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31.
Donglin He Ping Li Wei Wang Qi Wan Jian Zhang Kai Xi Xiumei Ma Zhiwei Liu Lin Zhang Xuanhui Qu 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(5)
Although silicon‐based materials are ideal candidate anodes for high energy density lithium‐ion batteries, the large volumetric expansion seriously damages the integrity of the electrodes and impedes commercial processes. Reasonable electrode design based on adjustable structures of silicon and strong binders prepared by a facile method is still a great challenge. Herein, a three‐pronged collaborative strategy via hollow nanocubes, amorphous Void@SiOx@C, and in situ cross‐linked polyacrylic acid and d ‐sorbitol 3D network binder (c‐PAA‐DS) is adopted to maintain structural/electrode integrality and stability. The all‐integrated c‐PAA‐DS/Void@SiOx@C electrode delivers excellent mechanical property, which is attributed to ductility of the c‐PAA‐DS binder and high adhesion energy between Void@SiOx@C and c‐PAA‐DS calculated by density functional theory. Benefiting from the synergistic effect of accommodation of the hollow structure, protection of outer carbon shell, amorphous Void@SiOx@C, and strong adhesive c‐PAA‐DS binder, c‐PAA‐DS/Void@SiOx@C shows excellent electrochemical performance. Long cycling stability with a reversible capacity of 696 mAh g?1 is obtained, as well as tiny capacity decay after 500 cycles at 0.5 A g?1 and high‐rate performance. The prelithiated Void@SiOx@C||LiNi0.5Co0.2Mn0.3O2 (NCM523) full cell is also assembled and shows a reversible capacity of 157 mAh g?1 at 0.5 C, delivering an excellent capacity retention of 94% after 160 cycles. 相似文献
32.
Microstructure and mechanical property of laser melting deposition (LMD) Ti/TiAl structural gradient material 总被引:1,自引:0,他引:1
This article presents fabrication, microstructure and mechanical properties study of Ti/TiAl functional gradient material. Ti–47Al–2.5V–Cr/Ti–6Al–2Zr–Mo–V gradient material was successfully fabricated by the laser melting deposition (LMD) manufacturing process. Microstructure and chemical composition was characterized by OM, SEM, TEM and EPMA. The Vickers hardness and room-temperature tensile property was evaluated on longitudinal direction. Results showed that fully lamellar (FL) microstructure consisted of γ-TiAl and α2-Ti3Al was formed on the Ti–47Al–2.5V–Cr side, while coarse basket weave microstructure was formed on the Ti–6Al–2Zr–1Mo–1V side. No cracking was found in the gradient zone after aging at 800 °C for 48 h. The room-temperature tensile strength of the as-deposited specimen is up to approximately 1198.8 MPa in the longitudinal direction, while the tensile elongation is approximately 0.4%, indicating a typical brittle fracture. 相似文献
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34.
Shaoming Liang Shanbin Xu Di Qu Luomiao Yang Jingguo Wang Hualong Liu Wei Xin Detang Zou Hongliang Zheng 《International journal of molecular sciences》2022,23(15)
Caffeic acid O-methyltransferase (COMT) is one of the core enzymes involved in lignin synthesis. However, there is no systematic study on the rice COMT gene family. We identified 33 COMT genes containing the methyltransferase-2 domain in the rice genome using bioinformatic methods and divided them into Group I (a and b) and Group II. Motifs, conserved domains, gene structure and SNPs density are related to the classification of OsCOMTs. The tandem phenomenon plays a key role in the expansion of OsCOMTs. The expression levels of fourteen and thirteen OsCOMTs increased or decreased under salt stress and drought stress, respectively. OsCOMTs showed higher expression levels in the stem. The lignin content of rice was measured in five stages; combined with the expression analysis of OsCOMTs and multiple sequence alignment, we found that OsCOMT8, OsCOMT9 and OsCOMT15 play a key role in the synthesis of lignin. Targeted miRNAs and gene ontology annotation revealed that OsCOMTs were involved in abiotic stress responses. Our study contributes to the analysis of the biological function of OsCOMTs, which may provide information for future rice breeding and editing of the rice genome. 相似文献
35.
It is common for subsidiaries of a group company to use the same types of components for producing similar products. Different subsidiary companies may well procure such components from the same suppliers. This paper studies two sourcing management models. One is the Subsidiary-Autonomous Sourcing Management (SD-ASM) where subsidiaries manage their inventories and place purchasing orders independent of each other. The other is the Headquarter-centered Common Sourcing Management (HQ-CSM) where purchasing orders of subsidiaries are processed centrally through some kind of headquarter coordination. In the SD-ASM model, each subsidiary places replenishment orders at a time interval corresponding to their economic order quantity (EOQ). In the HQ-CSM model, two purchasing order management policies are examined. One is the Order Coordination policy in which common replenishment epochs or time periods are proposed by the headquarter and the subsidiaries are encouraged to coordinate the timing of their orders based on the common replenishment epochs. The other is the Order Consolidation policy in which the subsidiaries combine the quantity of their orders and the headquarter places a combined order with the supplier. In the Order Coordination policy, classic RAND heuristic is used to find the best common replenishment epoch and the best replenishment timing of each subsidiary. In the Order Consolidation policy, the optimal order quantity of the combined order is obtained from a mathematical model. The combined order is then allocated to the subsidiaries according to a proportional allocation rule. A series of numerical studies is conducted to compare the costs of the SD-ASM and HQ-CSM policies. The results show that HQ-CSM outperforms SD-ASM in terms of cost and robustness against demand uncertainties. This achievement is largely due to the economies of process (synergistic ordering process), the economies of scale (large order quantity with price discount) and risk pooling effect (transshipments). The results also reveal that the Order Consolidation policy with a combined order always performs better than the Order Coordination policy with common replenishment epochs especially in face of high demand uncertainties and high service level in the global market. 相似文献
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38.
表面n沟CCD的电离辐射损伤 总被引:1,自引:0,他引:1
本文报道了150光敏元表面n沟CCD(电荷耦合器件)在不同能量电子和γ射线辐照后的电离辐射效应。试验结果表明,转移失效率在≤10Gy时已明显增大。但大多数器件在累积剂量≤50Gy时,通过调整“胖零”注入仍可工作。在高剂量辐照期间,不同栅偏压器件的转移效率退化存在较大差异。应用高频和准静态C-V技术分析了参数退化的原因。 相似文献
39.
本文论述了EGR降低柴油机NOX 排放的原理和采用该技术的必要性 ,探讨了柴油机NOX 和EGR率的测量方法 ,以及EGR的控制方法 ,并指出了与EGR相匹配的旨在全面控制柴油机排气污染物的技术。 相似文献
40.
Shuan-yang Zhang Zhi-guo Qu Hong-tao Xu Fariborz-Karimi Talkhoncheh Shun Liu Qiang Gao 《International Journal of Hydrogen Energy》2021,46(54):27700-27708
The gas flow field design has a significant influence on the overall performance of a proton exchange membrane fuel cell (PEMFC). A single-channel PEMFC with wedge-shaped fins in the cathode channel was proposed, and the effects of fin parameters such as volume (0.5 mm3, 1.0 mm3, and 1.5 mm3), number (3, 5, and 9), and porosity of the gas diffusion layer (GDL) (0.2, 0.4, 0.6, and 0.8) on the performance of PEMFC were numerically examined based on the growth rate of power density (GRPD) and polarization curve. It was shown that wedge-shaped fins could effectively improve the PEMFC performance. With an increase in fin volume, the distributions of oxygen mass fraction in the outlet area of the cathode channel were lower, the drainage effect of the PEMFC improved, and GRPD also increased accordingly. Similar results were obtained as the number of fins increased. The GDL porosity had a greater effect than the wedge-shaped fins on the improvement in PEMFC performance, but the influence of GDL porosity weakened and the GRPD of porosity decreased as the porosity increased. This study provides an effective guideline for the optimization of the cathode channel in a PEMFC. 相似文献