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61.
62.
In order to study water-gas transport processes in the gas-diffusion-layer (GDL) of a proton exchange membrane (PEM) fuel cell system, a multiphase, multiple-relaxation-time lattice Boltzmann model is presented in this work. The model is based on the mean-field diffuse interface theory and can handle the multiphase flows with large density ratios and various viscosities. By using the standard bounce back boundary condition and an approximate average scheme for the non-slip and wetting boundary walls, respectively, detailed liquid-gas transportation in the GDL, in which exact boundary condition is difficult to be implemented, can be simulated. Unlike most of lattice Boltzmann methods based on the Bhatnagar–Gross–Krook collision operator, the present model shows a viscosity-independent velocity field, which is very important in simulating multiphase flows where various viscosities coexist. We validate our model by simulating a static droplet on a wetting wall and compare with theoretical predictions. Then, we simulate a water-gas flow in the GDL of a PEM fuel cell and investigate the saturation-dependent transport properties under different conditions. The results are shown to be qualitatively consistent with the previous numerical and theoretical works. 相似文献
63.
RM Bionta G Blewitt CB Bratton D Casper A Ciocio R Claus M Crouch ST Dye S Errede GW Foster W Gajewski KS Ganezer M Goldhaber TJ Haines TW Jones D Kielczewska WR Kropp JG Learned JM LoSecco J Matthews HS Park LR Price F Reines J Schulz S Seidel E Shumard D Sinclair HW Sobel JL Stone L Sulak R Svoboda G Thornton van der Velde JC C Wuest 《Canadian Metallurgical Quarterly》1987,36(1):30-36
64.
一、从政府采购相关利益人心态分析当前治理商业贿赂的难点当前治理政府采购领域商业贿赂采取的主要工作方法是通过调查摸底、对照检查、处理整改和评估验收来进行,这种方式有效与否在很大程度上取决于相关利益人(主体)对此项工作的关注度和认识程度。然而.简单分析政府采购全过程中相关利益人的心态不难看出,单靠这种方法较难使商业贿赂的治理取得实质性效果。 相似文献
65.
Wenwei He Wuping Liao Weiwei Wang Deqian Li Chunji Niu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(9):1314-1320
BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (Kao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (Ea) was calculated to be 21·41 kJ mol?1 or 88·17 kJ mol?1 (dependent on temperature) from the slope of log Kao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (Cmin) is lower than 4·19 × 10?4 mol L?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd3+](a)/dt = kf[Nd3+](a)[H4A](o)0·727[H+](a)?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry 相似文献
66.
Effect of Cerium on Expression and Activity of MMP-9 from Human Carcinoma of Bladder Cell Line 总被引:1,自引:0,他引:1
Rareearthshaveledtowidespreadinterestsinlifescience ,whilethescientistsdoresearchesdeeplyinmedicalandbiochemicalfields .Rareearthsplaypotentialrolesininhibitingcancer ,andalargenum berofscientistsdedicatethemselvestoit[1] .Thema trixmetalloproteinases (MMPs)areafamilyofatleast1 7humanzinc dependentendopeptidasesthatareca pableofdegradingalmostallextracellularmatrix(ECM)components .Theyareessentialinmanyphys iologicalprocessesandseveralpathologicalconditions ,suchastumorprogression .MMPsare… 相似文献
67.
Mushroom-like ZnO microcrystals have been prepared via a solution calcination route, using Zn(NO3)2 as Zn source in the absence of any surfactants, templates or catalysts. This is the first example to prepare mushroom-like crystals as semiconductors, which are expected to show particular physical properties. The ZnO products were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy and photoluminescence (PL) spectrum measurements. A suitable concentration of Zn(NO3)2 solution was important for the growth of the mushroom-like products. The reported synthetic procedure is straightforward and inexpensive, and thus can be readily adopted to produce large quantities of mushroom-like ZnO microcrystals. 相似文献
68.
JD Haag LA Shepel BD Kolman DM Monson ME Benton KT Watts JL Waller CC Lopez-Guajardo DJ Samuelson MN Gould 《Canadian Metallurgical Quarterly》2003,63(18):5808-5812
It has previously been shown that the Copenhagen (COP) rat contains several genetic loci that contribute to its mammary tumor-resistant phenotype after 7,12-dimethylbenz(a)anthracene (DMBA) administration. One of these loci, mammary carcinoma susceptibility 1 (Mcs1), is located on the centromeric end of chromosome 2 and appears to act in a semidominant fashion. To confirm the existence and independent action of this locus and also aid in the identification of the physical location of the Mcs1 gene, congenic lines were generated by transferring the Mcs1 COP allele onto a Wistar Furth (WF) genetic background. Male carriers were genotyped using microsatellite markers spanning 20-30 cM of the Mcs1 locus. One of the congenic lines minimally retained the COP allele at D2Mit29 on the centromeric end of chromosome 2 and extended distally to D2Rat201. Heterozygous Mcs1 carrier rats were interbred, and the female offspring were treated with DMBA. The female rats from the Mcs1 congenic line that carried one or two COP alleles of the Mcs1 region had a significantly reduced (65 and 85%, respectively) tumor development (P < 0.001) compared with rats carrying zero COP alleles at this locus. A WF.COP-D2Mit29/D2Rat201 homozygous congenic strain derived at the N10 generation was treated with DMBA, and the COP homozygous rats developed 1.5 +/- 0.3 carcinomas/rat versus 6.3 +/- 0.5 in WF control rats (P < 0.0001). Fine mapping of this congenic interval using several recombinant lines identified three genetic loci within the Mcs1 congenic region that independently supported a tumor resistance phenotype. These genetic loci have been termed Mcs1a, Mcs1b, and Mcs1c. In rats for which each locus was homozygous for the COP allele, tumor development was reduced by approximately 60% compared with littermate controls. The identification of these independent loci within the Mcs1 COP allele provide a model of the genetic complexity of cancer. 相似文献
69.
PRO——一种新的地震资料处理方法 总被引:2,自引:0,他引:2
PRO(影像的参数展开)技术是由俄罗斯地球物理学家开发的一种崭新的地震资料处理技术。本文从PRO基本原理入手,简单介绍了PRO的速度分析原理。PRO速度分析和成像均以信号的椭圆展开和参数展开为基础,其中参数展开方法考虑波型转换、介质的横向不均匀造成传播速度的变化。该技术抛开了传统共中心点叠加的思想,从根本上解决了以CMP方法为基础的传统地震处理技术遇到的困难。通过模型与实例分析对比,PRO比传统CMP方法更优越。 相似文献
70.
A signal intensity based maximum-likelihood (ML) target location estimator that uses quantized data is proposed for wireless sensor networks (WSNs). The signal intensity received at local sensors is assumed to be inversely proportional to the square of the distance from the target. The ML estimator and its corresponding Crameacuter-Rao lower bound (CRLB) are derived. Simulation results show that this estimator is much more accurate than the heuristic weighted average methods, and it can reach the CRLB even with a relatively small amount of data. In addition, the optimal design method for quantization thresholds, as well as two heuristic design methods, are presented. The heuristic design methods, which require minimum prior information about the system, prove to be very robust under various situations 相似文献