Experimental evaluation of quinolinium and isoquinolinium derivatives as corrosion inhibitors of mild steel in 0.5 M H<Subscript>2</Subscript>SO<Subscript>4</Subscript> solution

The 1-methylquinolinium iodide (I) Qui⁺, I^– and 2-methylisoquinolinium iodide isoQui⁺, I^– were investigated as a corrosion inhibitors for mild steel in sulfuric acid using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that the corrosion inhibition efficiency and extent of surface coverage were increased with increase in inhibitors concentrations. Polarization curves revealed that both inhibitors acted as a mixed-type inhibitor. The thermodynamic parameters were evaluated for corrosion inhibition process. The adsorption of both inhibitors on mild steel surface obeyed Langmuir adsorption isotherm.     

Comparison of Oxidation Stability and Quenchant Cooling Curve Performance of Soybean Oil and Palm Oil

The potential use of vegetable oil-derived industrial oils continues to be of great interest because vegetable oils are relatively non-toxic, biodegradable, and they are a renewable basestock alternative to petroleum oil. However, the fatty ester components containing conjugated double bonds of the triglyceride structure of vegetable oils typically produce considerably poorer thermal-oxidative stability than that achievable with petroleum basestocks under typical use conditions. Typically, these conditions involve furnace loads of hot steel (850 °C), which are rapidly immersed and cooled to bath temperatures of approximately 50-60 °C. This is especially true when a vegetable oil is held in an open tank with agitation and exposed to air at elevated temperatures for extended periods of time (months or years). This paper will describe the thermal-oxidative stability and quenching performance of soybean oil and palm oil and the resulting impact on the heat transfer coefficient. These results are compared to typical fully formulated, commercially available accelerated (fast) and an unaccelerated (slow) petroleum oil-based quenchants.     

Eco-friendly Geopolymer Composite Based on Non-heat-treated Phosphate Sludge Reinforced With Polypropylene Fibers

Silicon - Geopolymers produced with metakaolin (MK) and thermally untreated phosphate sludge (PS) are beneficial and environmentally advantageous materials, but their fragility limits its...     

In Vivo Analysis of the Biocompatibility and Bone Healing Capacity of a Novel Bone Grafting Material Combined with Hyaluronic Acid

The present in vivo study analyses both the inflammatory tissue reactions and the bone healing capacity of a newly developed bone substitute material (BSM) based on xenogeneic bone substitute granules combined with hyaluronate (HY) as a water-binding molecule. The results of the hyaluronate containing bone substitute material (BSM) were compared to a control xenogeneic BSM of the same chemical composition and a sham operation group up to 16 weeks post implantationem. A major focus of the study was to analyze the residual hyaluronate and its effects on the material-dependent healing behavior and the inflammatory tissue responses. The study included 63 male Wistar rats using the calvaria implantation model for 2, 8, and 16 weeks post implantationem. Established and Good Laboratory Practice (GLP)-conforming histological, histopathological, and histomorphometrical analysis methods were conducted. The results showed that the new hyaluronate containing BSM was gradually integrated within newly formed bone up to the end of the study that ended in a condition of complete bone defect healing. Thereby, no differences to the healing capacity of the control BSM were found. However, the bone formation in both groups was continuously significantly higher compared to the sham operation group. Additionally, no differences in the (inflammatory) tissue response that was analyzed via qualitative and (semi-) quantitative methods were found. Interestingly, no differences were found between the numbers of pro- and anti-inflammatory macrophages between the three study groups over the entire course of the study. No signs of the HY as a water-binding part of the BSM were histologically detectable at any of the study time points, altogether the results of the present study show that HY allows for an optimal material-associated bone tissue healing comparable to the control xenogeneic BSM. The added HY seems to be degraded within a very short time period of less than 2 weeks so that the remaining BSM granules allow for a gradual osteoconductive bone regeneration. Additionally, no differences between the inflammatory tissue reactions in both material groups and the sham operation group were found. Thus, the new hyaluronate containing xenogeneic BSM and also the control BSM have been shown to be fully biocompatible without any differences regarding bone regeneration.     

Physicochemical Properties of Different Types of Starch Phosphate Monoesters

Different types of starch were phosphorylated to different degrees of substitution using monosodium and disodium hydrogen orthophosphate at 160 °C under vacuum. Generally, phosphation enhanced the physicochemical properties of the modified starches compared to their native counterparts. Solubility and swelling power greatly increase when phosphorylation was carried out to a low degree of substitution, while the solubility and swelling power decreased gradually by increasing the degree of substitution. However, the values of the monoesters were still higher than those of the corresponding native polysaccharides. Viscosities of different starch types except corn amylose showed the highest values at the lowest degree of substitution, when the degree of phosphation increased the viscosity values decreased. Native potato starch formed a clear paste (96% transmittance) due to the presence of phosphate groups while the paste clarity of potato starch decreased gradually by increasing the degree of phosphation. Generally, phosphorylation increased the light transmittance of the other starches investigated at the lowest degree of substitution but the clarity decreased by increasing the degree of substitution.     

Egyptian Mango Juice. Experiment on Storage Experience

In this study processed mango juice was packed in four types of containers and stored at different temperatures for 16 weeks through which furfural level determination and organoleptic assessment were conducted. The experiment revealed an evident relationship to exist among furfural level, storage temperature and type of packing material. Furfural level failed to closely parallel flavour difference; therefore it could be regarded as one of the features concomitant juice aging rather than accepted as a satisfactory criterion of off flavour. The study relates flavour deterioration to the changes in the lipid fraction of the juice.     

Instruction-Level Fault Tolerance Configurability

Due to modern technology trends such as decreasing feature sizes and lower voltage levels, fault tolerance (FT) is becoming increasingly important in computing systems. Several schemes have been proposed to enable a user to configure the FT at the application level, thereby enabling the user to trade stronger FT for performance or vice versa. In this paper, we propose supporting instruction-level rather than application-level configurability of FT, since different parts of some applications (e.g., multimedia) can have different reliability requirements. Weak or no FT will be applied to less critical parts, resulting in time and/or resource gains. These gains can be used to apply stronger FT techniques to the more critical parts; hence increasing the overall reliability. The paper shows how some existing FT techniques can be adapted to support instruction-level FT configurability, how a programmer can specify the desired FT level of the instructions, and how the compiler can manage it automatically. A comparison between the existing FT scheme EDDI (which duplicates all instructions) and the proposed approach is performed both at the kernel and at full application levels. The simulation results show that both the performance and the energy consumption are significantly improved (up to 50% at the kernel and up to 16% at full application level), while the fault coverage depends on the application. For the full application (JPEG encoder), our approach is only applied to one kernel in order to avoid increasing the programming effort significantly.

Randomized data selection in detection with applications to distributed signal processing

Performing robust detection with resource limitations such as low-power requirements or limited communication bandwidth is becoming increasingly important in contexts involving distributed signal processing. One way to address these constraints consists of reducing the amount of data used by the detection algorithms. Intelligent data selection in detection can be highly dependent on a priori information about the signal and noise. In this paper, we explore detection strategies based on randomized data selection and analyze the resulting algorithms' performance. Randomized data selection is a viable approach in the absence of reliable and detailed a priori information, and it provides a reasonable lower bound on signal processing performance as more a priori information is incorporated. The randomized selection procedure has the added benefits of simple implementation in a distributed environment and limited communication overhead. As an example of detection algorithms based upon randomized selection, we analyze a binary hypothesis testing problem, and determine several useful properties of detectors derived from the likelihood ratio test. Additionally, we suggest an adaptive detector that accounts for fluctuations in the selected data subset. The advantages and disadvantages of this approach in distributed sensor networks applications are also discussed.