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101.
Jens Georg Kaufmann Marc P. Y. Desmulliez Yingtao Tian Dennis Price Mike Hughes Nadia Strusevich Chris Bailey Changqing Liu David Hutt 《Microsystem Technologies》2009,15(8):1245-1254
In this paper we propose an agitation method based on megasonic acoustic streaming to overcome the limitations in plating
rate and uniformity of the metal deposits during the electroplating process. Megasonic agitation at a frequency of 1 MHz allows
the reduction of the thickness of the Nernst diffusion layer to less than 600 nm. Two applications that demonstrate the benefits
of megasonic acoustic streaming are presented: the formation of uniform ultra-fine pitch flip-chip bumps and the metallisation
of high aspect ratio microvias. For the latter application, a multi-physics based numerical simulation is implemented to describe
the hydrodynamics introduced by the acoustic waves as they travel inside the deep microvias. 相似文献
102.
Domestic energy use accounts for more than a quarter of CO2 emissions in the UK. Traditional approaches to energy reduction look at direct emissions savings, and recommend insulation
and efficiency as more cost-effective than microgeneration. However, microgeneration has indirect, ‘soft’ benefits and could
play a significant role in emissions reduction. Current uptake of microgeneration in the UK is low, with various barriers—economic,
technical, cultural, behavioural and institutional—both to uptake and to maximising energy and emissions savings once installed.
Subsidies and spreading information alone do not guarantee maximising uptake, and even if successful, this is not enough to
maximise savings. The industry focuses on maximising sales, with no incentives to ensure best installations and use; householders
do not have access to the best information, and user behaviour does not maximise energy and emission savings. This is related
to a broader state of socio-technical ‘lock-in’ in domestic energy use; there’s a lack of connection between personal behaviour
and energy consumption, let alone global climate change. This suggests that a major cultural–behavioural shift is needed to
reduce energy/emissions in the home. Transition theory and strategic niche management provide insights into possible systemic
change and a suitable framework for future policies, such as supporting a variety of radically innovative niches, both technological
and social. Microgeneration, properly employed, has the potential to play a part in such a transition by increasing awareness
and energy literacy and empowering people to seriously engage in energy debates as producers, as well as consumers, of energy.
This deeper understanding and heightened responsibility are crucial in a shift toward bottom-up emission-reducing behaviour
change and better acceptance of top-down energy-saving policy measures, as part of a new domestic energy paradigm. The implications
for policy are that, as well as supporting the technologies, it needs to support existing niches and to develop new niche
experiments. Policy needs to consider how to promote empowerment and responsibility and support or even develop new energy
sector models; this will involve a range of stakeholders and multiple governance levels, not just national incentive schemes. 相似文献
103.
Nick Blismas Christine Pasquire Alistair Gibb 《Construction Management & Economics》2013,31(2):121-130
Evaluating to what extent a component or building system should be produced off‐site is inadequate within the industry. The potential benefits of off‐site production (OSP) are commonly cited when justifying an OSP approach, yet holistic and methodical assessments of the applicability and overall benefit of these solutions, to a particular project, have been found to be deficient. Common methods of evaluation simply take material, labour and transportation costs into account when comparing various options, often disregarding other cost‐related items such as site facilities, crane use and rectification of works. These cost factors are usually buried within the nebulous preliminaries figure, with little reference to the building approach taken. Further, softer issues such as health and safety, effects on management and process benefits are either implicit or disregarded within these comparison exercises. Yet it is demonstrated that these issues are some of the most significant benefits of OSP. A series of case studies demonstrated that evaluation focus is almost solely on direct material and labour costs of components, without explicit regard for the wider cost or soft issue implications of OSP on a project. The paper argues that until evaluation is more holistic and value‐based rather than cost‐based, OSP uptake in construction will be slow. 相似文献
104.
The use of incentives in partnering and alliancing has been seen as an important way of reinforcing collaboration in the short term and helping to build trust between clients and contractors in the long term. Yet only rarely has the impact of incentives on such relationships been discussed, let alone subjected to systematic investigation. This is despite a wealth of theory and research which brings into question the use of incentives and reinforcers as ways of generating motivation and commitment. Drawing upon this theoretical knowledge base and using evidence from a number of case studies of partnerships and alliances, this paper demonstrates how a number of important cognitive and social dimensions affect the use and impact of incentives, sometimes in ways contrary to those intended. The conclusion drawn is that there are important limitations to the use of incentives as means of reinforcing collaboration and developing commitment and trust, and that this raises questions more generally about the assumptions that underlie many of the practical ‘tools and techniques’ commonly associated with partnering and alliancing. 相似文献
105.
Helen Clare Lingard Tracy Cooke Nick Blismas 《Construction Management & Economics》2013,31(5):367-382
Drawing upon an empirical analysis of the design and construction of a food processing facility, a theoretical understanding of the impact of design decision-making on the occupational health and safety (OHS) of construction workers is developed. It is argued that current policy and legislative approaches to Construction Hazard Prevention through Design (CHPtD) are inherently limited because they do not adequately reflect the socio-material complexity of decision-making in construction design. Specifically, the simplistic attribution of responsibility to a single socio-technical actor, ‘the designer’, does not reflect the multiple and disparate influences that impact upon OHS outcomes. Nor do existing CHPtD policy frameworks, management processes and tools recognize the manner in which the interactions and associations between relevant project stakeholders and various non-human artefacts shape (and are also influenced by) the evolution of design decisions. Drawing on actor-network theory (ANT) and using embedded units within a case study approach, the interactions between human actors and non-human artefacts are explored in relation to the design of four components of the food processing facility. The way in which design decisions unfolded and shaped OHS experiences during the construction stage of the project is revealed. The research highlights limitations inherent in current approaches to the management of CHPtD and the need to develop a more robust theoretically based approach to integrating OHS considerations into construction design practice. 相似文献
106.
Looking at historical projects has much to offer our understanding of project management, for both research and practice. However, there are important challenges in how alternative narratives about such projects are reconstructed and related to each other. To explore these challenges, this paper uses the example of the Thames Tunnel project, completed under the direction of Marc Brunel in 1843, and reputed to be the first tunnel to be built under a major river. In telling the story of the project, we focus on five alternative discourses: technico-rational; practice; networks of people, things, and ideas; politics; and society. The common response to such variety is either to attempt to construct an overarching meta-narrative, or to explore the differences as a way of highlighting the localized and contingent nature of knowledge about projects, or adopt some intermediate position somewhere on the spectrum between these two extremes. Instead we seek a different route grounded in a sociology of knowledge that acknowledges simultaneous, provisional, and contested processes of division and stabilization in the ways that epistemic communities constitute knowledge through their own narratives and practices. These have implications for the stories that are told about project management and, crucially, the activities and interests that both shape and are shaped by such narratives. 相似文献
107.
He Yining Zhong Ming Jones Nick Beuth Jack Webler Bryan 《Metallurgical and Materials Transactions A》2021,52(9):4206-4221
Metallurgical and Materials Transactions A - This work integrates experimental and numerical methods to determine the process conditions under which the columnar-to-equiaxed transition (CET)... 相似文献
108.
Nick D. Austin Nikolaos V. Sahinidis Ivan A. Konstantinov Daniel W. Trahan 《American Institute of Chemical Engineers》2018,64(1):104-122
In this article, we investigate reaction solvent design using COSMO‐RS thermodynamics in conjunction with computer‐aided molecular design (CAMD) techniques. CAMD using COSMO‐RS has the distinct advantage of being a method based in quantum chemistry, which allows for the incorporation of quantum‐level information about transition states, reactive intermediates, and other important species directly into CAMD problems. This work encompasses three main additions to our previous framework for solvent design (Austin et al., Chem Eng Sci. 2017;159:93–105): (1) altering the group contribution method to estimate hydrogen‐bonding and non‐hydrogen‐bonding σ‐profiles; (2) ab initio modeling of strong solute/solvent interactions such as H‐bonding or coordinate bonding; and (3) solving mixture design problems limited to common laboratory and industrial solvents. We apply this methodology to three diverse case studies: accelerating the reaction rate of a Menschutkin reaction, controlling the chemoselectivity of a lithiation reaction, and controlling the chemoselectivity of a nucleophilic aromatic substitution reaction. We report improved solvents/mixtures in all cases. © 2017 American Institute of Chemical Engineers AIChE J, 63: 104–122, 2018 相似文献
109.
Yunxia Yang Craig M. Brown Chunxia Zhao Alan L. Chaffee Burke Nick Dongyuan Zhao Paul A. Webley Jacob Schalch Jason M. Simmons Yun Liu Jae-Hyuk Her C.E. Buckley Drew A. Sheppard 《Carbon》2011,(4):1305-1317
Ordered microporous carbons containing dispersed platinum nanoparticles were fabricated and chosen as suitable models to investigate micro-structure development and hydrogen transport properties of zeolite-templated carbons. X-ray photoelectron spectroscopy analysis revealed that the enhanced heat of adsorption is related to the narrow micro-channels templated from the zeolite and the presence of certain CO groups on the carbon. The lack of a well-defined and intense rotational transition line and the persistent broad H2 recoil spectrum in neutron scattering results suggests a distribution of binding sites. Most interestingly, hydrogen diffusion occurs on two time scales, consisting of a fast liquid-like jump diffusion on the timescale of picoseconds along with an even faster bulk-like diffusion. The liquid-like motion is characterized by a diffusion constant of (2.1 ± 0.3) × 10−8 m2/s with an activation energy of ca. 77 K; both values indicate somewhat lower mobility than similar dynamics of H2 on nanotubes, activated carbon XC-72, or Grafoil, yet greater mobility than that of bulk liquid. These unusual characteristics for hydrogen in carbons are believed to arise from the network of narrow pores in this zeolite-templated image of the zeolite. In fact, the diffusion constants of the templated carbons are extremely similar to those measured for zeolite 13X. 相似文献
110.
Khalid Al-Anezi Chris Somerfield David Mee Nick Hankins Nidal Hilal 《Desalination》2008,227(1-3):46-56
The objective of this work is to present experimental data that would show the effect of temperature, salinity, pressure and the presence of anti-scale additives on CO2 solubility in seawater. The paper examines the solubility of CO2 in real seawater and real seawater dosed with two different anti-scale additives. The study has been performed at temperatures between 60ºC and 90ºC and at pressures of 1 and 2 bar. To assess the effect of each anti-scale additive on CO2 gas solubility varying doses, 2–10 ppm of anti-scale additive have been used. For the purpose of the experimentation an experimental rig has been designed to ensure adequate contact between the gas phase and the aqueous phase. The continuous quantitative analysis of CO2 concentration flowing from the experimental rig was measured using a CM-5011 Carbon Coulometer. A mass balance was carried out to calculate the amount of CO2 absorbed into solution; Henry’s law constant was then calculated. 相似文献