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991.
A series of 2′,7′‐diarylspiro(cyclopropane‐1,9′‐fluorene) derivatives are efficiently synthesized and characterized to determine the reason for the “green‐light” emission of these compounds. These compounds exhibit bright‐violet to blue photoluminescence (PL) (λPLmax = 353–419 nm) with excellent PL quantum efficiencies (ΦPL = 83–100 %) in solution and show high thermal stabilities (Td = 267–474 °C). The variation of the optical properties of these molecules in the solid state depends on the different stacking modes of these compounds containing different substituents, which are revealed by crystallographic analysis. CH…π hydrogen bonds instead of intermolecular π–π interactions act as the driving force between adjacent fluorenes, even though a very small dialkyl group (cyclopropane) is introduced at the C‐9 position of fluorene. The crosslike molecular stacking efficiently reduces the energy transfer between the herring‐like aggregates and therefore results in the absence of a “green‐light” emission tail. In order to determine the cause of the “green‐light” emission tails, the fluorescence spectra of the films annealed in N2 or in air are recorded. Broad green‐light emission tails were observed for the films annealed in air, which might be caused by fluorenone defects generated during processing or during the course of the photophysical analysis by reaction with residual oxygen. 相似文献
992.
Jing-Ran Lin Qi-Cong Peng Huai-Zong Shao Tai-Liang Ju 《中国电子科技》2007,5(2):175-179
A novel approach of unitarily interpolated array MVDR (UIA-MVDR) is proposed, aiming at avoiding the signal cancellation caused by broadband signal-correlated interferences. UIA-MVDR belongs to the classic approaches of spectral averaging. However, it is distinguished from the conventional interpolated array MVDR (IA-MVDR) by two points: 1) It imposes a unitary constraint on the transform matrices. 2) It only optimizes the worst-case performance of array manifold approximation. As a result, the restriction on the order of Bessel function expansion is released, so that very accurate approximation can be achieved even in the case of small or middle arrays. Compared with many related approaches, UIA-MVDR destroys the correlation more completely and then achieves better performance. Its excellent performance in both correlated and uncorrelated broadband interferences suppression is confirmed via a n umber of numerical examples. 相似文献
993.
Ping Yan Tao Shao Jue Wang Wei Gao Weiqun Yuan Ruzheng Pan Shichang Zhang Guangsheng Sun 《Dielectrics and Electrical Insulation, IEEE Transactions on》2007,14(3):634-642
Based on a Marx generator and a coaxial pulse forming line, an experimental investigation of surface flashover characteristics in vacuum is conducted by using nanosecond pulses of 10 ns rise time and 30 ns full width at half maximum (FWHM). Insulator dielectrics chosen for this investigation are Teflon, PMMA and Nylon. The tested factors include gas pressure, cone angle of conical frustum, diameter and length of cylindrical insulator, material and shape of electrode, and contact style between insulator and electrodes. The effects of these parameters on the surface flashover characteristics are described and analyzed in this paper. In addition, the character of flashover time lag in the nanosecond range, and surface flashover theory in vacuum charged by nanosecond pulses are also discussed. 相似文献
994.
Shuo Cao Jing Tang Yue Sun Kai Peng Yunan Gao Yanhui Zhao Chenjiang Qian Sibai Sun Hassan Ali Yuting Shao Shiyao Wu Feilong Song David A. Williams Weidong Sheng Kuijuan Jin Xiulai Xu 《Nano Research》2016,9(2):306-316
We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectroscopy. An extremely large positive diamagnetic coefficient is observed when an electron in the wetting layer combines with a hole in the quantum dot; the coefficient is nearly one order of magnitude larger than that of the exciton states confined in the quantum dots. Recombination of electrons with holes in a quantum dot of the coupled system leads to an unusual negative diamagnetic effect, which is five times stronger than that in a pure quantum dot system. This effect can be attributed to the expansion of the wavefunction of remaining electrons in the wetting layer or the spread of electrons in the excited states of the quantum dot to the wetting layer after recombination. In this case, the wavefunction extent of the final states in the quantum dot plane is much larger than that of the initial states because of the absence of holes in the quantum dot to attract electrons. The properties of emitted photons that depend on the large electron wavefunction extents in the wetting layer indicate that the coupling occurs between systems of different dimensionality, which is also verified from the results obtained by applying a magnetic field in different configurations. This study paves a new way to observe hybrid states with zero- and two-dimensional structures, which could be useful for investigating the Kondo physics and implementing spin-based solid-state quantum information processing. 相似文献
995.
Rapid Light‐Triggered Drug Release in Liposomes Containing Small Amounts of Unsaturated and Porphyrin–Phospholipids 下载免费PDF全文
Dandan Luo Nasi Li Kevin A. Carter Cuiyan Lin Jumin Geng Shuai Shao Wei‐Chiao Huang Yueling Qin G. Ekin Atilla‐Gokcumen Jonathan F. Lovell 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(22):3039-3047
Prompt membrane permeabilization is a requisite for liposomes designed for local stimuli‐induced intravascular release of therapeutic payloads. Incorporation of a small amount (i.e., 5 molar percent) of an unsaturated phospholipid, such as dioleoylphosphatidylcholine (DOPC), accelerates near infrared (NIR) light‐triggered doxorubicin release in porphyrin–phospholipid (PoP) liposomes by an order of magnitude. In physiological conditions in vitro, the loaded drug can be released in a minute under NIR irradiation, while liposomes maintain serum stability otherwise. This enables rapid laser‐induced drug release using remarkably low amounts of PoP (i.e., 0.3 molar percent). Light‐triggered drug release occurs concomitantly with DOPC and cholesterol oxidation, as detected by mass spectrometry. In the presence of an oxygen scavenger or an antioxidant, light‐triggered drug release is inhibited, suggesting that the mechanism is related to singlet oxygen mediated oxidization of unsaturated lipids. Despite the irreversible modification of lipid composition, DOPC‐containing PoP liposome permeabilization is transient. Human pancreatic xenograft growth in mice is significantly delayed with a single chemophototherapy treatment following intravenous administration of 6 mg kg?1 doxorubicin, loaded in liposomes containing small amounts of DOPC and PoP. 相似文献
996.
997.
Plasmonic Nanoparticles: Scalable Fabrication of Multiplexed Plasmonic Nanoparticle Structures Based on AFM Lithography (Small 42/2016) 下载免费PDF全文
998.
采用单辊快淬法制备了Fe_(75)Si_9B_(13)非晶薄带。磁阻抗测试显示,淬态非晶FeSiB合金薄带具有显著的巨磁阻抗效应(GMI),在7 MHz频率下,纵横向最大阻抗比分别达到30%和29%。磁畴结构观察表明,薄带样品磁畴结构为具有一定的横向取向的180°条形畴,易轴与样品横向夹角约为75°。磁电阻变化与样品各向异性变化没有直接关系,相比磁阻抗,磁感抗更确切地反映了磁矩转动磁化行为和样品各向异性场的大小,易轴具有一定的横向取向以及薄带各向异性在厚度方向的空间分布是影响其GMI变化特性的原因。分析了磁电阻、磁感抗对样品巨磁阻抗效应的影响,发现,低频下,磁电阻对磁阻抗变化起主要作用,随着趋肤效应增强,样品磁感抗逐渐成为影响磁阻抗变化行为的主要方面。 相似文献
999.
Grigorios Loukides Aris Gkoulalas-Divanis Jianhua Shao 《Knowledge and Information Systems》2013,36(1):153-210
Transaction data are increasingly used in applications, such as marketing research and biomedical studies. Publishing these data, however, may risk privacy breaches, as they often contain personal information about individuals. Approaches to anonymizing transaction data have been proposed recently, but they may produce excessively distorted and inadequately protected solutions. This is because these approaches do not consider privacy requirements that are common in real-world applications in a realistic and flexible manner, and attempt to safeguard the data only against either identity disclosure or sensitive information inference. In this paper, we propose a new approach that overcomes these limitations. We introduce a rule-based privacy model that allows data publishers to express fine-grained protection requirements for both identity and sensitive information disclosure. Based on this model, we also develop two anonymization algorithms. Our first algorithm works in a top-down fashion, employing an efficient strategy to recursively generalize data with low information loss. Our second algorithm uses sampling and a combination of top-down and bottom-up generalization heuristics, which greatly improves scalability while maintaining low information loss. Extensive experiments show that our algorithms significantly outperform the state-of-the-art in terms of retaining data utility, while achieving good protection and scalability. 相似文献
1000.
An ε-twin support vector machine for regression 总被引:1,自引:1,他引:0
Yuan-Hai Shao Chun-Hua Zhang Zhi-Min Yang Ling Jing Nai-Yang Deng 《Neural computing & applications》2013,22(1):175-185
A special class of recurrent neural network termed Zhang neural network (ZNN) depicted in the implicit dynamics has recently been introduced for online solution of time-varying convex quadratic programming (QP) problems. Global exponential convergence of such a ZNN model is achieved theoretically in an error-free situation. This paper investigates the performance analysis of the perturbed ZNN model using a special type of activation functions (namely, power-sum activation functions) when solving the time-varying QP problems. Robustness analysis and simulation results demonstrate the superior characteristics of using power-sum activation functions in the context of large ZNN-implementation errors, compared with the case of using linear activation functions. Furthermore, the application to inverse kinematic control of a redundant robot arm also verifies the feasibility and effectiveness of the ZNN model for time-varying QP problems solving. 相似文献