a range of 1× 10-7-1×10-4 mol/L for 6 min accumulation; the most of metal ions did not interfere with the determination. The developed method was applied to Cu(Ⅱ) determination in coal-ash sample, the results agreed with that of atomic adsorption spectroscopy(AAS).     

新技术在氯碱生产系统扩建中的合理应用

介绍了江苏金浦北方氯碱化工有限公司在4万t/a离子膜法烧碱技改项目中新技术、新设备的运用情况,针对运行中出现的问题,提出合理的解决方法.     

在VPO催化剂上丁烷选择氧化的质谱研究

The selective oxidation of n-butane to maleic anhydride(MA) on a vanadium-phosphorus oxide (VPO) catalyst was studied using on-line gas-chromatography combined with mass spectrometry(GC-MS) and transient response technique.The reaction intermediates,butene and furan,were found in the reaction effuent under near industrial feed condition (3% butane 15% O2),while dihydrofuran was detected at high butane concentration (12% butane,5%O2).Some intermediates of MA decomposition were also identified.Detection of these intermediates shows that the vanadium phosphorus oxides are able to dehydrogenate butane to butene,and butene further to form MA.Based on these observations,a modified scheme of reaction network is proposed.The transient experiments show that butane in the gas phase may directly react with oxygen both on the surface and from the metal oxide lattice,without a proceeding adsorption step.Gas phase oxygen can be adsorbed and transformed to surface lattice oxygen but it can not participate in selective oxidation.Adsorbed oxygen leads to deep oxidation,while lattice oxygen leads to selective oxidation.