Process and material considerations in the industrial application of lubricants in rigid PVC extrusion

The proper lubrication of rigid PVC compounds often plays an important role in the successful operation of a rigid PVC extrusion plant. Changes in a particular lubricant system can have a substantial effect on the fusion rates of a rigid PVC compound and on the thermodynamics of the fusion process. Recently published research on the morphology of PVC resin and rigid PVC finished products has provided new insights into the morphological changes rigid PVC undergoes during processing. Lubricants can have a substantial impact on the rates and extent of morphological changes of rigid PVC during processing. Successful industrial optimization of a lubricant system involves balancing the rheological characteristics of the compound against the shearing and heating characteristics of the extruder and die tooling. Changes in the extruder and die tooling or lubricant system will result in changes in the work and energy balance. The impact of increases in fusion promoting lubricants, as well as increases in fusion delaying lubricants, on the work and energy balance for a twin screw extruder is explained.     

Hydrocarbon synthesis over sulfide catalysts. Break-down of the Anderson-Schulz-Flory distribution

The kinetics of hydrocarbon synthesis over sulfide-based catalysts was studied. It appears that the formation of methane follows another reaction path than that of higher hydrocarbons. This might explain the very high selectivities for ethane and propane as compared with conventional Fischer-Tropsch catalysts. Reference is made to testing of the catalysts at industrial conditions.     

Physical gelation of crystallizing metallocene and Ziegler-Natta ethylene-hexene copolymers

The effect of molecular architecture on the evolution of viscoelastic properties during crystallization was investigated using ethylene-hexene copolymers manufactured via metallocene (M-LLDPE) and Ziegler-Natta (ZN-LLDPE) processes. Differences in branching distribution were shown to have a drastic effect on the viscoelastic properties near the gel point. It is shown that the branching distribution rather than branch content is the determining parameter for the evolution of the rheological properties during isothermal and non-isothermal crystallization, and for the width of the solidification interval. We developed a partial melting technique for the preparation of stable critical gels of LLDPE whose viscoelastic properties correspond to the intermediate state between melt and solid. Local molecular conformation and crystallinity in these gels were characterized by Raman spectroscopy, which shows that the transition from melt-like to solid-like rheological behavior (physical gelation) in LLDPE occurs at a very low overall crystallinity of less than 5%.     

Experimental study of stable surfaces for anti-slug control in multi-phase flow

Severe slugging flow is always challenging in oil & gas production, especially for the current offshore based production. The slugging flow can cause a lot of problems, such as those relevant to production safety, fatigue as well as capability. As one typical phenomenon in multi-phase flow dynamics, the slug can be avoided or eliminated by proper facility design or control of operational conditions. Based on a testing facility which can emulate a pipeline-riser or a gas-lifted production well in a scaled-down manner, this paper experimentally studies the correlations of key operational parameters with severe slugging flows. These correlations are reflected through an obtained stable surface in the parameter space, which is a natural extension of the bifurcation plot. The maximal production opportunity without compromising the stability is also studied. Relevant studies have already showed that the capability, performance and efficiency of anti-slug control can be dramatically improved if these stable surfaces can be experimentally determined beforehand. The paper concludes that obtaining the stable surface on the new developed map can significantly improve the production rate in a control scheme. Even though the production rate can be further improved by moving the stable surface using advanced control strategies, the constant inputs can in some cases be preferable due to the easier implementation.     

Path‐space Motion Estimation and Decomposition for Robust Animation Filtering

Renderings of animation sequences with physics‐based Monte Carlo light transport simulations are exceedingly costly to generate frame‐by‐frame, yet much of this computation is highly redundant due to the strong coherence in space, time and among samples. A promising approach pursued in prior work entails subsampling the sequence in space, time, and number of samples, followed by image‐based spatio‐temporal upsampling and denoising. These methods can provide significant performance gains, though major issues remain: firstly, in a multiple scattering simulation, the final pixel color is the composite of many different light transport phenomena, and this conflicting information causes artifacts in image‐based methods. Secondly, motion vectors are needed to establish correspondence between the pixels in different frames, but it is unclear how to obtain them for most kinds of light paths (e.g. an object seen through a curved glass panel). To reduce these ambiguities, we propose a general decomposition framework, where the final pixel color is separated into components corresponding to disjoint subsets of the space of light paths. Each component is accompanied by motion vectors and other auxiliary features such as reflectance and surface normals. The motion vectors of specular paths are computed using a temporal extension of manifold exploration and the remaining components use a specialized variant of optical flow. Our experiments show that this decomposition leads to significant improvements in three image‐based applications: denoising, spatial upsampling, and temporal interpolation.     

Improving SCTP retransmission delays for time-dependent thin streams

A large number of network services rely on IP and reliable transport protocols. For applications that provide abundant data for transmission, loss is usually handled satisfactorily, even if the application is latency-sensitive (Wang et al. 2004). For data streams where small packets are sent intermittently, however, applications can occasionally experience extreme latencies (Griwodz and Halvorsen 2006). As it is not uncommon that such thin-stream applications are time-dependent, any unnecessarily induced delay can have severe consequences for the service provided. Massively Multiplayer Online Games (MMOGs) are a defining example of thin streams. Many MMOGs (like World of Warcraft and Age of Conan) use TCP for the benefits of reliability, in-order delivery and NAT/firewall traversal. It has been shown that TCP has several shortcomings with respect to the latency requirements of thin streams because of the way it handles retransmissions (Griwodz and Halvorsen 2006). As such, an alternative to TCP may be SCTP (Stewart et al. 2000), which was originally developed to meet the requirements of signaling transport. In this paper, we evaluate the Linux-kernel SCTP implementation in the context of thin streams. To address the identified latency challenges, we propose sender-side only enhancements that reduce the application-layer latency in a manner that is compatible with unmodified receivers. These enhancements can be switched on by applications and are used only when the system identifies the stream as thin. To evaluate the latency performance, we have performed several tests over various real networks and over an emulated network, varying parameters like RTT, packet loss and amount of competing cross traffic. When comparing our modifications with SCTP on Linux and FreeBSD and TCP New Reno, our results show great latency improvements and indicate the need for a separate handling of thin and thick streams.     

Predictable Surprises

Justifying security expenditures in difficult economic times is problematic at best, career ending at worst. This article provides a methodology to improve the probability of budget success based on risk assessment techniques, proven project management skills, and economics.     

DanNet: the challenge of compiling a wordnet for Danish by reusing a monolingual dictionary

This paper is a contribution to the discussion on compiling computational lexical resources from conventional dictionaries. It describes the theoretical as well as practical problems that are encountered when reusing a conventional dictionary for compiling a lexical-semantic resource in terms of a wordnet. More specifically, it describes the methodological issues of compiling a wordnet for Danish, DanNet, from a monolingual basis, and not—as is often seen—by applying the translational expansion method with Princeton WordNet as the English source. Thus, we apply as our basis a large, corpus-based printed dictionary of modern Danish. Using this approach, we discuss the issues of readjusting inconsistent and/or underspecified hyponymy hierarchies taken from the conventional dictionary, sense distinctions as opposed to the synonym sets of wordnets, generating semantic wordnet relations on the basis of sense definitions, and finally, supplementing missing or implicit information.