Sodium sulfate: Deposition and dissolution of silica

The hot-corrosion process for SiO₂-protected materials involves deposition of Na₂SO₄ and dissolution of the protective SiO₂ scale. Dew points for Na ₂SO₄ deposition are calculated as a function of pressure, sodium content, and sulfur content. Expected dissolution regimes for SiO₂ are calculated as a function of Na₂SO₄ basicity, hence generated by fuels with 0.5% and 0.05% S. Controlled-condition burner-rig tests on quartz verify some of these predicted dissolution regimes. However, the basicity of Na₂SO₄ is not always a simple function of (Na₂O) show that carbon creates basic conditions in Na₂SO₄, which explains the extensive corrosion of SiO₂-protected materials containing carbon, such as SiC.     

Runout effects in milling: Surface finish, surface location error, and stability

This paper investigates the effect of milling cutter teeth runout on surface topography, surface location error, and stability in end milling. Runout remains an important issue in machining because commercially-available cutter bodies often exhibit significant variation in the teeth/insert radial locations; therefore, the chip load on the individual cutting teeth varies periodically. This varying chip load influences the machining process and can lead to premature failure of the cutting edges. The effect of runout on cutting force and surface finish for proportional and non-proportional tooth spacing is isolated here by completing experiments on a precision milling machine with 0.1 μm positioning repeatability and 0.02 μm spindle error motion. Experimental tests are completed with different amounts of radial runout and the results are compared with a comprehensive time-domain simulation. After verification, the simulation is used to explore the relationships between runout, surface finish, stability, and surface location error. A new instability that occurs when harmonics of the runout frequency coincide with the dominant system natural frequency is identified.     

Solving linear generalized Nash equilibrium problems numerically

This paper considers the numerical solution of linear generalized Nash equilibrium problems (LGNEPs). Since many methods for nonlinear problems require the nonsingularity of some second-order derivative, standard convergence conditions are not satisfied in our linear case. We provide new convergence criteria for a potential reduction algorithm (PRA) that allow its application to LGNEPs. Furthermore, we discuss a projected subgradient method (PSM) and a penalty method that exploit some known Nikaido–Isoda function-based constrained and unconstrained optimization reformulations of the LGNEP. Moreover, it is shown that normalized Nash equilibria of an LGNEP can be obtained by solving a single linear program. All proposed algorithms are tested on randomly generated instances of economic market models that are introduced and analysed in this paper and that lead to LGNEPs with shared and with non-shared constraints. It is shown that these problems have some favourable properties that can be exploited to obtain their solutions. With the PRA and in particular with the PSM we are able to compute solutions with satisfying precision even for problems with up 10,000 variables.     

Increased biogas production in a wastewater treatment plant by anaerobic co-digestion of fruit and vegetable waste and sewer sludge - a full scale study

Anaerobic digestion is a well established technology for the reduction of organic matter and stabilization of wastewater. Biogas, a mixture of methane and carbon dioxide, is produced as a useful by-product of the process. Current solid waste management at the city of Prince George is focused on disposal of waste and not on energy recovery. Co-digestion of fresh fruit and vegetable waste with sewer sludge can improve biogas yield by increasing the load of biodegradable material. A six week full-scale project co-digesting almost 15,000 kg of supermarket waste was completed. Average daily biogas production was found to be significantly higher than in previous years. Digester operation remained stable over the course of the study as indicated by the consistently low volatile acids-to-alkalinity ratio. Undigested organic material was visible in centrifuged sludge suggesting that the waste should have been added to the primary digester to prevent short circuiting and to increase the hydraulic retention time of the freshly added waste.     

Application of the Soil and Water Assessment Tool for six watersheds of Lake Erie: Model parameterization and calibration

The Soil and Water Assessment Tool (SWAT), a physically-based watershed-scale model, holds promise as a means to predict tributary sediment and nutrient loads to the Laurentian Great Lakes. In the present study, model performance is compared across six watersheds draining into Lake Erie to determine the applicability of SWAT to watersheds of differing characteristics. After initial model parameterization, the Huron, Raisin, Maumee, Sandusky, Cuyahoga, and Grand SWAT models were calibrated (1998-2001) and confirmed, or validated (2002-2005), individually for stream water discharge, sediment loads, and nutrient loads (total P, soluble reactive P, total N, and nitrate) based on available datasets. SWAT effectively predicted hydrology and sediments across a range of watershed characteristics. SWAT estimation of nutrient loads was weaker although still satisfactory at least two-thirds of the time across all nutrient parameters and watersheds. SWAT model performance was most satisfactory in agricultural and forested watersheds, and was less so in urbanized settings. Model performance was influenced by the availability of observational data with high sampling frequency and long duration for calibration and confirmation evaluation. In some instances, it appeared that parameter adjustments that improved calibration of hydrology negatively affected subsequent sediment and nutrient calibration, suggesting trade-offs in calibrating for hydrologic vs. water quality model performance. Despite these considerations, SWAT accurately predicted average stream discharge, sediment loads, and nutrient loads for the Raisin, Maumee, Sandusky, and Grand watersheds such that future use of these SWAT models for various scenario testing is reasonable and warranted.     

Relationships Between Satellite Observed Lit Area and Water Footprints

Global water resources are vulnerable to depletion due to the increasing demand of an ever-increasing human population. A country’s water footprint is a measure of the total volume of water needed to produce the goods and services consumed by the country, including water originating beyond its own borders. The water footprint can be a critical indicator of global water resource use, but its practical application is hindered by a lack of comparable data across national boundaries. The purpose of this article is to test the applicability of the nighttime imagery products produced by the Defense Meteorological Satellite Program’s Operational Linescan System (DMSP-OLS) for the assessment of the global water footprint. To accomplish this purpose, the average areal extent of nighttime lighting (lit area) is calculated from 1997 to 2001. Next, lit area is regressed on the total water footprint for each country, as indicated by the Water Footprint Network (WFN), to estimate that country’s total water footprint using nighttime imagery. Model residuals are analyzed at the national scale to understand the appropriateness of nighttime imagery for assessing water consumption. Results indicate strong positive correlations between lit area and total water footprint (TWF), domestic water withdrawal (DWW), and industrial water consumption (IWC) at the national scale. Overall, the analyses reveal that the rate of agricultural water consumption to total water footprint (AWCR) and population density can affect the precision of estimates when lit area is selected as a proxy to estimate water footprints.     

Verformungsverhalten nanostrukturierter HPPMS‐Hartstoffschichten

Elastic‐Plastic Deformation Behavior of Nanostructured HPPMS Hard Coatings Nitride hard coatings deposited via HPPMS (High Power Pulsed Magnetron Sputtering) or HiPIMS (High Power Impulse Magnetron Sputtering) are widely used in tribological applications due to their promising wear and corrosion resistance. During the application, the coated tools or components may be exposed to significant mechanical loads. Therefore, investigations on deformation behavior of the coatings under mechanical loading are of great importance. The objective of the present study was a comprehensive investigation on deformation behavior of nitride hard coatings from the coating system M‐Al‐O‐N (M = Cr, V) using nanoindentation und nanoscratch tests. In this regard, both nanoscale multilayer (nanolaminate) and monolayer coatings were investigated. All the coatings were deposited using HPPMS technology. Contrary to the expectations regarding a brittle behavior of ceramic‐like coatings, the results depict a considerable plastic deformation of the investigated hard coatings. Furthermore, in addition to a high strength, the applied coatings show a high crack resistance under mechanical loading.     

Time dependent voiding mechanisms in polyamide 6 submitted to high stress triaxiality: experimental characterisation and finite element modelling

Double notched round bars made of semi-crystalline polymer polyamide 6 (PA6) were submitted to monotonic tensile and creep tests. The two notches had a root radius of 0.45 mm, which imposes a multiaxial stress state and a state of high triaxiality in the net (minimal) section of the specimens. Tests were carried out until the failure occurred from one of the notches. The other one, unbroken but deformed under steady strain rate or steady load, was inspected using the Synchrotron Radiation Computed Tomography (SRCT) technique. These 3D through thickness inspections allowed the study of microstructural evolution at the peak stress for the monotonic tensile test and at the beginning of the tertiary creep for the creep tests. Cavitation features were assessed with a micrometre resolution within the notched region. Spatial distributions of void volume fraction (\(\mathit{Vf}\)) and void morphology were studied. Voiding mechanisms were similar under steady strain rates and steady loads. The maximum values of \(\mathit{Vf}\) were located between the axis of revolution of the specimens and the notch surface and voids were considered as flat cylinders with a circular basis perpendicular to the loading direction. A model, based on porous plasticity, was used to simulate the mechanical response of this PA6 material under high stress triaxiality. Both macroscopic behaviour (loading curves) and voiding micro-mechanisms (radial distributions of void volume fraction) were accurately predicted using finite element simulations.