国产Ru/Al2O3甲烷化催化剂的工业应用与探讨

对国产Ru/Al2O3催化剂研制开发、侧线试验及工业化试用情况进行了探讨,为国产Ru/Al2O3催化剂的推广应用提供了依据.     

非水解溶胶-凝胶法低温合成硅酸锆

以工业纯ZrCl4、 Si(OC2H5)4为前驱体,通过非水解溶胶-凝胶法合成了硅酸锆.采用DTA-TG和XRD等测试手段研究了凝胶热处理过程中的物相变化.结果表明:当前驱体溶胶中未引入矿化剂时,硅酸锆的合成温度高达1450℃;相比之下,溶胶中引入矿化剂LiF后在600℃下便开始出现了ZrSiO4衍射峰,在700℃合成的硅酸锆不仅合成率高,而且晶体发育好,实现了低温合成硅酸锆的目标.     

Electromagnetic properties of ferroelectric-ferrite ceramic composites

The NiFe₂O₄ and Pb(Zr_0.52Ti_0.48)O₃ ceramic composites are prepared by conventional solid state reaction method. The microstructural and morphological properties of the composites are studied by X-ray diffraction analysis and scanning electron microscopy. Results indicate that the ferrite and piezoelectric phases can co-exist in the composites. The relationship between the dielectric constant and frequency (40 Hz–40 MHz) as well as temperature is also investigated. It is noted that the transition temperature of the composites is about 380 °C. A double electric hysteresis loop is observed in our composites. The magnetic properties are relatively weak according to the magnetic hysteresis loop. With increase in the content of the ferrite phase, the permeability increases. The electromagnetic properties of the as-prepared composites are tunable according to the content of the NiFe₂O₄ phase.     

A novel poly(p-phenylene vinylene)-b-poly(methyl methacrylate) rod-coil diblock copolymer

In this letter, a novel well-defined PPV-b-PMMA rod-coil diblock copolymer, consisting of PPV oligomer as its rod block and PMMA as its coil block, respectively, was prepared via ATRP for the first time. The structure of the copolymer was determined by the measurements of FTIR, ¹H NMR and gel permeation chromatography (GPC). The thermal and optical properties of the copolymers are investigated by DSC, TGA, UV-Vis and photoluminescence (PL) spectra. The results showed that, the introduction of PMMA coil block can improve both the thermal stability and optical properties of PPV oligomer. The highly ordered hexagonally honeycomb-structured film of the copolymer fabricated by vaporizing solvent is also investigated by optical microscope and SEM.     

天然气管道燃压机组的性能试验及见证

结合西气东输管道工程燃气轮机驱动压缩机组设备订货及验收中对性能试验项目的确定、工厂试验及见证过程,介绍了燃压机组性能试验项目所涉及的主要内容、执行标准、需要达到的技术指标,各种性能试验的基本情况,买方参加工厂试验见证中需要重点处理好的问题等。以期为我国其他大型长输天然气管道机组订货及试验见证工作提供借鉴。     

Studies of substrate specificities of lipases from different sources

Although lipases are widely applied in a wide variety of reactions, available information on the factors that are responsible for the substrate specificities of lipases from different sources is scarce. In this paper, nine lipase‐producing microorganism strains were isolated from oil‐containing samples. The properties of these enzymes, including pH optima, temperature optima, thermal stability, and pH stability, vary significantly with the different sources from which these lipases were isolated. The substrate specificities of the nine lipases, including fatty acid and positional specificities, were also studied. The fatty acid specificities of the nine lipases were observably different toward 15 substrates with different carbon chain lengths, different saturation degrees and different side chains. The lipases from S₃ Penicillium citrinum (PCL), MJ₁ Aspergillus niger (ANL), MJ₂ Aspergillus oryzae (AOL), YM Bacillus coughing (BCL), S₉ Geotrichum candidum (GCL), and S₁₁ Candida lypolytica (CLL) showed the strongest specificities to short‐chain esters, and the other lipases showed strong selectivity for medium‐ or long‐chain and branched esters. The positional specificities were examined by analyzing the hydrolytic products of triolein catalyzed by the nine lipases, using TLC. The lipases can be mainly classified into two groups by their specificities for the ester bond at position 2 of triglycerides; one group can selectively hydrolyze the ester bond at position 2 of the triglycerides, the other group cannot. All these nine lipases were divided into four groups by hierarchical clustering analysis on the basis of the results of fatty acid and positional specificities.     

Composite group vector space method for estimating melting and boiling point of pure organic compound

Composition Group Vector Space (CGVS) method for estimating melting and boiling point T _m , T _b of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating T _m , T _b have been established and the numerical values of relative parameters have been presented. The average percentage deviations of T _m , T _b estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability to predict the above properties, compared to conventional group methods.     

导数火焰原子吸收法对调味品中锌的测定

将微量脉冲进样技术和导数火焰原子吸收法结合，建立了测定调味品中锌含量的新方法。该方法的检出限为0．013μg／mL，精密度4．46％，回收率96．67～113．33。