Evaluation of Water Content and Ionic Concentrations of Soils via Frequency Domain Analysis of TDR Waveform

This study addresses the development of a method for evaluating the water content and ionic concentrations of subsurface polluted soils by analyzing the TDR waveforms in the frequency domain. Soil specimens were prepared with different water contents and NaCl concentrations. A known electrical pulse with multiple harmonics was generated and induced through soil specimens. Reflected signals were then analyzed in the frequency domain and represented in terms of the magnitude and phase shift. Multivariate statistical analysis was performed for various magnitudes and phase shifts, which are dependent on water content and concentrations. Regression equations were obtained; hence, for a known reflected amplitude and phase shift, water content and ionic concentrations could be determined.     

Simple Technique for Observing Subsurface Damage in Machining of Ceramics

A simple technique is proposed for directly observing subsurface damage in the machining of ceramics. The technique requires two polished specimens and an optical microscope with Nomarski illumination for examination. The subsurface damage created by the grinding of an alumina ceramic is investigated using this technique. The mode of damage is identified as intragrain twinning/slip, and intergranular and transgranular cracking. Chipping along the twinned planes and along the transgranular crack planes, and dislodgement of the intergranularly debonded grains are suggested to be the mechanisms of material removal in the machining of this alumina ceramic.     

ABRASIVE MACHINING OF GLASS-INFILTRATED ALUMINA WITH DIAMOND BURS

The abrasive machining characteristics of a glass-infiltrated alumina used for fabrication of all-ceramic dental crowns were investigated using a high-speed dental handpiece and diamond burs with different grit sizes. The material removal rate, surface roughness, and extent of edge chipping were measured as a function of grit size. The removal rate decreased substantially with decreasing bur grit size from supercoarse (180 μm) to fine (40 μm) and ultrafine (10 μm). The removal rate with the supercoarse burs was approximately twice that achieved with the fine burs and four times the removal rate with the ultrafine burs. Both surface roughness and edge chipping damage were sensitive to diamond grit size. Chipping damage was severe and the surface roughness substantial with the supercoarse burs, while negligible edge chipping and smooth surfaces were obtained with the ultrafine burs. The removal rate also decreased with continued machining for all grit sizes. The observed reduction in removal rate was found to be primarily due to wear of the diamond grit and accumulation of debris on the bur (i.e., bur loading). After prolonged use, a significant loss of diamond grit was observed that led to a substantial loss of cutting efficiency. It is concluded that, with respect to material removal rate and surface integrity, diamond machining is a feasible machining process for glass-infiltrated alumina in the final infiltrated state. However, caution should be exercised in the use of diamond grit larger than 40 μm. Such burs may result in excessively rough surfaces, chipped edges, and strength limiting surface and subsurface microcracks.     

DNA microarray detection of nitrifying bacterial 16S rRNA in wastewater treatment plant samples

A small scale DNA microarray containing a set of oligonucleotide probes targeting the 16S rRNAs of several groups of nitrifying bacteria was developed for the monitoring of wastewater treatment plant samples. The microarray was tested using reference rRNAs from pure cultures of nitrifying bacteria. Characterization of samples collected from an industrial wastewater treatment facility demonstrated that nitrifying bacteria could be detected directly by microarray hybridization without the need for PCR amplification. Specifically, the microarray detected Nitrosomonas spp. but did not detect Nitrobacter. The specificity and sensitivity of direct detection was evaluated using on-chip dissociation analysis, and by two independent analyses--an established membrane hybridization format and terminal restriction fragment length polymorphism fingerprinting (T-RFLP). The latter two analyses also revealed Nitrospira and Nitrobacter to be contributing populations in the treatment plant samples. The application of DNA microarrays to wastewater treatment systems, which has been demonstrated in the current work, should offer improved monitoring capabilities and process control for treatment systems, which are susceptible to periodic failures.     

Differences and Commonalities in Physical,Chemical and Mineralogical Properties of Zanzibari Geophagic Soils

The function of human geophagy has long been questioned. We sought to test hypotheses concerning its potential physiological effects through analysis of soils and patterns in geophagy behavior. Eleven samples of geophagic soils consumed by pregnant women on Pemba Island, Zanzibar, Tanzania, were characterized according to their color, texture, major element chemistry, trace element chemistry, bulk mineralogy, and clay mineralogy. An epidemiological study (N = 2367) and ethnographic interviews (N = 57) on Pemba yielded information about geophagic behaviors and socio-demographic and biological characteristics of those who consumed earth. The soils varied widely in color, ranging from light red to white through various shades of brown and yellow, and texture ranged from clay to sand. Major element chemistry of the soils also varied greatly; most were low in Fe and Ca. Trace elements, whether of biological or non-biological significance, were uniformly low when compared with normal ranges of mineral soils. The sole commonality among the samples is that all clay fractions were dominated by a kaolin mineral: kaolinite, halloysite, or a mixture of both. Geophagy behavior also varied greatly, with one major exception: a greater proportion of pregnant women (7.1%) and young children (4.5%) consumed earth than non-pregnant women (0.2%) or men (0%). The presence of kaolin mineral in all samples, its palliative and detoxifying properties, and the highest prevalence of geophagy among those most biologically vulnerable suggest that geophagy may be a protective behavior.     

On codes over quaternion integers

Decoding algorithms for the correction of errors for cyclic codes over quaternion integers of quaternion Mannheim weight one up to two coordinates are discussed by Özen and Güzeltepe (Eur J Pure Appl Math 3(4):670–677, 2010). Though, Neto et al. (IEEE Trans Inf Theory 47(4):1514–1527, 2001) proposed decoding algorithms for the correction of errors of arbitrary Mannheim weight. In this study, we followed the procedures used by Neto et al. and suggest a decoding algorithm for an $n$ length cyclic code over quaternion integers to correct errors of quaternion Mannheim weight two up to two coordinates. Furthermore, we establish that; over quaternion integers, for a given $n$ length cyclic code there exist a cyclic code of length $2n-1$ . The decoding algorithms for the cyclic code of length $2n-1$ are given, which correct errors of quaternion Mannheim weight one and two. In addition, we show that the cyclic code of length $2n-1$ is maximum-distance separable (MDS) with respect to Hamming distance.     

Removal of lead from aqueous solutions with a treated spent bleaching earth

A spent bleaching earth from an edible oil refinery has been treated by impregnation with a normal sodium hydroxide solution followed by mild thermal treatment (100 degrees C). The obtained material (TSBE) was washed, dried and characterized by X-ray diffraction, FTIR, SEM, BET and thermal analysis. The clay structure was not apparently affected by the treatment and the impregnated organic matter was quantitatively removed. We have investigated the sorption of lead on this material, the spent bleaching earth (SBE) and the virgin bleaching earth (VBE). The kinetic results fit the pseudo second-order kinetic model and the Weber & Morris, intraparticle diffusion model. The pH had effect on the sorption efficiency. The sorption isotherms followed the Langmuir model for various sorbent concentrations with good values of determination coefficient. A comparison between the results obtained with this material and those of the literature highlighted a good removal capacity of the treated spent bleaching earth at low cost.