Simultaneous analysis of downlink beacon dynamics and skybrightness temperature. Part II. Extraction of amplitude scintillations

This paper addresses the long-standing problem of separating the tropospheric amplitude scintillations from the dominant trend of atmospheric attenuation in a satellite downlink. Following extensive theoretical and experimental work, it is shown how the use of a radiometer coaxial with the communications beacon receiver constitutes an excellent tool for an optimum separation regardless of the meteorological conditions along the propagation path and avoids the use of the long-traditional high-pass filter approach. The experimental and theoretical work has revealed that the angular resolution of the radiometer together with the dynamics of rain attenuation and tropospheric scintillations determine the success of the extraction. This is because fast fadings require large radiometer antennas in order to resolve the sky temperature fluctuations. The dynamic behavior of rain attenuation has been reanalyzed and adapted for this study with special focus on the Maseng-Bakken (MB) model and the impact of the slant path on attenuation dynamics. The importance of the antenna pattern in the time response of the radiometer is studied in detail and permits to derive the maximum Fourier component observable for a given antenna size. The theoretical work has been verified by means of extensive experimental results obtained using a dual radiometer system and a beacon receiver tracking the ITALSAT 39.5 GHz F40 beacon. Finally, because of its importance and direct relevance to future communication systems benefiting from fade countermeasure strategies, the minimum size of the radiometer antenna for a successful extraction of amplitude scintillations is determined as a function of the elevation angle and carrier frequency     

Biodegradability enhancement of a pesticide-containing bio-treated wastewater using a solar photo-Fenton treatment step followed by a biological oxidation process

This work proposes an efficient combined treatment for the decontamination of a pesticide-containing wastewater resulting from phytopharmaceutical plastic containers washing, presenting a moderate organic load (COD = 1662-1960 mg O₂ L⁻¹; DOC = 513-696 mg C L⁻¹), with a high biodegradable organic carbon fraction (81%; BOD₅ = 1350-1600 mg O₂ L⁻¹) and a remaining recalcitrant organic carbon mainly due to pesticides. Nineteen pesticides were quantified by LC-MS/MS at concentrations between 0.02 and 45 mg L⁻¹ (14-19% of DOC). The decontamination strategy involved a sequential three-step treatment: (a) biological oxidation process, leading to almost complete removal of the biodegradable organic carbon fraction; (b) solar photo-Fenton process using CPCs, enhancing the bio-treated wastewater biodegradability, mainly due to pesticides degradation into low-molecular-weight carboxylate anions; (c) and a final polishing step to remove the residual biodegradable organic carbon, using a biological oxidation process. Treatment performance was evaluated in terms of mineralization degree (DOC), pesticides content (LC-MS/MS), inorganic ions and low-molecular-weight carboxylate anions (IC) concentrations. The estimated phototreatment energy necessary to reach a biodegradable wastewater, considering pesticides and low-molecular-weight carboxylate anions concentrations, Zahn-Wellens test and BOD₅/COD ratio, was only 2.3 kJ_UV L⁻¹ (45 min of photo-Fenton at a constant solar UV power of 30 W m⁻²), consuming 16 mM of H₂O₂, which pointed to 52% mineralization and an abatement higher than 86% for 18 pesticides. The biological oxidation/solar photo-Fenton/biological oxidation treatment system achieved pesticide removals below the respective detection limits and 79% mineralization, leading to a COD value lower than 150 mg O₂ L⁻¹, which is in agreement with Portuguese discharge limits regarding water bodies.     

Treatment of a sanitary landfill leachate using combined solar photo-Fenton and biological immobilized biomass reactor at a pilot scale

A solar photo-Fenton process combined with a biological nitrification and denitrification system is proposed for the decontamination of a landfill leachate in a pilot plant using photocatalytic (4.16 m² of Compound Parabolic Collectors - CPCs) and biological systems (immobilized biomass reactor). The optimum iron concentration for the photo-Fenton reaction of the leachate is 60 mg Fe²⁺ L⁻¹. The organic carbon degradation follows a first-order reaction kinetics (k = 0.020 L kJ_UV⁻¹, r₀ = 12.5 mg kJ_UV⁻¹) with a H₂O₂ consumption rate of 3.0 mmol H₂O₂ kJ_UV⁻¹. Complete removal of ammonium, nitrates and nitrites of the photo-pre-treated leachate was achieved by biological denitrification and nitrification, after previous neutralization/sedimentation of iron sludge (40 mL of iron sludge per liter of photo-treated leachate after 3 h of sedimentation). The optimum C/N ratio obtained for the denitrification reaction was 2.8 mg CH₃OH per mg N-NO₃⁻, consuming 7.9 g/8.2 mL of commercial methanol per liter of leachate. The maximum nitrification rate obtained was 68 mg N-NH₄⁺ per day, consuming 33 mmol (1.3 g) of NaOH per liter during nitrification and 27.5 mmol of H₂SO₄ per liter during denitrification. The optimal phototreatment energy estimated to reach a biodegradable effluent, considering Zahn-Wellens, respirometry and biological oxidation tests, at pilot plant scale, is 29.2 kJ_UV L⁻¹ (3.3 h of photo-Fenton at a constant solar UV power of 30 W m⁻²), consuming 90 mM of H₂O₂ when used in excess, which means almost 57% mineralization of the leachate, 57% reduction of polyphenols concentration and 86% reduction of aromatic content.     

Automatic Inspection System of Welding Radiographic Images Based on ANN Under a Regularisation Process

In this paper, we describe an ANN with a modified performance function which is used in an automatic inspection system of welding defects in radiographic images. In a first stage, image processing techniques, including noise reduction, contrast enhancement, thresholding and labelling, were implemented to help in the recognition of weld regions and the detection of weld defects. In a second stage, a set of geometrical features which characterise the defect shape and orientation was proposed and extracted between defect candidates. In a third stage, an artificial neural network for weld defect classification was used under a regularisation process with different architectures for the input layer and the hidden layer. Our aim is to analyse this ANN modifying the performance function using a γ parameter in its function, for different neurons in the input and hidden layer in order to obtain a better performance on the classification stage. The automatic system of recognition and classification proposed consists in detecting the four main types of weld defects met in practice plus the non-defect type. The results was compared with the aim to know the parameters that allow the best classification. The correlation coefficients, confusion matrix and the accuracy or the proportion of the total number of predictions that were correct was determined obtaining a value of 80% for the ANN using a modified performance function with a parameter γ=0.6.     

Biodegradability of kraft mill TCF biobleaching effluents: Application of enzymatic laccase-mediator system

The great amount of pollutants released from kraft pulp processes, mainly from cooking and bleaching stages, is one of the most relevant environmental problems in this type of industry. New bleaching sequences are being studied based on the use of oxidative enzymes from fungal cultures. In this study, the bleaching systems consisting of Laccase and different mediators such as 1-hydroxybenzotriazole, violuric acid, syringaldehyde and methyl syringate in the bleaching sequence of Eucalyptus globulus kraft pulp were applied. The main objective of this study is to evaluate the aerobic and anaerobic biodegradability and toxicity to Vibrium fischeri of generated L-stage and total bleaching sequence effluents.The highest levels of aerobic and anaerobic degradation of the generated effluents were achieved for treatments with laccase plus violuric acid, with 80% of aerobic degradation and 68% of anaerobic biodegradation. V. fischeri toxicity was remarkably reduced for all the effluents after aerobic degradation.