Fabrication of HAp–8YSZ composite layer on Ti/TiO2 nanoporous substrate by EPD/MAO method

Zirconia/Hydroxyapatite composites containing 20–50 wt.% 8YSZ were prepared on Ti/TiO₂ substrates by electrophoretic deposition (EPD)/micro-arc oxidation (MAO) process. Titania, as an inner layer, was grown on the Ti plates using MAO treatment in order to form a strong join between substrate and HAp. These composites were produced by EPD in ethanol containing ZrO₂/HAp particles at 50, 100 and 150 V in 1 min. As-prepared samples were sintered at 900, 1100 and 1300 °C. HAp, β-TCP, CaZrO₃ phases were identified using X-ray diffractometry analysis (XRD). Scanning electron microscopy (SEM) utilized to study the surface morphology indicated a crack free microstructure at 1300 °C.     

On the formulation design and rheological evaluations of pectin-based functional gels

In the current study, formulation design and development of a novel pectin-based functional gel were investigated. Amidated low methoxyl pectin (ALMP), high methoxyl pectin (HMP), sorbitol, inulin, rebaudioside-A, gardenia, phloridzin, quercetin, apple flavor, and calcium chloride (as its dihydrated salt) were selected as general ingredients. Response surface methodology was applied to design different formulations and to investigate on their experimental responses. The oscillatory tests were carried out in 2 stages with ALMP, HMP, sorbitol, and inulin as the variables of the 1st stage and ALMP and calcium chloride as the variables of the 2nd stage. Results of the 1st stage indicated relatively similar behaviors throughout the frequency range applied for all of the samples studied (true gels). However, magnitudes of the 5 rheological parameters of this study (storage modulus, loss modulus, loss tangent, complex modulus, and complex viscosity) were affected by different variables (ALMP, HMP, inulin, and sorbitol concentrations). Experimental results confirmed that sorbitol could be omitted from the formula while inulin and HMP could be used at their highest levels studied. At the 2nd stage, only 2 formulas indicated a strong gel behavior and other formulas showed typical behaviors of weaker gels or those of the concentrated solutions. At the conclusion of this study, a finished gelled product formula was suggested with the application of the best levels of the ingredients. The resultant gel was found to be set rapidly with no syneresis and showed a potential to be considered as a functional gelled dessert.     

Three dimensional static and dynamic analysis of thick functionally graded plates by the meshless local Petrov–Galerkin (MLPG) method

In this paper, three dimensional (3D) static and dynamic analysis of thick functionally graded plates based on the Meshless Local Petrov–Galerkin (MLPG) is presented. Using the kinematics of a three-dimensional continuum, the local weak form of the equilibrium equations is derived. A weak formulation for the set of governing equations is transformed into local integral equations on local sub-domains using a Heaviside step function as test function. In this case, governing equations corresponding to the stiffness matrix do not involve any domain integration or singular integrals. Nodal points are distributed in the 3D analyzed domain and each node is surrounded by a cubic sub-domain to which a local integral equation is applied. The meshless approximation based on the three-dimensional Moving Least-Square (MLS) is employed as shape function to approximate the field variable of scattered nodes in the problem domain. The Newmark time integration method is used to solve the system of coupled second-order ODEs. Effective material properties of the plate, made of two isotropic constituents with volume fractions varying only in the thickness direction, are computed using the Mori–Tanaka homogenization technique. Numerical examples for solving the static and dynamic response of elastic thick functionally graded plates are demonstrated. As a result, the distributions of the deflection and stresses through the plate thickness are presented for different material gradients and boundary conditions. The effects of the volume fractions of the constituents on the centroidal deflection are also investigated. The numerical efficiency of the proposed meshless method is illustrated by the comparison of results obtained from previous literatures.     

Preparation of nanocrystalline MgO by surfactant assisted precipitation method

Nanocrystalline magnesium oxide with high surface area was prepared by a simple precipitation method using pluronic P123 triblock copolymer (Poly (ethylene glycol)-block, Poly (propylene glycol)-block, Poly (ethylene glycol)) as surfactant and under refluxing conditions. The prepared samples were characterized by X-ray diffraction (XRD), N₂ adsorption (BET) and scanning and transmission electron microscopies (SEM and TEM). The obtained results revealed that the refluxing time and temperature and the molar ratio of surfactant to metal affect the structural properties of MgO, because of the changes in the rate and extent of P123 adsorption on the prepared samples. The results showed that the addition of surfactant is effective to prepare magnesium oxide with high surface area and affects the morphology of the prepared samples. With increasing the P123/MgO molar ratio to 0.05 the pore size distribution was shifted to larger size. The sample prepared with addition of surfactant showed a plate-like shape which was completely different with the morphology of the sample prepared without surfactant. The formation of nanoplate-like MgO was related to higher surface density of Mg ions on the (0 0 1) plane than that on the other planes of the Mg(OH)₂ crystal. The (0 0 1) plane would be blocked preferentially by the adsorbed P123 molecules during the growing process of Mg(OH)₂ nanoentities and the growth on the (0 0 1) plane would be markedly restricted, and the consequence is the generation of nanoplate-like MgO. In addition, increase in refluxing temperature and time increased the specific surface area of the prepared MgO samples.     

A nodal link perceptron network with applications to control of anonholonomic system

A new perceptron neural network (PNN) for functional approximation and control of a general class of nonlinear systems is introduced. The basic structure of the network along with the conditions for its exponential convergence under a suitable training law are derived. A novel discrete-time control strategy is formulated that employs the PNN for direct online estimation of the feedforward control input. The developed controller can be applied to both discrete- and continuous-time plants. Unlike most of the existing direct adaptive or learning schemes, the nonlinear plant is not assumed to be feedback linearizable. The developed controller is then applied for tracking control of a nonholonomic (free-flying) robot. The simulation results of this application demonstrate a perfect tracking performance after the network is fully trained.     

Experimental Study and Numerical Simulation of the Large-Scale Testing of Polymeric Composite Journal Bearings: Two-Dimensional Modeling and Validation

The self-lubricating properties of some polymeric materials make them very valuable in bearing applications, where the lubrication is difficult or impossible. Composite bearings combine the self-lubricating properties of polymeric materials with better mechanical and thermal properties of the fibers. At present, there are few studies about these bearings and their design is mainly based on manufacturers’ experiences. This study includes an experimental and numerical study of the large-scale testing of fiber-reinforced polymeric composite bearings. In the first part of this article, a new tribological test setup for large composite bearings is demonstrated. Besides, a two-dimensional finite-element model is developed in order to study the stress distribution in the composite bearing and kinematics of the test setup. A mixed Lagrangian–Eulerian formulation is used to simulate the rotation of the shaft and the contact between the composite bearing and the shaft. Simulation results correspond closely to the experimental data, and provide careful investigation of the stress distribution in the bearing. In the second part of this article, three-dimensional quasi-static and two-dimensional dynamic models are studied.     

Precision control of a piezo-actuated micro telemanipulation system

Piezoelectric actuators are widely used in micro manipulation applications. However hysteresis nonlinearity limits accuracy of these actuators. This paper presents a novel approach for utilizing a piezoelectric nano-stage as slave manipulator of a teleoperation system. The Prandtl-Ishlinskii (PI) model is used to model actuator hysteresis in feedforward scheme to cancel out this nonlinearity. To deal with the influence of parametric uncertainties, unmodeled dynamics, and PI identification error a perturbation term is added to the slave model and apply a sliding mode based impedance control with perturbation estimation. The stability of the entire system is guaranteed by Llewellyn’s absolute stability criterion. Performance of the proposed controllers is verified through experiments.     

A novel chelate-assisted C−C bond formation on a Cd(II) complex of an asymmetric heptadentate(N7) tripodal Schiff base ligand

Cadmium(II) complexes of some potentially heptadentate tripodal Schiff base ligands with the general formula N{(CH₂)_nNCHC₅H₄N}₂{(CH₂)_mNCHC₅H₄N}) (where n = m = 2, L₂₂₂; n = 2, m = 3, L₃₂₂; n = 3, m = 2, L₃₃₂) have been studied. These ligands are products of the full condensation of a number of tripodal tetraamines with 2-pyridinecarboxaldehyde. An unusual reaction of an additional 2-pyridine-carboxaldehyde with a methylene group adjacent to the imine bond only during template preparation of [Cd(L₃₃₂)]²⁺ was observed. The latter reaction is a novel chelate-assisted C?C bond formation because it is occurred only where a rigid five-membered chelate ring is present.     

Dynamische Steifigkeit und Dämpfung von Pfahlgruppen

Dynamic stiffness and damping properties of pile groups. The dynamic stiffness and damping properties of pile‐groups have been investigated in this paper. Also, the substantial influence of these properties on an economic structure and foundation design is demonstrated. The analysis has been carried out using the “Thin‐Layer‐Method”, which is a very efficient and powerful analysis procedure in frequency domain.     

Concentrations of polychlorinated biphenyls in indoor air and polybrominated diphenyl ethers in indoor air and dust in Birmingham, United Kingdom: implications for human exposure

Polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) were measured in air (using PUF disk passive samplers) in 31 homes, 33 offices, 25 cars, and 3 public microenvironments. Average concentrations of sigmaBDE (273 pg m(-3)) and sigmaPCB (8920 pg m(-3)) were an order of magnitude higher than those previously reported for outdoor air. Cars were the most contaminated microenvironment for sigmaBDE (average = 709 pg m(-3)), but the least for sigmaPCB (average = 1391 pg m(-3)). Comparison with data from a previous spatially consistent study, revealed no significant decline in concentrations of sigmaPCB in indoor air since 1997-98. Concentrations in indoor dust from 8 homes were on average 215.2 ng sigmaBDE g(-1), slightly higher than other European dust samples, but twenty times lower than Canadian samples. Inhalation makes an important contribution (between 4.2 and 63% for adults) to overall UK exposure to sigmaPCB. For sigmaBDE, dust ingestion makes a significant but--in contrast to Canada-a not overwhelming contribution (up to 37% for adults, and 69% for toddlers). Comparison of UK and Canadian estimates of absolute exposure to sigmaBDE suggest that differences in dust contamination are the likely cause of higher PBDE body burdens in North Americans compared to Europeans.