Acceptance testing of fluoroscopy systems used for interventional purposes

This study presents the results of acceptance testing on 18 interventional fluoroscopy systems in Ireland. Acceptance testing and routine quality assurance (QA) of X-ray systems are the requirements of the EU Medical Exposures Directive (MED) and these requirements were subsequently implemented into Irish legislation. The MED states that special consideration should be given to the QA and dose assessment of high dose procedures such as interventional fluoroscopy. Owing to the advances in fluoroscopy technology, it has been found that comprehensive testing of interventional systems proves challenging in a busy hospital environment. A number of recurrent problems have been identified and are presented.     

A training syllabus for radiation protection in dental radiology

The EU Council Directive 97/43/EURATOM (MED) states that Member States shall ensure that adequate theoretical and practical training is provided for dental practitioners working with ionising radiation; this also includes the provision of continuing education and training programmes, post-qualification. The area of dental radiology is specifically mentioned in this legally binding document. The Department of Medical Physics and Bioengineering, St James's Hospital, Dublin, is particularly interested in the area of radiation protection training and routinely provides educational courses both at national and international levels. A recent review of their dental radiation protection course was undertaken in conjunction with a number of Principal Dental Surgeons within the Health Service Executive in Ireland. The revised course was delivered to over 200 dental staff members at two separate meetings during 2006. The response from attendees was very positive. It is proposed to extend this course to other dental professionals, working both in the Irish private and public health sectors in the future.     

Exposures to transit and other sources of noise among New York City residents

To evaluate the contributions of common noise sources to total annual noise exposures among urban residents and workers, we estimated exposures associated with five common sources (use of mass transit, occupational and nonoccupational activities, MP3 player and stereo use, and time at home and doing other miscellaneous activities) among a sample of over 4500 individuals in New York City (NYC). We then evaluated the contributions of each source to total noise exposure and also compared our estimated exposures to the recommended 70 dBA annual exposure limit. We found that one in ten transit users had noise exposures in excess of the recommended exposure limit from their transit use alone. When we estimated total annual exposures, 90% of NYC transit users and 87% of nonusers exceeded the recommended limit. MP3 player and stereo use, which represented a small fraction of the total annual hours for each subject on average, was the primary source of exposure among the majority of urban dwellers we evaluated. Our results suggest that the vast majority of urban mass transit riders may be at risk of permanent, irreversible noise-induced hearing loss and that, for many individuals, this risk is driven primarily by exposures other than occupational noise.     

Large‐scale optimization strategies for pressure swing adsorption cycle synthesis

Pressure swing adsorption (PSA) is an efficient method for gas separation and is a potential candidate for carbon dioxide (CO₂) capture from power plants. However, few PSA cycles have been designed for this purpose; the optimal design and operation of PSA cycles for CO₂ capture, as well as other systems, remains a very challenging task. In this study, we present a systematic optimization‐based formulation for the synthesis and design of novel PSA cycles for CO₂ capture in IGCC power plants, which can simultaneously produce hydrogen (H₂) and CO₂ at high purity and high recovery. Here, we apply a superstructure‐based approach to simultaneously determine optimal cycle configurations and design parameters for PSA units. This approach combines automatic differentiation, efficient ODE solvers for the state and sensitivity equations of the PSA model, and state of the art nonlinear programming solvers. Three optimization models are proposed, and two PSA case studies are considered. The first case study considers a binary separation of H₂ and CO₂ at high purity, where specific energy is minimized, whereas the second case study considers a larger five component separation. © 2012 American Institute of Chemical Engineers AIChE J, 58: 3777–3791, 2012     

Pre-rigor temperature and the relationship between lamb tenderisation,free water production,bound water and dry matter

The M. longissimus from lambs electrically stimulated at 15 min post-mortem were removed after grading, wrapped in polythene film and held at 4 (n = 6), 7 (n = 6), 15 (n = 6, n = 8) and 35 °C (n = 6), until rigor mortis then aged at 15 °C for 0, 4, 24 and 72 h post-rigor. Centrifuged free water increased exponentially, and bound water, dry matter and shear force decreased exponentially over time. Decreases in shear force and increases in free water were closely related (r² = 0.52) and were unaffected by pre-rigor temperatures.     

Application of a novel microwave plasma treatment for the sintering of nickel oxide coatings for use in dye-sensitized solar cells

In this study the use of microwave plasma sintering of nickel oxide (NiO_x) particles for use as p-type photoelectrode coatings in dye-sensitized solar cells (DSSCs) is investigated. NiO_x was chosen as the photocathode for this application due to its stability, wide band gap and p-type nature. For high light conversion efficiency DSSCs require a mesoporous structure exhibiting a high surface area. This can be achieved by sintering particles of NiO_x onto a conductive substrate. In this study the use of both 2.45 GHz microwave plasma and conventional furnace sintering were compared for the sintering of the NiO_x particles. Coatings 1 to 2.5 μm thick were obtained from the sintered particles (mean particle size of 50 nm) on 3 mm thick fluorine-doped tin oxide (FTO) coated glass substrates. Both the furnace and microwave plasma sintering treatments were carried out at ~ 450 °C over a 5 min period. Dye sensitization was carried out using Erythrosin B and the UV–vis absorption spectra of the NiO_x coatings were compared. A 44% increase in the level of dye adsorption was obtained for the microwave plasma sintered samples as compared to that obtained through furnace treatments. While the photovoltaic performance of the DSSC fabricated using the microwave plasma treated NiO_x coatings exhibited a tenfold increase in the conversion efficiency in comparison to the furnace treated samples. This enhanced performance was associated with the difference in the mesoporous structure of the sintered NiO_x coatings.     

Simulations and measurements of in‐mold melt flow during the injection molding of polystyrene

Simulations are often used to model polymer flow during injection molding to design molds and select processing parameters. It is difficult to determine the accuracy of these simulations due to a lack of experimentally measured in‐mold velocimetry and melt‐front progression data. This article compares the results from commercial mold‐filling simulation software to experimental data obtained via particle image velocimetry (PIV) in a special optical‐access mold with a rectangular cavity. Moldflow was used to simulate the mold filling by a polystyrene melt in the experimental configuration, and these simulated results are compared to the appropriately averaged time‐varying velocity field measurements. Simulated results for melt‐front progression are also compared with experimentally observed flow fronts. The ratio of the experimentally measured average velocity magnitudes to the simulation magnitudes was found on average to be 0.99 with a standard deviation of 0.25, and the difference in velocity orientations was found to be 0.9° with a standard deviation of 3.2°. The corner area opposite the gate was most problematic for the simulation. The region behind the front also had a relatively high simulation error, though not as severe as that in the corner. POLYM. ENG. SCI. 2013. © 2012 Society of Plastics Engineers     

Rhabdopeptides as Insect‐Specific Virulence Factors from Entomopathogenic Bacteria

Six novel linear peptides, named “rhabdopeptides”, have been identified in the entomopathogenic bacterium Xenorhabdus nematophila after the discovery of the corresponding rdp gene cluster by using a promoter trap strategy for the detection of insect‐inducible genes. The structures of these rhabdopeptides were deduced from labeling experiments combined with detailed MS analysis. Detailed analysis of an rdp mutant revealed that these compounds participate in virulence towards insects and are produced upon bacterial infection of a suitable insect host. Furthermore, two additional rhabdopeptide derivatives produced by Xenorhabdus cabanillasii were isolated, these showed activity against insect hemocytes thereby confirming the virulence of this novel class of compounds.