Simultaneous preconcentration and removal of iron, chromium, nickel with N,N'-etylenebis-(ethane sulfonamide) ligand on activated carbon in aqueous solution and determination by ICP-OES

In this study, Fe, Cr and Ni have been preconcentrated and removed by using N,N'-ethylenebis (ethane sulfonamide), (ESEN) ligand on activated carbon (AC) in aqueous solution. For this purpose, complexes between these metals and ligands have been investigated and used in preconcentration and removal studies. Factors which have affected adsorption of metals on activated carbon have been optimized. Adsorbed metals have been preconcentrated 10-fold and determined by ICP-OES. Interferences of Ca, Mg and K to this process have been investigated. The proposed method has been applied to the tap water and Ankara Creek water in order to Fe, Cr, and Ni remediation and preconcentration. Determination of metals by ICP-OES has been checked with standard reference material (NIST 1643e). The proposed method provides the recoveries of 87%, 108% and 106% for Fe, Cr and Ni, respectively, in preconcentration. It also provides the removal of Fe, Cr and Ni by 93%, 100% and 100% removal from waters, respectively.     

Electrochromic properties of some bis‐chalcone derivatives‐based nanofibers

Two bis‐chalcone derivatives, (2E,6E)‐2,6‐bis[(thiophen‐2‐yl)methylene]cyclohexanone ( C1 ) and (2E,6E)‐2,6‐bis[(furan‐2‐yl)methylene]cyclohexanone ( C2 )‐based electrochromic (EC) nanofibers were produced in the presence of poly(methyl methacrylate) (PMMA) as supporting polymer using the electrospinning technique. The scanning electron microscopy (SEM) and energy dispersive X‐ray spectroscopy were used to examine morphology and chemical compositions of nanofibers before and after stability test. SEM images of the obtained smooth and bead‐free nanofibers before the stability test showed that both bis‐chalcone derivatives were homogeneously dispersed on the surface of the electrospun nanofibers. Nanofibers of bis‐chalcone derivatives were characterized with Fourier‐transform infrared spectroscopy. The electrochemical and EC properties of these bis‐chalcone derivatives were investigated. The C1 ‐PMMA nanofiber‐based electrochromic device (ECD) showed higher ΔT_max (41.47%) than that of the C2 ‐PMMA nanofiber‐based ECD (4.67%) during coloration/bleaching at 715 nm. The switching times for coloration and bleaching of C1 ‐PMMA nanofiber‐based ECD were found to be 4.42 and 1.12 s, respectively, and the coloration efficiency was 136.18 cm²/C. Repeated cyclic voltammograms and 1000 cycles of chronoamperometric measurements of the bis‐chalcone derivatives indicated that ECDs have long‐term redox stability. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46010.     

Agglomeration of Non-metallic Inclusions at the Steel/Ar Interface: Model Application

Inclusion agglomeration is an important element in several industrial problems during steelmaking, such as nozzle clogging. In parallel work by the authors, a revised Kralchevsky-Paunov model has been established and the performance of this model has been validated against the experimental data from in-situ observations using confocal laser scanning microscopy. In this work, the revised model has been applied to quantitatively evaluate the attractive capillary force for the agglomeration of various inclusions at the interface between Ar and liquid iron/steel. A parametric study of the effects on the capillary force of the inclusion density, contact angle between the inclusion and liquid steel, and the surface tension of the liquid metal are quantitatively investigated. The results show that inclusion density and contact angle have a more marked effect on the capillary force than surface tension of liquid metal. Moreover, the inclusion agglomeration behavior in the liquid iron/steel matrix is discussed. The coagulation coefficient of various inclusions is calculated. Both the calculation results of the attractive capillary force of inclusions at the interface between Ar and liquid iron/steel and coagulation coefficient of inclusions in the liquid iron/steel matrix can offer a close agreement; moreover, the order of magnitude of inclusion agglomeration tendency is suggested. By using the coagulation coefficient, the inclusion collision volume and collision rate are calculated and the effects of inclusion composition, size, and number density are investigated. The evaluation results show that the tendency for affecting inclusion collision is inclusion number density > inclusion size > inclusion composition.     

Applicability of European landscape typology in Turkey (Çakırlar Watershed case/Antalya)

The aim of this study is to put forward Turkey as a case study of the applicability of the European approach to landscape characterisation studies at the local scale within the context of the European Landscape Convention. For this purpose, a classification of landscape types with the help of LANMAP typology is suggested at the European scale in a basin in Turkey where there are obvious differences in terms of landscape characteristics. In particular, this study examines the usability of a countrywide thematic database when making this classification. It is understood that a mapping system as well as a common nomenclature of types of land covered at the country scale is insufficient for the suggested methodology for Europe. Later, results of the continuation of a classification system at the local scale for landscape characterisation are discussed, and some deficiencies of LANMAP when characterising the landscapes at this scale are mentioned.     

Documentation and analysis of structural elements of traditional houses for conservation of cultural heritase in Siverek ((S)anl(i)urfa,Turkey)

This study deals with the architectural properties of traditional Siverek houses, which are important in the larger corpus of Southeastern Anatolian houses. The historical city center of Siverek has partly preserved its authentic character with its monumental buildings and traditional houses. Despite the considerable number of traditional courtyard houses in Siverek, no detailed survey has been conducted on them. In this work, these traditional houses in the historical Siverek City center are identified and documented for the first time. Their plans, façades, and structural systems are examined in detail, and the structural elements are comprehensively analyzed. We document the architectural features of these traditional Siverek houses and introduce the cultural heritage of the city. These details provide information for proper decision-making regarding the preparation of restitution and restoration projects and selecting materials and techniques that suit the structures to be restored.     

Dissolution Behavior of Aluminum Titanate Inclusions in Steelmaking Slags

Metallurgical and Materials Transactions B - The current work investigates the dissolution path and mechanism of aluminum titanate inclusions in steelmaking slags using a high-temperature confocal...     

Cyclic fatigue resistance of rotary NiTi instruments produced with four different manufacturing methods

The aim of this study was to compare the cyclic fatigue resistance of rotary NiTi files, produced with four different manufacturing methods on specially designed dynamic models that simulated clinical conditions. In this study, 120 files, consisting of 30 files for Typhoon, ProTaper Next, RaCe, and Twisted Files nickel titanium rotary systems were used. The 30 files of each group were divided into three subgroups to be used in artificial canals with a 60° angle of curvature and radii of curvature of 2, 5, and 8 mm (n = 10). All files were rotated in the artificial canals until fracture occurred and the number of cycles to fracture was calculated. The data were analyzed using one‐ and two‐way analyses of variance and Tamhane multiple comparison tests. In all three groups, Typhoon instruments had the highest number of cycles to failure than the RaCe, ProTaper Next, and Twisted Files instruments, and the difference statistically significant (p < .05). There were no significant differences between the RaCe, ProTaper Next, and Twisted Files groups (p > .05). The CM wire Typhoon system was significantly more resistant to cyclic fatigue compared to the other file systems in all three artificial canals. When the fracture resistance of an instrument in three different artificial canals was compared, the mean NCFs decreased as the radius of the curvature of the canal decreased from 8 to 2 mm. Manufacturing method is one of the most important factors on cyclic fatigue resistance, also the radius of curvature effects the cyclic fatigue.     

Performance analysis of drying of green olive in a tray dryer

This paper deals with the performance evaluation of a single layer drying process of green olives in a tray dryer using exergy analysis method. Green olive was used as the test material being dried. Drying process was realized at four different drying air temperatures (40, 50, 60 and 70 °C) and a constant relative humidity of 15%. The effects of temperatures and mass flow rates were investigated. Maximum exergy efficiency of the drying chamber was obtained at a temperature of 70 °C and a drying air mass flow rate of 0.015 kg/s with 0.0004 kg/s of olive. The exergy efficiency values were found to be in the range of 68.65%–91.79% from 40 °C to 70 °C with drying air mass flow rates of 0.01 kg/s–0.015 kg/s.