浸渍次序对双元改性HZSM—5上正戊烷芳构化反应的影响

本文研究了不同浸渍次序对Ｚｎ－Ｍ双元改性ＨＺＳＭ－５催化剂芳构化性能的影响。结果表明,对于Ｚｎ－Ｍ双元改性ＨＺＳＭ－５催化剂来讲,先引入Ｚｎ组分,然后再引入Ｃｕ、Ａｌ等其它组分改性效果最佳,而同时引入两种改性组分的效果最差。这种差异是由于改变浸渍次序而引起的表面活性中心的不同造成的。     

p-moment stability of stochastic impulsive differential equations and its application in impulsive control

The exponential p-moment stability of stochastic impulsive differential equations is addressed. A new theorem to ensure the p-moment stability is established for the trivial solution of the stochastic impulsive differential system. As an application of the theorem proposed, the problem of controlling chaos of Lorenz system which is excited by parameter white-noise excitation is considered using impulsive control method. Finally, numerical simulation results are given to verify the feasibility of our approach. Supported by the National Natural Science Foundation of China (Grant No. 10772046)     

我国土地资源配置的“双失”问题及对策研究

摘 要 研究目的:从西方经济学的原理出发,通过对我国土地资源配置中市场失灵和政府失灵问题的分 析,寻求在市场和政府的双重作用机制下土地资源高效配置的实现途径。研究方法:文献资料分析法、比 较分析法。研究结果:在市场经济条件下,单纯地依靠市场或政府,不可能实现我国土地资源的优化配置, 必须将二者结合起来,以规划的宏观调控来弥补和矫正市场失灵的缺陷,但是当前的土地利用规划存在失 效的负面影响。研究结论:应该从加强土地利用规划的政府宏观调控与完善土地市场机制两个途径入手, 实现土地资源的高效配置。     

Deconstructing the semantics of big-step modelling languages

With the popularity of model-driven methodologies and the abundance of modelling languages, a major question for a requirements engineer is: which language is suitable for modelling a system under study? We address this question from a semantic point-of-view for big-step modelling languages (BSMLs). BSMLs are a class of popular behavioural modelling languages in which a model can respond to an input by executing multiple transitions, possibly concurrently. We deconstruct the operational semantics of a large class of BSMLs into eight high-level, mostly orthogonal semantic aspects and their common semantic options. We analyse the characteristics of each semantic option. We use feature diagrams to present the design space of BSML semantics that arises from our deconstruction, as well as to taxonomize the syntactic features of BSMLs that exhibit semantic variations. We enumerate the dependencies between syntactic and semantic features. We also discuss the effects of certain combinations of semantic options when used together in a BSML semantics. Our goal is to empower a requirements engineer to compare and choose an appropriate BSML from the plethora of existing BSMLs, or to articulate the semantic features of a new desired BSML when such a BSML does not exist.     

ASP体系对耐碱砂和石英砂裂缝导流能力影响

实验研究了三元复合体系对石英砂和耐碱树脂砂充填裂缝导流能力影响。结果表明,与弱碱相比较,强碱对石英砂溶蚀作用较强,颗粒破碎率较高,填砂裂缝导流能力降低幅度较大。与石英砂相比较,碱型对耐碱树脂砂溶蚀作用程度差异较小,对耐碱树脂砂填砂裂缝导流能力影响程度差异不大。随闭合压力增加,石英砂和耐碱树脂砂充填裂缝导流能力下降,但降低幅度逐渐减小。与石英砂相比较,闭合压力对耐碱树脂砂充填裂缝导流能力影响程度较小,裂缝导流能力较大。     

用于较大水平位移测量的电阻应变式位移传感器

针对目前位移传感器很难直接测得木结构或木构件在转动中产生较大绝对水平位移的问题,研制了量程为±500 mm的电阻应变式位移传感器（WD位移传感器）,应用正交试验法分析WD位移传感器的影响因素,并对其进行设计与制作,拟合了传感器在不同量程下应变位移的分段函数关系,通过计算得出了WD位移传感器的6种静态参数指标。试验结果表明,WD位移传感器克服了传统电阻应变式位移传感器量程小的问题,解决了木结构或木构件发生非直线运动很难直接测得绝对水平位移的问题,且各静态参数指标良好。     

Synthesis and characterization of soluble aromatic azopolyamides containing sulfone and ether units

A series of new polyamides 3a–d containing aryl-azo, ether and sulfone groups in the main chain were synthesized from bis[4-(4-aminophenoxy)phenyl sulfone] 1 and several azo aromatic diacyl chlorides 2a–d by the low temperature solution polycondensation technique. FTIR spectroscopy, nuclear magnetic resonance (NMR) and elemental analyses confirmed the structure of these polymers. Owing to the aryl and amide groups in the main chain, these polymers exhibit photochromic properties as well as excellent thermal stabilities. The transition temperatures (T _g) are between 242 and 265 °C, and the char yields at 800 °C in nitrogen atmosphere were above 39%. Based on incorporation of flexible ether linkages and polar sulfone groups, the polyamides show desirable solubility in organic solvents such as DMAc, N,N-dimethylformamide (DMF), N-methyl-2-pyrroidinone (NMP) and dimethylsulfoxide (DMSO). And it is exemplified that polyamide containing 2 and 2′ substitutes performed better solubility. Funded by the National Natural Science Foundation of China (No. 50572081)     

The Mechanism of the Eeffect of Mineral Admixtures on the Expansion of Aalkali-silica Reaction

On the base of the influence rule of silica fume, slag and fly ash on alkali-silica reaction under the condition of 70℃, the mechanism of the effect of mineral admixtures on alkali-silica reaction is studied further in the paper. The results show that the effects of mineral admixtures on alkali-silica reaction are mainly chemistry effect and surface physichemistry effect. Under suitable condition, the chemistry effect may make alkali-silica reaction to be inhibited effectively, but the physichemistry effect only make alkali-silica reaction to be delayed. The chemistry effect and the physichemistry effect of minerals admixture are relative to the content of Ca(OH)2 in system. Under the condition that there is a large quantity of Ca(OH)2, mineral admixture cannot inhibit alkali-silica reaction effectively. Only when Ca(OH)2 in the system is very less, it is possible that mineral admixture inhibits alkali-silica reaction effectively.     

纳米TiO2/EVA共混复合材料的制备及其性能

采用熔融共混方法,以直接分散、一步法、二步法3种不同工艺制备出乙烯-醋酸乙烯酯共聚物(EVA)/纳米TiO2复合材料,并探讨了制备工艺与力学性能之间的关系。利用FESEM与FT-IR测试手段表征纳米TiO2微粒在EVA中的分散性及结构。结果表明:将EVA、纳米TiO2和乙烯基三乙氧基硅烷同时进行复合(一步法),可使后两者达到协同增韧EVA的作用,有利于纳米粒子在基体中的分散;一步法工艺最佳,具有补强作用的TiO2微粒在EVA基体中的分散粒径小于100 nm,且当纳米TiO2颗粒的质量分数为1%时,对EVA的改性效果最佳。此外,FT-IR测试表明,纳米TiO2与乙烯基三乙氧基硅烷、EVA之间形成了新的键合结构。     

电流密度对纳米锌镍合金镀层显微组织的影响

采用适当的添加剂在碱性体系中获得了晶粒度为14—33 nm的纳米锌镍合金电镀层。并应用赫尔槽试验、透射电镜(TEM)、扫描电镜(SEM)和X射线衍射(XRD)等技术研究了电流密度对镀层晶体结构的影响。结果表明,在该体系中,在电流密度为0.5—50 A/dm2得到的纳米锌镍合金镀层均为单一的γ-相(N i5Zn21)结构。随电流密度的增加,在低电流密度区镀层的晶粒度由33 nm迅速降至17 nm,在中高电流密度区晶粒度保持在14—17 nm。另外,镀层中还存在亚微米级晶粒团簇,其尺寸随电流密度的增加呈线性增大。