Boosting TiO2-anatase antimicrobial activity: Polymer-oxide thin films

TiO₂ incorporation into an isotactic polypropylene (iPP) polymeric matrix was achieved via a straightforward and cost-effective melting process using laboratory-made nanometric anatase-TiO₂ and an industrial polymer. The structural characteristics of the resulting nanocomposite thin films as a function of the inorganic component content were examined using wide and small angle X-ray scattering (WAXS/SAXS) and vibrational Raman spectroscopy. Electron scanning and transmission microscopy (SEM/TEM) studies were also performed to provide evidence of the nanometric dispersion of the oxide within the polymer matrix, showing the presence of average aggregates of ca. 80 nm. TiO₂ incorporation into the iPP renders self-sterilized nanocomposite films upon light excitation, the activity of which was tested against Gram negative (P. aeruginosa) and positive (E. faecalis) bacteria. TiO₂ displays maximum activity for a sample containing a 2 wt.% of anatase-TiO₂ irrespective of the microorganism nature. The antimicrobial activity of the nanocomposite films is significantly enhanced with respect to that of the oxide alone. This key fact is interpreted on physical basis with the help of a complete optical (UV–vis and photoluminescence) and electron paramagnetic resonance (EPR) characterization.     

Mirror‐based reflection in AmbientTalk

This paper introduces a novel mechanism to perform intercession (a form of reflection) in an object‐oriented programming language with the goal of making the language extensible from within itself. The proposed mechanism builds upon a mirror‐based architecture, leading to a reusable reflective application programming interface that cleanly separates interface from implementation details. However, support for intercession has been limited in contemporary mirror‐based architectures. This is due to the fact that mirror‐based architectures only support reflection explicitly triggered by metaprograms, while intercession requires reflection implicitly triggered by the language interpreter. This work reconciles mirrors with intercession in the context of an actor‐based, object‐oriented programming language named AmbientTalk. We describe this language's full reflective architecture, highlighting its novel mirror‐based approach to reflect upon both objects and concurrently executing actors. Subsequently, we apply AmbientTalk's mirror‐based reflection to implement two language features, which crucially depend on intercession, to wit future‐type message passing and leased object references. Copyright © 2008 John Wiley & Sons, Ltd.     

An ontology,intelligent agent-based framework for the provision of semantic web services

Intelligent agents and semantic web services are two technologies with great potential. Striking new applications can be developed by using the tools and techniques they provide. However, semantic web services need for an upper software entity able to deal with them and, on the other hand agent technology has historically suffered from a number of drawbacks that must be addressed. Integrating these two technologies in a joint environment can overcome their problems while strengthening their advantages. In this paper, the necessity for integrating these technologies and the potential benefits of their combination are analyzed. Based on this study, we present SEMMAS, an ontology-based framework for seamlessly integrating Intelligent Agents and Semantic Web Services. The basics of the framework are detailed and a proof-of-concept implementation described.     

Phosphoric and boric acid activation of pine sawdust

Chemical activation of pine sawdust using aqueous solutions of phosphoric and boric acid was studied. Thermogravimetric analyses of the impregnated lignocellulosic precursor as well as their reactivities are presented. The role of the activating agents in the thermal decomposition of the precursor and their effects on the development of porosity in activated carbons is discussed. The use of boric acid as activating agent and a final heat treatment temperature (HTT) of 600 °C produced some porosity and activated carbons with a surface area of 600 m² g^?1. With a HTT of 450 °C, molecular sieve‐like materials were produced. In contrast, phosphoric acid activation produced activated carbons with high surface areas. The amount of phosphoric acid retained in the precursor was, as expected, a function of the initial concentration as well as the impregnation time and temperature. The fact that the activated carbon porosity increases with the phosphoric acid content per gram of precursor was confirmed. The use of 6 M phosphoric acid solution and HTT of 450 °C produced the activated carbon with the highest surface area, about 1600 m² g^?1. The high degree of microporosity which developed in phosphoric acid‐activated carbons is related to the low reactivity during the thermal treatment of chemical activation. The presence of up to 10% oxygen during HTT with phosphoric acid activation caused only small textural changes. Copyright © 2003 Society of Chemical Industry     

Vicissitudes of autobiographical memories in a bilingual analysis.

Discusses repression in bilingual analyses, including repressed memories, transference, and dreams, as well as the whole associative process. As certain memories are more accessible in one language than the other, repression for bilingual individuals may be partly a function of linguistic accessibility. The concept of repression will therefore need to be reassessed in the context of these observations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Analytical determination of phosphatidylcholine: comparison of HPLC and enzymatic methods

Two analytical techniques for the quantitation of phosphatidylcholine in food samples, high performance liquid chromatography (HPLC) and enzymatic analysis, have been tested in different cocoa powder and lecithin samples. The results given by the two techniques are highly correlated, although there are systematic differences between them. This is attributed to analytical interference due to the nature of the samples.     

Arc crossing minimization in hierarchical digraphs with tabu search

Graphs are used commonly as a basic modeling tool in areas such as project management, production scheduling, line balancing, business process reengineering, and software visualization. An important problem in the area of graph drawing is to minimize arc crossings in a multi-layer hierarchical digraph. Existing solution methods for this problem are based on simple ordering rules for single layers that may lead to inferior drawings. This article first introduces an extensive review of relevant work previously published in this area. Then a tabu search implementation is presented that seeks high-quality drawings by means of an intensification phase that finds a local optimum according to an insertion mechanism and two levels of diversification. Computational experiments with 200 graphs with up to 30 nodes per layer and up to 30 layers are presented to assess the merit of the method.     

C-HEAP: A Heterogeneous Multi-Processor Architecture Template and Scalable and Flexible Protocol for the Design of Embedded Signal Processing Systems

The key issue in the design of Systems-on-a-Chip (SoC) is to trade-off efficiency against flexibility, and time to market versus cost. Current deep submicron processing technologiesenable integration of multiple software programmable processors (e.g., CPUs,DSPs) and dedicated hardware components into a single cost-efficient IC. Ourtop-down design methodology with various abstraction levels helps designingthese ICs in a reasonable amount of time. This methodology starts with a high-levelexecutable specification, and converges towards a silicon implementation.A major task in the design process is to ensure that all components (hardwareand software) communicate with each other correctly. In this article, we tacklethis problem in the context of the signal processing domain in two ways: wepropose a modular, flexible, and scalable heterogeneous multi-processor architecturetemplate based on distributed shared memory, and we present an efficient andtransparent protocol for communication and (re)configuration. The protocolimplementations have been incorporated in libraries, which allows quick traversalof the various abstraction levels, so enabling incremental design. The designdecisions to be taken at each abstraction level are evaluated by means of(co-)simulation. Prototyping is used too, to verify the system's functionalcorrectness. The effectiveness of our approach is illustrated by a designcase of a multi-standard video and image codec.He currently works with Magma Design Automation. E-mail:     

Method Used to Measure the Thermal Diffusivity of Ceramic Materials

A method used to determine the thermal diffusivity of ceramic materials is discussed. This technique uses the readings from at least three equally spaced thermocouples inserted in either powdered or bulk samples of the ceramic material. The method requires that a transient, one-dimensional heat flow, either by heating or cooling, is established in the sample. The values of thermal diffusivity obtained by the present method yield reasonable results in bulk samples of insulating silica blankets and in samples of powdered magnesia.