Crystallographic Texture and Volume Fraction of <Emphasis Type="Italic">α</Emphasis> and <Emphasis Type="Italic">β</Emphasis> Phases in Zr-2.5Nb Pressure Tube Material During Heating and Cooling

The phase transformations in an as-received Zr-2.5Nb pressure tube material were characterized in detail by neutron diffraction. The texture and volume fraction of α and β phases were measured on heating at eight different temperatures 373 K to 1323 K (100 °C to 1050 °C) traversing across the α/(α + β) and (α + β)/β solvus lines, and also upon cooling at 1173 K and 823 K (900 °C and 550 °C). The results indicate that the α-phase texture is quite stable, with little change in the {0002} and { 11[`2]0 } \left\{ {11\bar{2}0} \right\} pole figures during heating to 1123 K (850 °C). The β-phase volume fraction increased while a slight change in texture was observed until heating reached 973 K (700 °C). On further heating to 1173 K (900 °C), there appears a previously unobserved α-phase texture component due to coarsening of the prior primary α grains; meanwhile the transformed β-phase texture evolved markedly. At 1323 K (1050 °C), the α phase disappeared with only 100 pct β phase remaining but with a different texture than that observed at lower temperatures. On cooling from the full β-phase regime, a different cooldown transformed α-phase texture was observed, with no resemblance of the original texture observed at 373 K (100 °C). The transformed α-phase texture shows that the {0002} plane normals are within the radial-longitudinal plane of the pressure tube following the Burgers orientation relationship of (110)<sub>bcc</sub>//(0002)<sub>hcp</sub> and [[`1]11]_\textbcc //[11[`2]0]_\texthcp [\bar{1}11]_{\text{bcc}} //[11\bar{2}0]_{\text{hcp}} with a memory of the precursor texture of the primary α grains observed on heating at 1173 K (900 °C).     

Angiotensin-I Converting Enzyme (ACE) Inhibitory and Anti-Oxidant Activities of Sea Cucumber (Actinopyga lecanora) Hydrolysates

In recent years, food protein-derived hydrolysates have received considerable attention because of their numerous health benefits. Amongst the hydrolysates, those with anti-hypertensive and anti-oxidative activities are receiving special attention as both activities can play significant roles in preventing cardiovascular diseases. The present study investigated the angiotensin-I converting enzyme (ACE) inhibitory and anti-oxidative activities of Actinopyga lecanora (A. lecanora) hydrolysates, which had been prepared by alcalase, papain, bromelain, flavourzyme, pepsin, and trypsin under their optimum conditions. The alcalase hydrolysate showed the highest ACE inhibitory activity (69.8%) after 8 h of hydrolysis while the highest anti-oxidative activities measured by 2,2-diphenyl 1-1-picrylhydrazyl radical scavenging (DPPH) (56.00%) and ferrous ion-chelating (FIC) (59.00%) methods were exhibited after 24 h and 8 h of hydrolysis, respectively. The ACE-inhibitory and anti-oxidative activities displayed dose-dependent trends, and increased with increasing protein hydrolysate concentrations. Moreover, strong positive correlations between angiotensin-I converting enzyme (ACE) inhibitory and anti-oxidative activities were also observed. This study indicates that A. lecanora hydrolysate can be exploited as a source of functional food owing to its anti-oxidant as well as anti-hypertension functions.     

Feasibility of pulse combustion in micro gas turbines

In gas turbines, a fast decrease of efficiency appears when the output decreases; the efficiency of a large gas turbine (20…30 MW) is in the order of 40 %, the efficiency of a 30 kW gas turbine with a recuperator is in the order of 25 %, but the efficiency of a very small gas turbine (2…6 kW) in the order of 4…6 % (or 8…12 % with an optimal recuperator). This is mainly a result of the efficiency decrease in kinetic compressors, due to the Reynolds number effect. Losses in decelerating flow in a flow passage are sensitive to the Reynolds number effects. In contrary to the compression, the efficiency of expansion in turbines is not so sensitive to the Reynolds number; very small turbines are made with rather good efficiency because the flow acceleration stabilizes the boundary layer. This study presents a system where the kinetic compressor of a gas turbine is replaced with a pulse combustor. The combustor is filled with a combustible gas mixture, ignited, and the generated high pressure gas is expanded in the turbine. The process is repeated frequently, thus producing a pulsating flow to the turbine; or almost a uniform flow, if several parallel combustors are used and triggered alternately in a proper way. Almost all the compression work is made by the temperature increase from the combustion. This gas turbine type is investigated theoretically and its combustor also experimentally with the conclusion that in a 2 kW power size, the pulse flow gas turbine is not as attractive as expected due to the big size and weight of parallel combustors and due to the efficiency being in the order of 8 % to 10 %. However, in special applications having a very low power demand, below 1000 W, this solution has better properties when compared to the conventional gas turbine and it could be worth of a more detailed investigation.     

Cuckoo search for wind farm optimization with auxiliary infrastructure

This paper focuses on the optimization problem of a wind farm layout. This area of research is currently receiving widespread attention, as optimal positioning of the turbines promotes the financial viability of the wind farm and enhances the competitiveness of wind projects in the energy market. In this work, cuckoo search (CS), a modern population‐based metaheuristic optimization algorithm, is used. The objective is to find the turbine layout and types that maximize the net present value of the wind farm, while constraints on the turbine positions have to be met. The following constraints are considered: Firstly, the minimum distance between turbines for safe operation; secondly, a realistic wind farm shape including forbidden zones for installation and the existing infrastructure. Furthermore, the optimization of the wind farm includes an algorithm to find the least expensive layout of the wind farm roads and the electrical collector system. The algorithm is based on Dijkstra's shortest path and Prim's minimum spanning tree algorithms. The test results indicate that the infrastructure cost has a significant effect on the optimum wind farm solution. A genetic algorithm, commonly applied to wind farm micro‐siting problems, is used to benchmark the performance of the CS. The results show that the CS is capable of consistently finding better solutions than the genetic algorithm.     

PUFAs in Fish: Extraction,Fractionation, Importance in Health

ABSTRACT: Polyunsaturated fatty acids (PUFAs), especially eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), are currently in demand in the pure form and actively being studied to understand their potential roles in human health. Arachidonic acid, 20:4 (n‐6), and DHA, 22:6 (n‐3), are important in normal neurodevelopment and visual function. Infants fed formula often have low blood lipid 20:4 (n‐6) and 22:6 (n‐3). Consumption of fish oils may increase the 20:5 (n‐3) (EPA) and 22:6 (n‐3) (DHA) in human blood. Some marine fish oils contain higher amounts of arachidonic acid, EPA, and DHA. PUFA contents in different marine fishes and methods for their extraction and fractionation, in terms of fatty acid constituents in the form of methyl esters, are covered in this review. Emphasis is given to the fractionations of EPA and DHA by means of supercritical fluid extractions (SFE). The advantages of SFE compared to conventional methods are discussed in this review. PUFAs are usually extracted at about 10 to 30 MPa and at 40 to 80 °C. SFE is a promising and currently the best technique to extract PUFAs, especially EPA and DHA, from marine and freshwater fish.     

Characterization of ten H2 producing cyanobacteria isolated from the Baltic Sea and Finnish lakes

The genetic background and activities of the enzymes involved in H₂ production were investigated from ten distinct H₂ producing cyanobacteria, revealed by a recent screening. All strains are N₂-fixing, filamentous and heterocystous. Southern hybridization revealed that the tested strains possess the genes encoding the conventional nitrogenase (nifHDK1), and lack the alternative nitrogenases. The high H₂ production rate of these strains was shown not to be dependent on the presence of highly active nitrogenase or bidirectional hydrogenase enzymes. Moreover, most of the strains possessed a highly active uptake hydrogenase enzyme. We also examined the structure of the nif and hup operons encoding nitrogenase and uptake hydrogenase enzymes in the Calothrix 336/3 strain, the best H₂ producer in the screening. We concluded that the ability of the cyanobacteria to produce high levels of H₂ is not directly linked to the maximum capacities of the enzymes involved in H₂ production.