全文获取类型
收费全文 | 1352篇 |
免费 | 115篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 14篇 |
化学工业 | 685篇 |
金属工艺 | 27篇 |
机械仪表 | 18篇 |
建筑科学 | 19篇 |
能源动力 | 32篇 |
轻工业 | 174篇 |
水利工程 | 4篇 |
石油天然气 | 11篇 |
无线电 | 62篇 |
一般工业技术 | 248篇 |
冶金工业 | 31篇 |
原子能技术 | 5篇 |
自动化技术 | 138篇 |
出版年
2024年 | 5篇 |
2023年 | 38篇 |
2022年 | 199篇 |
2021年 | 186篇 |
2020年 | 52篇 |
2019年 | 38篇 |
2018年 | 46篇 |
2017年 | 53篇 |
2016年 | 62篇 |
2015年 | 49篇 |
2014年 | 83篇 |
2013年 | 70篇 |
2012年 | 77篇 |
2011年 | 77篇 |
2010年 | 50篇 |
2009年 | 46篇 |
2008年 | 61篇 |
2007年 | 45篇 |
2006年 | 39篇 |
2005年 | 42篇 |
2004年 | 33篇 |
2003年 | 15篇 |
2002年 | 15篇 |
2001年 | 7篇 |
2000年 | 12篇 |
1999年 | 2篇 |
1998年 | 12篇 |
1997年 | 12篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1964年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有1468条查询结果,搜索用时 31 毫秒
21.
The structure of silver deposits plated from different complex electrolytes is investigated. It is shown that from all electrolytes based on cyano-argentate complexes, electrodeposits with a basic orientation along the <111> axis are plated. If other complex-forming agents are used, textures along different crystallographic axes can be obtained. At high current densities the deposits display a random orientation. No evidence for a direct relationship between the type of texture and the deposition overvoltage of silver in the electrolytes studied has been established. Silver deposits with structural characteristics and properties similar to those of coatings deposited from cyanide baths can be obtained from ferrocyanide-thiocyanate electrolytes. 相似文献
22.
Very long chain (VLC) PUFA of the n−6 and n−3 series are known to occur in mammalian testis. The aim of this work was to characterize
further two testicular lipid classes with VLCPUFA, cholesterol esters (CE) and total triglycerides (TG) in rat and mouse testis.
The VLCPUFA predominating in these lipids were a series of n−6 pentaenes and tetraenes with 24 to 32 carbons, including small
amounts of odd-chain PUFA, 28∶5n−6 and 24∶5n−6 prevailing in CE and TG, respectively. Most of the VLCPUFA of TG were concentrated
in a small fraction of TG, made up by 1-O-alkyl-2,3-DAG. This TG subclass was absent altogether from the TG of sexually immature testis. The TG and the CE with VLCPUFA
only occurred in testis of adult fertile animals. The proportion of VLCPUFA in total TG and CE was higher in rodents than
in other mammals. In the n−6 PUFA-rich adult mouse testis, the amounts of testicular triacylglycerols decreased significantly
after consumption of fish oil for 2 wk. Whereas 18∶2n−6 was significantly reduced, the amounts of 22∶5n−6 and longer n−6 PUFA
were less affected in all mamor testicular lipids including PC and PE, where they were unchanged. The 1-O-alkyl-2,3-DAG and their n−6 VLCPUFA were virtually unaffected by the diet. The VLCPUFA-containing molecular species of CE
and TG may represent a form of storage of cholesterol and polyenoic FA required to sustain spermatogenesis. Via chain-shortening, VLCPUFA stored in the neutral lipids may serve as precursors of the major C22 PUFA typical of cell membrane glycerophospholipids, protecting testicular cells against shifts in FA composition induced
by dietary changes. 相似文献
23.
Muhammad Khafidh Natalia Valentina Rodriguez Marc Arthur Masen Dirk Jan Schipper 《Tribology - Materials, Surfaces & Interfaces》2016,10(2):70-73
The friction in tribo-systems that contain viscoelastic materials, such as elastomers, is relevant for a large number of applications. Examples include tyres, hoses, transmission and conveyor belts. To quantify the friction in these applications, one must first understand the contact behaviour of such viscoelastic materials, both in static and in dynamic situations. This work discusses an experimental study into the change of the contact area with the sliding velocity and relates the change in contact area with the mechanical properties of the elastomer. The results show that for a tribo-system containing an elastomer, there is a threshold velocity, above which the size of the contact area significantly reduces. 相似文献
24.
Natalia Criado Elizabeth Black Michael Luck 《Autonomous Agents and Multi-Agent Systems》2016,30(4):640-680
Norms can be used in multi-agent systems for defining patterns of behaviour in terms of permissions, prohibitions and obligations that are addressed to agents playing a specific role. Agents may play different roles during their execution and they may even play different roles simultaneously. As a consequence, agents may be affected by inconsistent norms; e.g., an agent may be simultaneously obliged and forbidden to reach a given state of affairs. Dealing with this type of inconsistency is one of the main challenges of normative reasoning. Existing approaches tackle this problem by using a static and predefined order that determines which norm should prevail in the case where two norms are inconsistent. One main drawback of these proposals is that they allow only pairwise comparison of norms; it is not clear how agents may use the predefined order to select a subset of norms to abide by from a set of norms containing multiple inconsistencies. Furthermore, in dynamic and non-deterministic environments it can be difficult or even impossible to specify an order that resolves inconsistencies satisfactorily in all potential situations. In response to these two problems, we propose a mechanism with which an agent can dynamically compute a preference order over subsets of its competing norms by considering the coherence of its cognitive and normative elements. Our approach allows flexible resolution of normative inconsistencies, tailored to the current circumstances of the agent. Moreover, our solution can be used to determine norm prevalence among a set of norms containing multiple inconsistencies. 相似文献
25.
To support analysis and modelling of large amounts of spatio-temporal data having the form of spatially referenced time series (TS) of numeric values, we combine interactive visual techniques with computational methods from machine learning and statistics. Clustering methods and interactive techniques are used to group TS by similarity. Statistical methods for TS modelling are then applied to representative TS derived from the groups of similar TS. The framework includes interactive visual interfaces to a library of modelling methods supporting the selection of a suitable method, adjustment of model parameters, and evaluation of the models obtained. The models can be externally stored, communicated, and used for prediction and in further computational analyses. From the visual analytics perspective, the framework suggests a way to externalize spatio-temporal patterns emerging in the mind of the analyst as a result of interactive visual analysis: the patterns are represented in the form of computer-processable and reusable models. From the statistical analysis perspective, the framework demonstrates how TS analysis and modelling can be supported by interactive visual interfaces, particularly, in a case of numerous TS that are hard to analyse individually. From the application perspective, the framework suggests a way to analyse large numbers of spatial TS with the use of well-established statistical methods for TS analysis. 相似文献
26.
This paper reports on a case study of a teacher from a technical education institution who explored the educational affordances of PDA technology over a period of six months. Based on this teacher’s perspectives, the study was designed to inform our own understanding of educational affordances of this new and emerging technology. Understanding of educational affordances is important in the context of planning a suitable intervention to support pedagogically effective integration of PDA technology. The study explicated a set of five affordances of PDA technology: as a multimedia-access tool, connectivity tool, capture tool, representational tool and analytical tool. We call on further research to expand this set into a more comprehensive collage of educational affordances of PDA technology. 相似文献
27.
Classification of a video stream is an essential preliminary step to estimate the bit loss when the video stream is transmitted over a communication network. In this paper, we classify the video frames by the average frame size and estimate the bit loss for each class when the bitrate exceeds the capacity of the bottleneck link. The video stream under study is encoded using the explicit slice-based H.264/AVC encoding scheme. This scheme reduces the burstiness of regular H.264/AVC encoded video by removing the traditional GOP structure. Instead, a repetitive combination of intracoded and predicted slices is employed, thereby introducing a specific dependence structure in the video data. We consider a bufferless model of the communication system and evaluate the channel capacity required to give a maximum allowed loss rate for each class.Due to the high variability, non-stationarity and non-homogeneity of the underlying video data, the obtained classes are checked regarding the dependence and distribution structure of the data. The high quantiles of the losses are estimated for each class. 相似文献
28.
Engineering Transition Metal Layers for Long Lasting Anionic Redox in Layered Sodium Manganese Oxide
Natalia Voronina Jun Ho Yu Hee Jae Kim Najma Yaqoob Olivier Guillon Hyungsub Kim Min-Gi Jung Hun-Gi Jung Koji Yazawa Hitoshi Yashiro Payam Kaghazchi Seung-Taek Myung 《Advanced functional materials》2023,33(5):2210423
Oxygen-redox-based-layered cathode materials are of great importance in realizing high-energy-density sodium-ion batteries (SIBs) that can satisfy the demands of next-generation energy storage technologies. However, Mn-based-layered materials (P2-type Na-poor Nay[AxMn1−x]O2, where A = alkali ions) still suffer from poor reversibility during oxygen-redox reactions and low conductivity. In this work, the dual Li and Co replacement is investigated in P2-type-layered NaxMnO2. Experimentally and theoretically, it is demonstrated that the efficacy of the dual Li and Co replacement in Na0.6[Li0.15Co0.15Mn0.7]O2 is that it improves the structural and cycling stability despite the reversible Li migration from the transition metal layer during de-/sodiation. Operando X-ray diffraction and ex situ neutron diffraction analysis prove that the material maintains a P2-type structure during the entire range of Na+ extraction and insertion with a small volume change of ≈4.3%. In Na0.6[Li0.15Co0.15Mn0.7]O2, the reversible electrochemical activity of Co3+/Co4+, Mn3+/Mn4+, and O2-/(O2)n- redox is identified as a reliable mechanism for the remarkable stable electrochemical performance. From a broader perspective, this study highlights a possible design roadmap for developing cathode materials with optimized cationic and anionic activities and excellent structural stabilities for SIBs. 相似文献
29.
Ivona Kafedjiska Igal Levine Artem Musiienko Natalia Maticiuc Tobias Bertram Amran Al-Ashouri Christian A. Kaufmann Steve Albrecht Rutger Schlatmann Iver Lauermann 《Advanced functional materials》2023,33(34):2302924
The performance of five hole-transporting layers (HTLs) is investigated in both single-junction perovskite and Cu(In, Ga)Se2 (CIGSe)-perovskite tandem solar cells: nickel oxide (NiOx,), copper-doped nickel oxide (NiOx:Cu), NiOx+SAM, NiOx:Cu+SAM, and SAM, where SAM is the [2-(3,-6Dimethoxy-9H-carbazol-9yl)ethyl]phosphonic acid (MeO-2PACz) self-assembled monolayer. The performance of the devices is correlated to the charge-carrier dynamics at the HTL/perovskite interface and the limiting factors of these HTLs are analyzed by performing time-resolved and absolute photoluminescence ((Tr)PL), transient surface photovoltage (tr-SPV), and X-ray/UV photoemission spectroscopy (XPS/UPS) measurements on indium tin oxide (ITO)/HTL/perovskite and CIGSe/HTL/perovskite stacks. A high quasi-Fermi level splitting to open-circuit (QFLS-Voc) deficit is detected for the NiOx-based devices, attributed to electron trapping and poor hole extraction at the NiOx-perovskite interface and a low carrier effective lifetime in the bulk of the perovskite. Simultaneously, doping the NiOx with 2% Cu and passivating its surface with MeO-2PACz suppresses the electron trapping, enhances the holes extraction, reduces the non-radiative interfacial recombination, and improves the band alignment. Due to this superior interfacial charge-carrier dynamics, NiOx:Cu+SAM is found to be the most suitable HTL for the monolithic CIGSe-perovskite tandem devices, enabling a power-conversion efficiency (PCE) of 23.4%, Voc of 1.72V, and a fill factor (FF) of 71%, while the remaining four HTLs suffer from prominent Voc and FF losses. 相似文献
30.
Nikolova L Todorov T Ivanov M Andruzzi F Hvilsted S Ramanujam PS 《Applied optics》1996,35(20):3835-3840
We investigate thin phase polarization holographic gratings recorded with two waves with orthogonal linear polarizations in materials in which illumination with linearly/circularly polarized light gives rise to linear/circular birefringence. The theoretical analysis shows that the presence of circular photoanisot-ropy changes significantly the diffraction characteristics of the gratings. The intensities of the waves diffracted in the +1 and -1 orders of diffraction and their ratio depend substantially on the reconstructing-wave polarization. Experiments with films of side-chain liquid-crystalline azobenzene polyester that is a photoanisotropic material of the considered type confirm the unusual polarization properties. It is shown that polarization holography may be used for real-time simultaneous measurement of photoinduced linear and circular birefringence. 相似文献