Drying process in vapor swollen heterogels

Disk-shaped heterogels were prepared by combining methyl methacrylate (MMA) and styrene (S) with ethylene glycol dimethacrylate (EGDM) as a crosslinker agent in the presence of 2,2′-azobisisobutyronitrile (AIBN). Swelling experiments were performed under chloroform vapor and the swollen gels are then allowed to dry under room temperature. Gravimetric technique was used to study drying processes. It is observed that two different regimes are present in the drying processes of these heterogels. Fickian diffusion model was used to determine desorption coefficients for each drying step in both regimes. Desorption coefficients, D _d, of heterogels were found to be strongly correlated with the mixture composition of polymeric materials in the heterogel system for both regimes. Heterogels with high S content dry much slower than the heterogels with low S content.     

Bifunctional Catalyst Control of Alkene Isomerization

The ability to control the formation and chemistry of alkenes is of central importance to organic synthesis in both industry and academia. Progress in using catalysts with bifunctional (heteroaryl)phosphines to control positional and/or geometric selectivity in alkene isomerization and related chemistry is summarized.     

Routing table updating by using intelligent agents

In a network, one of the important problems is making an efficient routing decision. Many studies have been carried out on making a decision and several routing algorithms have been developed. In a network environment, every node has a routing table and these routing tables are used for making routing decisions. Nowadays, intelligent agents are used to make routing decisions. Intelligent agents have been inspired by social insects such as ants. One of the intelligent agent types is self a cloning ant. In this study, a self cloning ant colony approach is used. Self cloning ants are a new synthetic ant type. This ant assesses the situation and multiplies through cloning or destroying itself. It is done by making a routing decision and finding the optimal path. This study explains routing table updating by using the self cloning ant colony approach. In a real net, this approach has been used and routing tables have been created and updated for every node.     

Assessment of the effectiveness of the educational environment supported by computer aided presentations at primary school level

The objective of this study is to assess the effectiveness of the educational environment supported by computer aided presentations at primary school. The effectiveness of the environment has been evaluated in terms of students’ learning and remembering what they have learnt. In the study, we have compared experimental group and control group in terms of learning and recalling what has been learned regarding the effect which computer aided learning environment imposes. Data have been collected through the control grouped pretest–final test model. During the experiment, we have prepared an achievement test, which explains behaviors the students should acquire. According to the findings obtained, a computer aided educational environment has been observed to be more effective than that of conventional education in terms of learning. However, in terms of the permanence of what has been learned, no meaningful difference between the educational environment supported by computer aided presentations and that of conventional education has come out. According to the results of the follow-up tests performed, even though students in the test group have forgotten more of what they have learnt, it has been concluded that students in both groups have forgotten on the same level. Consequently, it has been observed that though the educational environment supported by computer aided presentations has positive contributions to learning activity, it does not have effects on the permanence of what has been learnt.     

Physical and Mechanical Properties of PP Composites based on Different Types of Lignocellulosic Fillers

The presents preparation and characterization of different types of lignocellulosic fillers (pine wood sawdust/ walnut shell flour/ black rice husk powder) reinforced polypropylene composites were presented. The effect of MAPP as coupling agent (4wt%) on the physical and mechanical properties was also investigated. Polypropylene composites were prepared at different rates of filler/matrix (wt%) by using extrusion (for melt blending) and hot compression molding process. Maximum values of tensile and flexural strength were obtained as 26.1 and 43.4 MPa, respectively, whereas the elongation at break value was 4.11% at 10% pine wood sawdust reinforced PP. Tensile and flexural modulus of composites reached the maximum values as 3855 and 3633 MPa with the composite of 30% walnut shell flour reinforced PP. Characterization of composites was carried out by using tensile test, flexural test, FT-IR, and SEM.     

Morphological changes in poly(?-caprolactone) in dense carbon dioxide

Morphological changes that take place in poly(?-caprolactone) upon exposure to carbon dioxide at high pressures have been explored as a function of pressure and temperature. SEM and DSC results point to a competition between CO₂-modulated crystallization and pressure-induced phase separation which leads to unique morphologies. At 293 K, exposure to CO₂ at pressures up to 45 MPa leads to recrystallization resulting in higher level of crystallinity and higher melting temperatures. Highest crystallinity levels along with distinct crystal morphology were observed after exposure to CO₂ at 308 K and 21 MPa. At a higher pressure at this temperature (308 K/34 MPa) polymer undergoes melting, and foaming is achieved during depressurization prior to solidification. At 323 K, the polymer is found to display unique crystal morphology with concave crystal geometry as well as porous domains. The results are discussed in terms of the crystallization and phase separation paths that are followed during exposure to CO₂ and the depressurization stages.