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71.
R.V. Mangalaraja S. AnanthakumarM. Paulraj H. PesentiMarta López Carlos P. CamurriLoreto A. Barcos Ricardo E. Avila 《Journal of Alloys and Compounds》2012,510(1):134-140
Nanocrystalline samarium doped ceria electrolyte [Ce0.9Sm0.1O1.95] was synthesized by citrate gel combustion technique involving mixtures of cerium nitrate oxidizer (O) and citric acid fuel (F) taken in the ratio of O/F = 1. The as-combusted precursors were calcined at 700 °C/2 h to obtain fully crystalline ceria nano particles. It was further made into cylindrical pellets by compaction and sintered at 1200 °C with different soaking periods of 2, 4 and 6 h. The sintered ceria was characterized for the microstructures, electrical conductivity, thermal conductivity and thermal diffusivity properties. In addition, the combustion derived ceria powder was also analysed for the crystallinity, BET surface area, particle size and powder morphology. Sintered ceria samples attained nearly 98% of the theoretical density at 1200 °C/6 h. The sintered microstructures exhibit dense ceria grains of size less than 500 nm. The electrical conductivity measurements showed the conductivity value of the order of 10−2 S cm−1 at 600 °C with activation energy of 0.84 eV between the temperatures 100 and 650 °C for ceria samples sintered at 1200 °C for 6 h. The room temperature thermal diffusivity and thermal conductivity values were determined as 0.5 × 10−6 m2 s−1 and 1.2 W m−1 K−1, respectively. 相似文献
72.
Carolina Gismene Jorge Enrique Hernndez Gonzlez Angela Rocio Nio Santisteban Andrey Fabricio Ziem Nascimento Lucas dos Santos Cunha Fbio Rogrio de Moraes Cristiano Luis Pinto de Oliveira Caio C. Oliveira Paola Jocelan Scarin Provazzi Pedro Geraldo Pascutti Raghuvir Krishnaswamy Arni Ricardo Barros Mariutti 《International journal of molecular sciences》2022,23(17)
Staphylococcal exfoliative toxins (ETs) are glutamyl endopeptidases that specifically cleave the Glu381-Gly382 bond in the ectodomains of desmoglein 1 (Dsg1) via complex action mechanisms. To date, four ETs have been identified in different Staphylococcus aureus strains and ETE is the most recently characterized. The unusual properties of ETs have been attributed to a unique structural feature, i.e., the 180° flip of the carbonyl oxygen (O) of the nonconserved residue 192/186 (ETA/ETE numbering), not conducive to the oxyanion hole formation. We report the crystal structure of ETE determined at 1.61 Å resolution, in which P186(O) adopts two conformations displaying a 180° rotation. This finding, together with free energy calculations, supports the existence of a dynamic transition between the conformations under the tested conditions. Moreover, enzymatic assays showed no significant differences in the esterolytic efficiency of ETE and ETE/P186G, a mutant predicted to possess a functional oxyanion hole, thus downplaying the influence of the flip on the activity. Finally, we observed the formation of ETE homodimers in solution and the predicted homodimeric structure revealed the participation of a characteristic nonconserved loop in the interface and the partial occlusion of the protein active site, suggesting that monomerization is required for enzymatic activity. 相似文献
73.
74.
Pre-term infants, that are not breast-fed, are deprived of vital intrauterine fat accretion during late pregnancy and must
rely on formula to obtain fatty acids essential for normal development, particularly of the visual system. Preterm infants
(30 wk postconception) receiving human milk were compared to infants given one of the following formulae: Formula A was a
commercial preterm formula with predominantly 18∶2ω6 (24.2%) and low (0.5%) 18∶3ω3; Formula B was based on soy oil and contained
similar 18∶2ω6 levels (20%) and high 18∶3ω3 (2.7%); Formula C was also a soy oil-based formula (20% 18∶2, 1.4% 18∶3) but was
supplemented with marine oil to provide ω3 long-chain polyunsaturated fatty acids (LCP) at a level (docosahexaenoic acid,
DHA, 0.35%) equivalent to human milk. At entry (10 days of age), the fatty acid composition of plasma and red blood cell (RBC)
membrane lipids of the formula groups were identical. By 36 wk postconception, the DHA content in lipids of group A was significantly
reduced compared to that in the human milk and marine oil formula groups. Omega-3 LCP results were further amplified by 57
wk with compensatory increases in 22∶5ω6 in both plasma and RBC lipids. Provision of 2.7% α-linolenic acid in formula group
B was sufficient to maintain 22∶6ω3 levels equivalent to those in human milk-fed infants at 36 wk but not at 57 wk. Effects
on the production of thiobarbituric acid reactive substances and fragility of RBC attributable to the marine oil supplementation
were negligible. The results support the essentiality of ω3 fatty acids for preterm infants to obtain fatty acid profiles
comparable to infants receiving human milk. Formula for preterm infants should be supplemented with ω3 fatty acids including
LCP.
Based on a paper presented at the Symposium on Milk Lipids held at the AOCS Annual Meeting, Baltimore, MD, April 1990. 相似文献
75.
Angulo J Ojeda R de Paz JL Lucas R Nieto PM Lozano RM Redondo-Horcajo M Giménez-Gallego G Martín-Lomas M 《Chembiochem : a European journal of chemical biology》2004,5(1):55-61
Six synthetic heparin-like oligosaccharides have been used to investigate the effect of the oligosaccharide sulfation pattern on the stimulation of acidic fibroblast growth factor (FGF-1) induced mitogenesis signaling and the biological significance of FGF-1 trans dimerization in the FGF-1 activation process. It has been found that some molecules with a sulfation pattern that does not contain the internal trisaccharide motif, which has been proposed for high affinity for FGF-1, stimulate FGF-1 more efficiently than those with the structure of the regular region of heparin. In contrast to regular region oligosaccharides, in which the sulfate groups are distributed on both sides of their helical three-dimensional structures, the molecules containing this particular sulfation pattern display the sulfate groups only on one side of the helix. These results and the fact that these oligosaccharides do not promote FGF-1 dimerization according to sedimentation-equilibrium analysis, confirm the importance of negative-charge distribution in the activation process and strongly suggest that FGF dimerization is not a general and absolute requirement for biological activity. 相似文献
76.
Laura de Andrade Souza Denise Ramos Moreira Nágila Maria Pontes Silva Ricardo Martin Edmund Maier Paulo Roberto Campos Flexa Ribeiro Filho Francisco Murilo Tavares Luna Cesar Liberato Petzhold 《Journal of the American Oil Chemists' Society》2023,100(2):175-184
Vegetable oils are very promising alternatives to fossil lubricants due to their abundance, low cost, excellent performance, and environmental friendliness. Due to its multifunctional structure, castor oil is an excellent precursor in the synthesis of new biolubricants. However, it showed poor thermal-oxidative stability and a higher pour point. This study used castor oil fatty acids prepared by transesterification (EHRO), epoxidation (TEPO), and oxirane ring opening with the aromatic amines aniline (ANIL) and p-anisidine (ANIS). The chemical structure of these oils was verified by 1H and 13C NMR analysis, and mass spectrometry. Measurements show that the presence of an aromatic amine increases the viscosity resulting in 172 (ANIL) and 199 (ANIS) cSt at 40°C, but reduces viscosity index to 16 and 1, respectively. In addition, the amine groups can scavenge radicals increasing their thermal and oxidative stability. These products do not oxidize copper, and tribological analysis reveals that ANIS has the lowest torque with wear equivalent to commercial mineral lubricant NH-140. 相似文献
77.
Odinei Hess Gonçalves Fernanda Vitória Leimann Pedro Henrique Hermes de Araújo Ricardo Antonio Francisco Machado 《应用聚合物科学杂志》2013,130(6):4521-4527
Structured micrometric polystyrene/poly(methyl methacrylate) particles were obtained by suspension polymerization and their expansion behavior was investigated using n‐pentane as blowing agent. The expanded particles presented two distinct microstructures with an outer region (PMMA‐rich shell) composed by cells of about 10 µm while the center of the particle (PS‐rich core) had much larger cells (50–100 μm). The core–shell particles did not expand at 100°C meaning that the PMMA shell hindered the expansion of the particles. Maximum expansion was dependent on the PMMA concentration and also on the heating temperature and the increase in the PMMA molar mass led to a delay in the onset of the process. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4521–4527, 2013 相似文献
78.
79.
The drying of carrot particles (6 mm × 6 mm × 12 mm) was studied in a tunnel dryer; a vacuum-freeze dryer, either with or without infrared radiation; a pulsed fluidized-bed dryer assisted by microwave radiation; and combinations of these methods. The effect of two freezing rates (quick freezing in liquid nitrogen and slow freezing in a household freezer) was also studied. The drying kinetics for these drying methods were determined and modeled, and the dried products were subjected to texture (hardness), color, and rehydration analysis, as well as 2D and 3D image analysis of pictures from scanning electron microscope. The combination of freeze drying with other dehydration techniques reduces the drying time by 6–70%, although, in general, the structural damage increases with respect to freeze drying alone. The hybrid drying systems did not show significant differences in drying times either for quick- or slow-frozen samples. The combination of freeze drying followed by conventional drying reduces the drying time between 23 and 40% on average. The Page empirical model represents adequately the entire drying process for combined methods, with specific parameters for each drying zone. The values of effective diffusivity calculated with the simplified constant diffusivity model agree with those reported in the literature. 相似文献
80.
Soybean (Glycine max (L.) Merr.) is the most important oilseed in the world market. Seed quality has a direct influence on the success of the crop and contributes significantly to productivity levels. The quality of soybean seeds can be influenced by several factors during drying. This study evaluated the drying of soybean seeds in a fixed bed dryer, considering the heterogeneity of the process and the effect of process variables on seed quality. Seed and air temperatures, seed moisture, and seed quality were measured throughout the bed. Empirical equations were obtained relating seed quality indicators, at several bed axial positions, as a function of process variables. 相似文献