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41.
Cellular mechanisms for developmental toxicity of chlorpyrifos: targeting the adenylyl cyclase signaling cascade 总被引:8,自引:0,他引:8
X Song FJ Seidler JL Saleh J Zhang S Padilla TA Slotkin 《Canadian Metallurgical Quarterly》1997,145(1):158-174
Developmental neurotoxicity caused by chlorpyrifos exposure is generally thought to target cholinesterase but chlorpyrifos may also act on cellular intermediates, such as adenylyl cyclase, that serve global functions in the coordination of cell development. In the current study, neonatal rats were exposed to apparently subtoxic doses of chlorpyrifos (no weight loss, no mortality) either on Postnatal Days 1-4 or on Postnatal Days 11-14, and the effects on components of the adenylyl cyclase cascade were evaluated in brain regions that are enriched (forebrain) or sparse (cerebellum) in cholinergic innervation, as well as in a nonneural tissue (heart). In all three, chlorpyrifos evoked deficits in multiple components of the adenylyl cyclase cascade: expression and activity of adenylyl cyclase itself, functioning of G-proteins that link neurotransmitter and hormone receptors to cyclase activity, and expression of neurotransmitter receptors that act through this cascade. Disruption of signaling function was not restricted to transduction of cholinergic signals but rather extended to adrenergic signals as well. In most cases, the adverse effects were not evident during the immediate period of chlorpyrifos administration, but appeared after a delay of several days. These results suggest that chlorpyrifos can affect cell development by altering the activity and reactivity of the adenylyl cyclase signaling cascade, a major control point for trophic regulation of cell differentiation. The effects are not restricted to cholinergic targets, nor even to the central nervous system. Hence, disruption of cell development by chlorpyrifos is likely to be more widespread than previously thought. 相似文献
42.
Y. Xun R. Rodriguez E. J. Lavernia F. A. Mohamed 《Metallurgical and Materials Transactions A》2005,36(10):2849-2859
The present article deals with the processing and microstructural evolution of powder metallurgy (PM) Zn-22Al pct eutectoid
alloy. The powder material was produced through inert gas atomization and then cryomilled in liquid nitrogen. The milled powder
particles were consolidated by hot isostatic pressing (“hipping”) followed by thermomechanical treatment, resulting in a two-phase
microstructure. The microstructures were characterized using scanning electron microscopy (SEM) and transmission electron
microscopy (TEM). The principal processing factors and microstructural characteristics associated with the major processing
steps, including spray atomization, mechanical milling (MM), consolidation, and heat treatment, were evaluated and discussed.
Hot isostatic pressing and extrusion followed by heat treatment to produce the superplastic structure (Al-rich phase and Zn-rich
phase) are effective in elimination porosity. A TEM examination of the microstructure of the alloy after processing reveals
the presence of nanodispersion particles that are not uniformly distributed. The formation of the dispersions was attributed
to the interaction between the powder material (primarily Al phase) and environmental elements such as oxygen and nitrogen
during milling. Moreover, the size and distribution of the dispersions present in the bulk material met the anticipated requirements
for serving as inhibitors for grain growth and barriers for dislocation movement. The TEM observations on crept specimens
reveal extensive dislocation/dispersion interactions. 相似文献
43.
44.
A space reactor power system (SRPS) has been developed for avoidance of single point failures in reactor cooling and energy conversion. The sectored compact reactor (SCoRe) in this system is lithium-cooled and the reactor core is divided into six equal sectors with liquid metal heat pipes dividers. These reactor sectors are neutronically, but not thermal-hydraulically, coupled. Each sector has its own primary and secondary circulating lithium loops, which are thermally coupled both in a SiGe thermoelectric (TE) power conversion assembly (PCA) and a thermoelectric conversion assembly (TAC) that powers the electromagnetic pumps in the primary and secondary loops. Each secondary loop also has a separate, segmented radiator panel that is optimized for low specific mass and low liquid lithium inventory. The primary loops transport the thermal power generated in the reactor to six PCAs that nominally supply a total of 111.5 kWe to the load at 450 V DC. Each of the 12 primary and secondary loops has its own bellows-type accumulator that is designed to regulate the lithium pressures in the loops. A dynamic simulation model of this thermoelectric SRPS (DynMo-TE) has been developed and used to investigate the transient operation of the system during a startup from a fully-thawed condition at 600 K, to nominal steady-state operation at which the lithium coolant exits the reactor at only 1179 K. Also investigated is the load-following characteristic of the SCoRe-TE SRPS, following a change in the electrical load demand. 相似文献
45.
A novel approach is presented to calculate the sensitivities of the scattering parameters of microwave filters obtained with the full‐wave mode‐matching (MM) technique. Using only the MM simulation of the original network, the sensitivities of the scattering parameters with respect to all designable parameters are obtained. The adjoint network method (ANM) is applied to the generalized scattering matrices of the different filter components. This guarantees good accuracy of the calculated sensitivities. The implementation details are discussed for N‐resonator ridge waveguide filters. Excellent agreement is obtained between the sensitivities calculated using ANM and those obtained using the expensive central differences. © 2006 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2006. 相似文献
46.
Bing Q. Han Farghalli A. Mohamed Enrique J. Lavernia 《Metallurgical and Materials Transactions A》2003,34(1):71-83
In the present study, the mechanical properties of Fe processed via severe plastic deformation (equal-channel angular pressing (ECAP)) at room temperature were investigated for the first time.
The grain size of annealed Fe, with an initial grain size of about 200 μm, was reduced drastically during ECAP. After eight passes, the grain size reaches 200 to 400 nm, as documented by means of
transmission electron microscopy (TEM). The value of microhardness during pressing increases 3 times over that of the starting
material after the first pass and increases slightly during subsequent pressing for higher-purity Fe. Examination of the value
of microhardness after eight passes as a function of post-ECAP annealing temperature shows a transition from recovery to recrystallization,
an observation that resembles the behavior reported for heavily deformed metals and alloys. The tensile and compression behaviors
were examined. In tension, a drop in the engineering stress-engineering strain curve beyond maximum load was observed both
in the annealed Fe and the ECAP Fe. This drop is related to the neck deformation. The fracture surface, examined by scanning
electron microscopy (SEM), shows vein patterns, which is different from the dimples found on the fracture surface of annealed
Fe. In compression, an initial strain-hardening region followed by a no-strain-hardening region was observed in the ECAP Fe.
The yield strength in tension of the ECAP Fe was observed to be higher than that in compression. The strengthening mechanisms
and softening behavior are discussed. 相似文献
47.
Yehia A. Ibrahim Magdy A. Abdelhameed Taher A. Al-Sahhaf Mohamed A. Fahim 《Petroleum Science and Technology》2003,21(5):825-837
Asphaltenes obtained by precipitation from crude Kuwaiti oils have been analyzed by proton magnetic resonance (1H-NMR), carbon-13 nuclear magnetic resonance (13C-NMR) and Infrared (IR) spectral techniques. The molecular weight and elemental analysis were also determined. These combined analytical data were used for the characterization of these Kuwaiti oils. The asphaltenes molecular weights range from approximately 4200-6500 with an H/C ratio of 0.91-1.1 with an average 45-71% aromatic carbons. The average side chain length was of 4-6 carbons. It can also be concluded that the asphaltenes under investigation contain 5-9 sets of condensed aromatic rings joined together by bridges of alkyl chains or other hetero atoms and the average number of each of these sets of condensed aromatic rings is nearly 7. There are a number of alicyclic rings and condensed alicyclic rings in asphaltene. The IR spectra showed main molecular groups including OH, NH, SH, C=O and aliphatic and aromatic C-H's. 相似文献
48.
We present a general method and a toolkit for designing, implementing and visualizing distributed algorithms. We make use of the high level encoding of distributed algorithms as graph rewriting systems. The result is a unified and simple framework for describing, implementing and visualizing a large family of distributed algorithms. 相似文献
49.
The Bou Hadjar low-temperature hydrothermal system is located in northeast Algeria. The four main thermal springs that are the subject of the study emerge ith temperatures between 32 and 60°C from allochthonous formations. The reservoir temperature has been estimated from chemical compositions by utilizing simultaneously the silica, gas and sulfate-water oxygen isotope geothermometers, fluid-mineral equilibrium calculations, and a mixing model. According to these thermometric methods, the most probable subsurface temperature is in the range 75–106°C. The mixing model suggests a temperature of 125°C for the parent water. 相似文献
50.