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101.
Synthesis and hydrophilic property of polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA)) 总被引:1,自引:0,他引:1
Nobuo Kawahara Junji Saito Shingo Matsuo Hideyuki Kaneko Tomoaki Matsugi Norio Kashiwa 《Polymer Bulletin》2010,64(7):657-666
Polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA)), which is a hydrophobic-hydrophilic graft copolymer, was synthesized by a combination of an atom transfer radical
polymerization (ATRP) of PEGMA with brominated polypropylene (PP-Br), which was synthesized from PP-OH prepared by metallocene-catalyzed
copolymerization. Its structure was confirmed by 1H NMR and GPC analyses. Transmission electron microscope (TEM) micrographs of PP-g-P(PEGMA) revealed the nanometer level microphase-separation morphology between the PP segment and the P(PEGMA) segment. The
obtained PP-g-P(PEGMA) showed water-absorbing property as well as thermostability. 相似文献
102.
The carbon black/alumina gel composites were prepared by sol-gel reaction of aluminum isopropoxide in the presence of polymer-grafted carbon black. The electric resistance of the alumina gel composite from polymer-grafted carbon black was very sensitive to vapor of good solvent for grafted polymer on carbon black: the electric resistance of the alumina gel composite suddenly decreased in solvent vapor and returned to initial resistance when it was transferred into dry air. The effect of surface area and particle size of carbon black on the responsiveness was also investigated. In addition, the electric resistance of the alumina gel composite was found to respond to water and methanol in n-hexane and diethyl ether. 相似文献
103.
104.
Abstract— Of the two types of thermal‐stress processes for glass, i.e., surface scribing and full body cleavage, the latter is not presently applied in commercial manufacturing due to the technical difficulties, notwithstanding its various advantages. These difficulties, which were pointed out by Kondratenko and were refered to as size effect, consist of a reduced processing speed in a large glass plate and the positional inaccuracy when cleaving close to edges of a glass plate. The result of the investigation aimed to solve these problems, which can pave the way to the commercial application of full body cleavage in the manufacturing of flat‐panel‐display (FPD) devices, is reported. 相似文献
105.
The Green's functions of a point dislocation, a concentrated moment, a normal point force, a couple moment, and a couple bending force applied to an infinite plate with an arbitrarily shaped hole under a displacement boundary condition are derived in this paper. The closed-form stress functions are obtained by using the technique of the rational mapping function and the complex stress function approach. In the derivation, the analytical continuation and Cauchy integral are used for the different actions. Without loss of generality, some calculated results are shown for a square hole under a fixed boundary. The solutions show that the stress functions have different orders of singularity for the different actions. In order to illustrate the stress level due to bending moment and shear force clearly and efficiently, the effective stress of thin plate bending is shown. 相似文献
106.
ARTS: Accelerated Ray-Tracing System 总被引:14,自引:0,他引:14
In this article we propose algorithms that address the two basic problems encountered in generating continuous-tone images by ray tracing: speed and aliasing. We examine previous approaches to the problem and then propose a scheme based on the coherency of an auxiliary data structure imposed on the original object domain. After investigating both simple spatial enumeration and a hybrid octree approach, we developed 3DDDA, a 3D line generator for efficient traversing of both structures. 3DDDA provides an order of magnitude improvement in processing speed compared to other known ray-tracing methods. Processing time is found to be virtually independent of the number of objects involved in the scene. For large numbers of objects, this method actully becomes faster than scan-line methods. To remove jags from edges, a scheme for identifying edge orientation and distance from pixel center to true edge has been implemented. The time required for antialiasing depends on the total length of the edges encountered, but it is normally only a fractional addition to the time needed to produce the scene without antialiasing. 相似文献
107.
108.
The unsteady behavior of flow driven by a jet suddenly injected into a cell is numerically studied by solving the axisymmelric two-dimensional compressible Navier-Stokes equations. The system of the calculation is a model of the laser ablation of a certain duration followed by a discharging process through the exit hole at the down- stream end of the cell. In the calculations, the contour of the cell is changed while other parameters such as the Mach number of the jet, its duration, and the diameter of the cell exit are fixed. Monitoring the velocity at the exit hole is used to investigate the influence of the shape on the interaction between the shock wave and the jet. As the result, it was found that the velocity peak value and its arrival time at the downstream end of the cell exit are determined by the diameter of the cell. 相似文献
109.
110.
Jungo Kondo Aoki K. Kondo A. Ejiri T. Iwata Y. Hamajima A. Mori T. Mizuno Y. Imaeda M. Kozuka Y. Mitomi O. Minakata M. 《Photonics Technology Letters, IEEE》2005,17(10):2077-2079
We present a novel thin-sheet X-cut LiNbO/sub 3/ optical modulator structure which can be fabricated by precise polishing and lapping to obtain a thinner LiNbO/sub 3/ substrate for a lower driving voltage in addition to velocity matching and impedance matching. We demonstrated that the fabricated modulator had a driving voltage V/spl pi/ of 2 V and zero chirp for 40-Gb/s operation and had a high potential for suppressed dc drift, and long-term reliability. 相似文献