An investigation on hydride VPE growth and properties of semi-insulating InP:Fe

Growth of highly resistive semi-insulating InP : Fe has been achieved by the Hydride VPE technique in an ambient consisting mostly of nitrogen. After dealing with some thermodynamic considerations pertinent to InP:Fe growth, the experimental growth parameters are described. It is shown that various amounts of iron can be introduced into the InP crystal just by varying the temperature of the iron source. The crystal quality of the grown material is estimated to be good by etch pit density and x-ray diffraction analyses. Current-voltage behaviour and capacitance studies on ann ⁺-SI-n ⁺ structure are explained by invoking the theory of current injection in solids by Lampert and Mark: the experimental current densities at the threshold of each observed regime are compared with the theoretically derived current densities; in the absence of current injection, the measured capacitance is found to be the same as the geometrical capacitance.     

<Emphasis Type="Italic">μ</Emphasis>DTNSec: a security layer with lightweight certificates for Disruption-Tolerant Networks on microcontrollers

In Delay/Disruption-Tolerant Networks, man-in-the-middle attacks are easy: due to the store-carry-forward principle, an attacker can simply place itself on the route between source and destination to eavesdrop or alter bundles. This weakness is aggravated in networks, where devices are energy-constrained but the attacker is not. To protect against these attacks, we design and implement μDTNSec, a security layer for Delay/Disruption-Tolerant Networks on microcontrollers. Our design establishes a public key infrastructure with lightweight certificates as an extension to the Bundle Protocol. It has been fully implemented as an addition to μDTN on Contiki OS and uses elliptic curve cryptography and hardware-backed symmetric encryption. In this enhanced version of μDTNSec, public key identity bindings are validated by exchanging certificates using neighbor discovery. μDTNSec provides a signature mode for authenticity and a sign-then-encrypt mode for added confidentiality. Our performance evaluation shows that the choice of the curve dominates the influence of the payload size. We also provide energy measurements for all operations to show the feasibility of our security layer on energy-constrained devices. Because a high quality source of randomness is required, we evaluated the random number generators by the AT86RF231 radio, its successor AT86RF233, and one based on the noise of the A/D converter. We found that only AT86RF233 provides the required quality.     

Antenna Array Designs for OFDM WLAN Indoor Transmission

Wireless local area networks (WLAN??s) based on the 802.11 standards are ubiquitous. However, the popularity of WLAN??s has made interference between WLAN users an issue. Spatial division multiple access (SDMA) is one way to orthogonalize these users and reduce interference. The contribution of this paper is to use real antenna array prototypes to determine the best array design for implementing indoor SDMA. Two SDMA antenna array prototypes are constructed and used to collect propagation measurements in an indoor environment. The propagation data is then incorporated into an SDMA orthogonal frequency division multiplexing (OFDM) analysis. This approach is able to very accurately predict how the two array designs will influence SDMA-OFDM performance in the indoor environment where the measurements are collected. The results indicate that the compact sectorized antenna array prototype performs better than the linear array prototype for in-room communication and that the reverse is true for inter-room communication.     

Efficiency of Light Outcoupling Structures in Organic Light‐Emitting Diodes: 2D TiO2 Array as a Model System

Organic light‐emitting diodes (OLEDs) are widely used in research and are established in the industry. The building block nature of organic compounds enables a vast variety of materials. On top of that, there exist many strategies to improve the light outcoupling of OLEDs making a direct comparison of outcoupling technologies difficult. Here, a novel approach is introduced for the evaluation of light outcoupling structures. The new defined “efficiency of light outcoupling structures” (ELOS) clearly determines the effectiveness of the light outcoupling structure by weighting the experimental efficiency enhancement over the theoretical outcoupling gain. It neither depends on cavity design nor on the chosen organic material. The methodology is illustrated for red phosphorescent OLEDs comprising internal and external light outcoupling structures. Assumptions and further uses are discussed with respect to experimental and theoretical handling. In addition, the ELOS is calculated for various outcoupling techniques from literature to demonstrate the universality. Finally, most suitable reference OLEDs are discussed for application of light outcoupling structures. The presented approach enables new possibilities for studying light outcoupling structures and improves their comparability in a highly material‐driven research field.     

Solid Ink Laser Patterning for High-Resolution Information Labels with Supervised Learning Readout

Tagging, tracking, or validation of products are often facilitated by inkjet-printed optical information labels. However, this requires thorough substrate pretreatment, ink optimization, and often lacks in printing precision/resolution. Herein, a printing method based on laser-driven deposition of solid polymer ink that allows for printing on various substrates without pretreatment is demonstrated. Since the deposition process has a precision of <1 µm, it can introduce the concept of sub-positions with overlapping spots. This enables high-resolution fluorescent labels with comparable spot-to-spot distance of down to 15 µm (444,444 spots cm⁻²) and rapid machine learning-supported readout based on low-resolution fluorescence imaging. Furthermore, the defined thickness of the printed polymer ink spots can be used to fabricate multi-channel information labels. Additional information can be stored in different fluorescence channels or in a hidden topography channel of the label that is independent of the fluorescence.     

Charge transfer in thin films of donor–acceptor complexes studied by infrared spectroscopy

The degree of charge transfer in thin films of organic charge transfer (CT)-complexes, which are deposited via thermal evaporation, is examined via infrared-spectroscopy. We demonstrate a linear relationship between the shift in the excitation energy of the CN-stretching mode of CT-complexes with the acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ) and the charge transfer. The measured correlation corresponds very well with DFT calculations. For Na-TCNQ we observe a splitting in the peak of the CN-stretching mode, which can be explained by the coupling of two modes and was confirmed by the calculations. In CT-complexes with partial charge transfer the appearance of an electronic excitation is demonstrated.     

Inwards Interweaving of Polymeric Layers within Hydrogels: Assembly of Spherical Multi‐Shells with Discrete Porosity Differences

The unique inwards interweaving morphology of polyamines and polyacids within agarose hydrogels that leads to the formation of striated shells with different porosities within the spherical scaffold is reported. Microcompartments with sophisticated structures are commonly used in drug delivery, tissue engineering, and other biomedical applications. However, a method capable of producing well‐defined, multiporous shells within a single compartment is still lacking. By the alternating deposition of polyallylamine (PA) and polystyrenesulfonic acid (PSS) in 1‐butanol, at equal mass ratios, multiple levels of porosity are generated within an agarose microsphere. Each level of porosity is represented by a well‐defined, concentric shell of interweaving PA and PSS layers. The number, thickness, and porosity of the striated shells can be easily controlled by varying the number of PA/PSS bilayers and the polymer concentration, respectively. The feasibility of utilizing this morphology for the assembly of a multi‐shell porous spherical scaffold is validated by trapping different molecular weight dextrans within different regions of porosity. The unique interaction of polyacids and polyamines in hydrogels represents a facile and inexpensive approach to the development of intricate scaffold architectures.     

Mobility management approaches for SDN-enabled mobile networks

The evolving network technologies aim at meeting the envisioned communication demands of future smart cities and applications. Although software-defined networking (SDN) enables flexible network control, its applicability to mobile networks is still in its infancy. When it comes to introducing the SDN vision to mobile networks, handling of wireless events and mobility management operations stand out as major challenges. In this paper, we study the scalability issues of SDNized wireless networks, specifically those relevant to mobility management. We design and implement different mobility management approaches in SDNized wireless networks and investigate the impact of various system variables on the overall handover delays. We also study the improvements in handover delays: (i) when a proposed proactive mobility management algorithm is implemented; (ii) when the controller delegates partial control of mobility management to the forwarding entities. For the implementation of the proposed approaches on the OpenFlow network, the paper also suggests potential extensions to the OpenFlow protocol. The contributed approaches are validated on a full-scale demonstrator, with results showing that proactive outperforms reactive and that the delegated control approach performs better than proactive for smaller topology sizes. Furthermore, a proposal for LTE X2-specific control delegation is discussed as a use case.