Investigation of the soil amplification factor in the Adapazari region

Turkey is located on the highly active Eurasian plate. A very active strike slip fault, the North Anatolian Fault Zone (NAFZ), crosses Turkey from east to west; earthquakes occurred on this fault on August 17, 1999 (Kocaeli) and November 12, 1999 (Düzce). Regional geology and subsoil conditions can significantly change the characteristics of ground motion. For this reason, determining soil amplification during an earthquake, especially for soft soils, is a very important topic for researchers. In this study, one dimensional ground response analyses were performed for selected Adapazari sites using the August 17, 1999 Kocaeli earthquake strong ground motion record with SHAKE2000 software. Soil characteristics and depth to engineering bedrock at the selected sites are different and the observed level of structural damage at these sites during the Kocaeli earthquake was also different. Calculated soil surface response spectrums at these sites were compared with the recommended design spectra of the Turkish Earthquake Code and the Eurocode 8. According to one dimensional ground response analyses, the calculated response spectra of the selected sites exceed the recommended design spectra of the Turkish Earthquake Code and the Eurocode 8. Calculations show that higher amplification ratios occur at higher periods due to soil behaviour. Results of this study indicate that local geological conditions may amplify ground motion at some periods and, due to this amplification, the calculated response spectra may exceed the recommended design spectra. Therefore, it is clear that local site conditions must be considered for earthquake-resistant engineering designs on soft alluvial soil deposits.     

Use of o-phenylene dioxydiacetic acid impregnated in Amberlite XAD resin for separation and preconcentration of uranium(VI) and thorium(IV)

The impregnation of o-phenylene dioxydiacetic acid (OPDA) into a polymeric matrix, Amberlite XAD-2000, is reported and was characterized by infrared spectroscopy. The amount of attached OPDA to the polymer resin was found to be 1.77mmolg(-1) resin. The resin was used for the sorption of U(VI) and Th(IV) from aqueous solution. This sorbent was capable of preconcentrating U(VI) and Th(IV) from weakly acidic or neutral solution. The retained metals were eluted sequentially using 0.25molL(-1) HCl for U(VI) and 1molL(-1) HCl for Th(IV) and determined spectrophotometrically using arsenazo-(III). The capacity of the resin for U(VI) and Th(IV) was found to be 0.121 and 0.113mmolg(-1), respectively. The impregnated resin exhibits a high chemical stability, reusability and fast equilibration. The method was used for the determination of U(VI) and Th(IV) in synthetic samples and rock samples.     

Electrically Activated Paper Actuators

This paper describes the design and fabrication of electrically controlled paper actuators that operate based on the dimensional changes that occur in paper when the moisture absorbed on the surface of the cellulose fibers changes. These actuators are called “Hygroexpansive Electrothermal Paper Actuators” (HEPAs). The actuators are made from paper, conducting polymer, and adhesive tape. They are lightweight, inexpensive, and can be fabricated using simple printing techniques. The central element of the HEPAs is a porous conducting path (used to provide electrothermal heating) that changes the moisture content of the paper and causes actuation. This conducting path is made by embedding a conducting polymer (PEDOT:PSS) within the paper, and thus making a paper/polymer composite that retains the porosity and hydrophilicity of paper. Different types of HEPAs (straight, precurved, and creased) achieved different types of motions (e.g., bending motion, accordion type motion). A theoretical model for their behavior is proposed. These actuators have been used for the manipulation of liquids and for the fabrication of an optical shutter.     

An advanced fabrication method of highly ordered ZnO nanowire arrays on silicon substrates by atomic layer deposition

In this work, the controlled fabrication of highly ordered ZnO nanowire (NW) arrays on silicon substrates is reported. Si NWs fabricated by a combination of phase shift lithography and etching are used as a template and are subsequently substituted by ZnO NWs with a dry-etching technique and atomic layer deposition. This fabrication technique allows the vertical ZnO NWs to be fabricated on 4 in Si wafers. Room temperature photoluminescence and micro-photoluminescence are used to observe the optical properties of the atomic layer deposition (ALD) based ZnO NWs. The sharp UV luminescence observed from the ALD ZnO NWs is unexpected for the polycrystalline nanostructure. Surprisingly, the defect related luminescence is much decreased compared to an ALD ZnO film deposited at the same time ona plane substrate. Electrical characterization was carried out by using nanomanipulators. With the p-type Si substrate and the n-type ZnO NWs the nanodevices represent p–n NW diodes.The nanowire diodes show a very high breakthrough potential which implies that the ALD ZnO NWs can be used for future electronic applications.     

EFFECT OF INITIAL MOISTURE CONTENT ON THE THIN LAYER DRYING CHARACTERISTICS OF HAZELNUTS DURING ROASTING

ABSTRACT

Effect of initial moisture content on the thin layer drying characteristics of hazelnuts during roasting was described for a temperature range of 100-160°C, using several thin layer equations. The effective diffusivity varied from 2.8×10^?7 to 21.5×10^?7m²/s over the temperature and moisture range. Temperature dependence of the diffusivity coefficient was described by Arrhenius-type relationship. The activation energy for moisture diffusion was found to be 2703 kJ/kg, 2289 kJ/kg and 2030 kJ/kg for the initial moisture content of 12.3% db, 6.14% db, and 2.41% db, respectively. Two-term equation gave better predictions than Henderson and Pabis and Thompson equations, and satisfactorily described thin layer drying characteristics of hazelnut roasting. A generalised mathematical model with the linear temperature dependence for moistured, non-treated and pre-dried hazelnuts were also developed.     

Microstructural characterization of corn starch‐based porous thermoplastic composites filled with multiwalled carbon nanotubes

Microstructural characterization of corn starch‐based porous thermoplastic (TPS) composites containing various contents (0.1, 0.5, and 1 wt %) of multiwalled carbon nanotubes (MWCNTs) was performed. Corn starch was plasticized with a proper combination of glycerol and stearic acid. TPS composites with MWCNT were prepared conducting melt extrusion followed by injection molding. TPS containing 1 wt % of MWCNTs exhibited higher tensile strength and elastic modulus values than neat TPS. Moreover, TPS electrical conductivity was determined to increase with increasing content of MWCNTs. X‐ray diffraction measurements revealed that incorporation of MWCNTs increased the degree of TPS crsystallinity to some extent. Scanning electron microscopy examination revealed that MWCNT altered TPS surface morphology and tensile failure modes, significantly. Transmission electron microscopy investigation showed that dispersion characteristics of MWCNTs within TPS were in the form of tiny clusters around micro pores of TPS, which is considered influential on electrical conductivity of the resulting composites. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Electric field effects on CNTs/vinyl ester suspensions and the resulting electrical and thermal composite properties

In this study, electrical conductivity of a vinyl ester based composite containing low content (0.05, 0.1 and 0.3 wt.%) of double and multi-walled carbon nanotubes with and without amine functional groups (DWCNTs, MWCNTs, DWCNT-NH₂ and MWCNT-NH₂) was investigated. The composite with pristine MWCNTs was found to exhibit the highest electrical conductivity. Experiments aimed to induce an aligned conductive network with application of an alternating current (AC) electric field during cure were carried out on the resin suspensions with MWCNTs. Formation of electric anisotropy within the composite was verified. Light microscopy (LM), scanning electron (SEM) and transmission electron microscopy (TEM) were conducted to visualize dispersion state and the extent of alignment of MWCNTs within the polymer cured with and without application of the electric field. To gain a better understanding of electric field induced effects, glass transition temperature (T_g) of the composites was measured via Differential Scanning Calorimetry (DSC). It was determined that at 0.05 wt.% loading rate of MWCNTs, the composites, cured with application of the AC electric field, possessed a higher T_g than the composites cured without application of the AC electric field.     

Improving the accuracy of contact-type drawbead elements in panel stamping analysis

A finite element modeling technique is proposed to improve the accuracy of contact-type drawbead elements in panel forming analyses, and a performance assessment in terms of part border and thickness predictions is presented in conjunction with panel stamping experiments of two automotive sheets. Inherent model limitations causing incorrect part geometry and thickness predictions are, firstly, evaluated considering blank deformations on a plain–strain section of a stamping die. The influence of omitted drawbead geometry and overestimated drawbead exit thickness are described analytically, and a closed form expression is obtained to correct draw-in model error. Then a sectional deformation model is used to calculate restraint force and drawbead exit thickness for a particular blank and drawbead design. The proposed technique is applied in process modeling of polygon shaped panels made of draw-quality and bake-hardenable steels. Three bead penetrations were investigated in process simulations as well as in stamping experiments. The same blankholder force was applied in all process conditions. Computed draw-in and thickness distributions were compared with on-part measurements using an experimental panel-draw die. It was determined that drawbead models based on force parameters only resulted in remarkably high thickness values at the die entry and mostly overestimated draw-in along panel border lines. An evaluation of thickness distributions computed with proposed technique showed an improved correlation with experiment results of both blank materials and confirmed the use of the drawbead exit thickness as a drawbead modeling parameter. Effects of bead penetration on panel border lines were also simulated in accord with stamping experiments.     

Catalytic efficiency of immobilized glucose isomerase in isomerization of glucose to fructose

Glucose isomerase (GI) from Streptomycesrubiginosus was immobilized covalently onto Eupergit C 250 L made by copolymerization of N,N-methylene-bis-methacrylamide, glycidyl methacrylate, allyl glycidyl ether and methacrylamide. The catalytic efficiency of immobilized GI in isomerization of glucose to fructose was found as three fold higher than that of free GI. The residual activity of immobilized GI after 18 reuses in a batch type stirred reactor was about 85% of its initial activity. The thermal stability of immobilized GI was almost same with that of the free GI at 60 °C for 18 h preincubation time. The residual activities of immobilized GI when stored at 5 °C and 25 °C for four weeks were 72% and 69% of the initial activity, respectively. However, free GI retained 88% and 78% of its initial activity at 5 °C and 25 °C upon four weeks storage, respectively. Thus, the use of Eupergit C 250 L immobilized GI instead of free GI is suggested in enzymatic isomerization of glucose to fructose.     

A numerical analysis of sheet metal formability for automotive stamping applications

A theoretical failure model is presented for the numerical prediction of the forming limit strains of automotive sheets. The model uses the Swift’s diffuse necking and Hill’s localized necking concepts in describing tearing-type sheet metal failures and a computational scheme is proposed in which the failure conditions are expressed in incremental forms. The Bauschinger effect is included properly in the deformation modeling using an additive backstress form of the nonlinear-kinematic hardening rule. The necking conditions and plasticity model are transformed into a set of algebraic equations that may be applied both for proportional and non-proportional strain-controlled loadings. An iterative approach is employed in the incremental solution of algebraic equations. The formability analyses are conducted using the proposed theoretical model and the forming limit strains of two new generation auto sheets (Trip600 1.4 mm, DP980 1.15 mm) are estimated. The numerically generated FLC are compared with the experimental data and the FLC calculated with the Keeler–Brazier equation. For both steels, the model produced conservative plain–strain intercept values, FLC₀, when compared with the predictions of Keeler–Brazier equation. Also the negative minor strain part of the experimental FLD’s is estimated with sufficient accuracy. For the positive minor strain side, however, the predictions are lower than both the experimental fit and the standard curve.