Infrared laser ablation atmospheric pressure photoionization mass spectrometry

In this paper we introduce laser ablation atmospheric pressure photoionization (LAAPPI), a novel atmospheric pressure ion source for mass spectrometry. In LAAPPI the analytes are ablated from water-rich solid samples or from aqueous solutions with an infrared (IR) laser running at 2.94 μm wavelength. Approximately 12 mm above the sample surface, the ablation plume is intercepted with an orthogonal hot solvent (e.g., toluene or anisole) jet, which is generated by a heated nebulizer microchip and directed toward the mass spectrometer inlet. The ablated analytes are desolvated and ionized in the gas-phase by atmospheric pressure photoionization using a 10 eV vacuum ultraviolet krypton discharge lamp. The effect of operational parameters and spray solvent on the performance of LAAPPI is studied. LAAPPI offers ~300 μm lateral resolution comparable to, e.g., matrix-assisted laser desorption ionization. In addition to polar compounds, LAAPPI efficiently ionizes neutral and nonpolar compounds. The bioanalytical application of the method is demonstrated by the direct LAAPPI analysis of rat brain tissue sections and sour orange (Citrus aurantium) leaves.     

Polymeric dual-slab waveguide interferometer for biochemical sensing applications

A polymer based dual-slab waveguide Young's interferometer was demonstrated for biochemical sensing. Evanescent field is utilized for probing the binding events of biomolecules on the waveguide surface. Refractive index sensing in analyte and protein adsorption on the sensing surface were investigated with glucose de-ionized water solution and bovine serum albumin, immunoglobulin G solutions in phosphate buffered saline buffer. A detection limit of 10(-5) RIU and 4 pg/mm(2) was achieved for homogeneous and surface sensing, respectively. Also, the influence of water absorption inside the polymeric device on the measurement stability was evaluated. The results indicate that the waveguide polymer sensor fabricated with the spin coating technique can achieve a satisfactory sensitivity for homogeneous refractive index sensing and, as well, for monitoring molecular binding events on the surface.     

Energy-efficient control strategy for variable speed-driven parallel pumping systems

The article aims to find a solution for the energy efficiency improvements in variable speed-controlled parallel pumping systems with lesser initial data and without additional flow metering and start-up measurements. This paper introduces a new control strategy for variable speed-controlled parallel pumps based on flow rate estimation and pump operation analysis utilizing variable speed drives. The energy-saving potential of the new control strategy is studied with simulations and laboratory measurements. The energy consumption of the parallel pumps using the new control strategy is compared with the traditional rotational speed control strategy of parallel pumps. The benefit of the new control strategy is the opportunity to operate variable speed-controlled parallel pumps in a region which suggests improved energy efficiency and lower risk of mechanical failure of the controlled pumps compared with traditional control. The article concludes by discussing the implications of the findings for different applications and varying system conditions.     

Hydrolysis behaviour of crosslinked poly(ester anhydride) networks prepared from functionalised poly(ε-caprolactone) precursors

Biodegradable poly(ester anhydride) networks based on functionalised poly(ε-caprolactone) precursors with different hydrophobicities, molecular weights and architectures were synthesised. Networks that were prepared from the star-shaped precursors clearly showed higher gel contents and crosslinking densities than the networks that were prepared from the linear precursors. Functionalising with different alkenylsuccinic anhydrides and/or varying the molecular weight of the precursor, the thermal properties, surface hydrophobicity and erosion of the crosslinked networks were widely tailored. The dissolution behaviour of the networks changed dramatically as the molecular weight of the precursor increased from 2000 to 4000 g/mol or the alkenyl chain of the alkenylsuccinic anhydride increased from 8 to 18 carbons. The networks that were prepared from the lower molecular weight precursors, without an alkenyl chain or with an 8 carbon alkenyl chain, lost their mass in a few days, whereas the networks that were prepared from higher molecular weight precursors or contained a hydrophobic 18 carbon alkenyl chain did not show any mass loss over a period of 8 weeks.     

Optimization issues of the broke management system in papermaking

This paper presents an optimization strategy for the design and operation of a broke management system in a papermaking process. A stochastic model based on a two-state Markov process is presented for the broke system and a multiobjective and bi-level stochastic optimization model is developed featuring (i) a multiobjective operational subproblem for the optimization of the broke dosage and (ii) a multiobjective design problem formulation. An efficient optimization strategy is proposed for the operational subproblem along with a simulation based Pareto optimal solution for the design problem, and illustrated with a detailed case study.     

The correlation between the interference colour and growth procedure of anodic titanium dioxide nanotube arrays

Titanium dioxide nanotube arrays were anodised from titanium foils in an aqueous electrolyte solution of hydrofluoric acid. The formed oxide showed visually different colours owing to light interference in the titanium dioxide layer. The behaviour of interference colour in anodic titanium dioxide film was investigated by varying anodisation parameters such as the applied voltage and the anodisation time. The morphologies and the crystalline phases of anodised samples were studied on a field emission scanning electron microscope and X‐ray diffractometer. The correlation between the interference colour and growth procedure of anodic titanium dioxide nanotube arrays was studied. The anodic films prepared under different conditions consisted of a compact oxide film with a nanoporous/tubular structure upon/beneath it. The crystalline phase of the anodic oxide layer was amorphous. The optical properties of the oxide film were investigated on a spectrophotometer. Optical interference could be detected in compact oxide layers when the thickness of the titanium dioxide was as small as 70 nm. In general, the interferences of the nanoporous/tubular structures were lower than those for compact structures. The empirical colour properties were estimated by the L*a*b* system. The relationships between the interference colour of anodic titanium dioxide film and its thickness and morphology are discussed.     

New Technologies in Ammonia Refrigerating and Air-Conditioning Systems

This review paper describes a brief historic perspective of transition from natural refrigerants to synthetic and now back to natural refrigerants. The thermodynamic, physical and safety properties of ammonia are presented. The advantages and disadvantages of ammonia refrigerant are discussed. The heat exchanger technology has seen introduction of compact and efficient equipment both in shell and tube and plate technologies. The micro-channel exchangers are being introduced in the automotive industry and it could soon enter into the commercial and industrial refrigeration markets. Compact heat exchangers are of interest due to their low refrigerant inventory features. A new electromotor technology is being developed now, using encapsulated copper windings or aluminum windings for semi-hermetic ammonia compressors. A hermetic scroll compressor for ammonia small refrigerating systems is also in the offing. In the last several years large numbers of air conditioning systems with ammonia chillers have been installed in commercial and public facilities. In large industrial systems where there is a need for low evaporating temperatures, Ammonia/Carbon Dioxide cascade systems are being proposed and installed.     

Drying of Solid Furl Particlbs in Hot Gases

ABSTRACT

Drying of solid fuel particles in hot gases ( 50–200c) is studied both theoretically and experimentally. The measurements are carried out by using a thermobalance reactor constructed for drying and pyrolysis studies of particles up to 30 mm by diameter. The model is based on the solution of the conservation equations for mass and energy. The drying is considered to consist of three successive periods: a short initial heating period, period of constant rate of drying and period of falling rate of drying. It is assumed that the particle moisture distribution is uniform during the constant rate of drying. Shrinking core model is assumed for the falling rate period. esides fuel particles, the model is applicable also for other solid particle drying processes. Model calculations are compared to measurements for wood chips. The model can predict the efFect of the main parameters reasonably well. These main parameters affecting the drying rate are: particle size, particle shape, initial particle moisture content, gas temperature and gas moisture content, emperature of the reactor walls and slip velocity. The irregular shape of practical fuel particles can approximately be simulated as one-dimensional case ( plate, cylinder, sphere) by using an equivalent volumc to surface area ratio.     

Capacities of Physical Layer Scheduling Strategies on a Shared Link

We compare capacities of three physical layer scheduling algorithms: on-off scheduling (OOS), maximum SNR, and round robin schedulers. With OOS, downlink transmission is suspended if the instantaneous received SNR in the mobile station falls below a given threshold requiring only one feedback bit per user, which considerably decreases the overhead of the feedback signaling when compared with maximum SNR scheduler. In case of FDD systems, OOS and maximum SNR schedulers require a fast feedback channel from mobile to base station like the one in the FDD WCDMA system, while round robin operates independently of the channel state. We derive asymptotic capacity gains of the three schedulers in high SNR region and study the effect of feedback bit errors to capacities. It is noticed that OOS has an optimal threshold, which depends on the number of users and their mean SNRs. As expected, maximum SNR scheduler provides the largest capacity among the three schedulers, but if additional spatial diversity, i.e., transmit antenna selection is available, the difference between the capacities of OOS and maximum SNR schedulers is small.     

Transmit Diversity in the WCDMA System

This document presents the transmit diversityconcept adopted for the FDD mode of the thirdgenerationWCDMA system in ETSI in 1998. The open-loop mode isbased on the space-time block code attaining full diversity order with two transmit antennas.Different feedback modes are specified. They all utilizeterminal measurements in controlling the transmitweighting in the transmit antennas. The concept is described in detail for two transmit antennas.It is shown that very limited feedback from the terminalto the base, as defined for the FDD mode, can increasedownlink performance significantly when compared to single-antenna transmission.