Preparation of Titanium Nitride/Alumina Laminate Composites

A preparation route for TiN/Al₂O₃ laminate composites has been described. A water-based process using Al₂O₃ and TiN slurries with solids contents of 40 and 35 vol%, respectively, was used to make TiN and Al₂O₃ tapes. The removal of the binder was monitored by weight-loss measurements in a thermogravimetry unit. Bodies composed of Al₂O₃ and TiN tapes were densified at temperatures of 1400° and 1500°C using the Spark Plasma Sintering^® (SPS) technique. Densities of >98% of the theoretical densities were approached. Crack-free and almost fully densified TiN/Al₂O₃ compacts were prepared by heating the burned-out green bodies to the final sintering temperature (1500°C) at a rate of 100°C/min, and with a holding time of 5–10 min, under a pressure of 75 MPa. The microstructures of the obtained compacts were studied using scanning electron microscopy. Grain sizes in the sintered Al₂O₃ and TiN compacts were similar to those of the precursor powders. Hardness and indentation fracture toughness were measured at room temperature, and the monolithic compacts as well as the laminate composites exhibited anisotropic mechanical behavior; i.e., the cracks propagated much more easily in a direction parallel to the laminas than perpendicular to them.     

吊车断裂弹簧钢板的焊接修复

吊车上的板弹簧是一个很重要的零件,它在反复应力下工作,承受较大的冲击负荷和振动,要求其应具有较高的疲劳强度、抗拉强度等性能。由于板弹簧为碳含量较高的合金钢,焊接性差,修复断裂的板弹簧较困难。某公司的一台日本进口TL-252型25t吊车,在使用二年内先后发现五块弹簧钢板断裂,给现场施工带来了不便和一定的经济损失。经制定严格的工艺,对断裂板弹簧成功地进行了焊接修复,修复后使用效果很好。1板簧材料及可焊性分析断裂的弹簧钢板为日本钢号SUP6,相当于我国的60Si2Mn弹簧钢,其化学成份见表1。表1SUP6钢的化学成份(%)C Si Mn S P …     

Studies of microhardness and mar resistance using a scanning probe microscope

Scanning probe microscopy (SPM) is in a period of rapid development. It shows great promise for characterizing coating surfaces. This paper describes modification of an SPM so that it can be used to mar the surfaces of coatings under controlled conditions and to characterize the mars. Mar resistance of coatings is analyzed in terms of a ‘three response, two mechanism model.' The three responses (fracture, elastic, and plastic) can be measured quantitatively using the SPM. Of the three responses, only two (fracture and plastic deformation) are marring mechanisms – elastic deformations recover instantaneously. In some cases mars resulting from plastic deformation may recover slowly with time or with immersion in water; this phenomenon is attributed to viscoelastic creep. Microhardness is also measured with the modified SPM. Some thermoset coatings appear to be substantially harder near their surfaces than in the mass of material, and such materials may respond quite differently to stress applied at different levels near the surface. This finding has important implications for all coating properties that are strongly influenced by the surface. A quantity called ‘micro mar resistance' is defined. It may be useful for comparing different coatings under specified conditions of marring. However, there can be no single quantity that expresses ‘mar resistance' of a coating under all conditions.     

加压下二氧化碳在二甲基甲酰胺中的溶解度研究

本文报道了二氧化碳在二甲基甲酰胺中的溶解度,实验温度分别为15、20、25、30、35、40、45℃,实验压力为207.21—1684.02kPa.并且提出一个考虑了过量熵的、用溶度参数表示的活度系数方程.     

游戏产品有效粘合用户时间的策略研究

通过对游戏的分类、发展历程梳理以及用户的需求分析,结合游戏产生过程给出了游戏产品有效粘合用户时间的策略,最后预测了游戏的发展趋势。     

Research on the friction and wear mechanism of Poly(vinyl alcohol)/hydroxylapatite composite hydrogel

Poly(vinyl alcohol)/Hydroxylapatite (PVA/HA) composite hydrogel was prepared with poly(vinyl alcohol) and hydroxylapatite as raw materials, using the method of repeated freezing and thawing. The morphologies of PVA/HA composite hydrogel were observed by means of high-accuracy 3D profiler and scanning electron microscope (SEM). The compressive elastic modulus and the stress relaxation characteristics of PVA/HA composite hydrogel were measured using the flat-head cylinder indenter. The friction and wear tests between PVA/HA composite hydrogel and bovine knee articular cartilage were performed on the micro-tribometer. The worn morphologies of PVA/HA composite hydrogel were observed with environmental scanning electron microscope (ESEM). The results showed that PVA/HA composite hydrogel has the cross-link network microstructure which is similar to that of the natural bovine knee articular cartilages. With the increase of freezing-thawing cycles and the HA content, the degree of cross-link and the crystallization of PVA/HA composite hydrogel both increase, the elastic modulus increases evidently, the rate of stress relaxation is improved and the value of balance stress decreases. The friction coefficient decreases with the increase of the freezing-thawing cycles and the HA content. The more the freezing-thawing cycles are, the earlier the friction coefficient reaches the stable balance value. The friction deformation depth between PVA/HA composite hydrogel and bovine knee articular cartilage is inversely proportional to freezing-thawing cycles and the HA content. The main wear mechanisms of PVA/HA composite hydrogel are plastic flowing and adhesive flaking. The wear severity degree decreases with the increase of freezing-thawing cycles and the HA content. Supported by Key Program of the National Natural Science Foundation of China (Grant No. 50535050), Program for New Century Excellent Talents in University (Grant No. NCET-06-0479) and Natural Science Foundation of Jiangsu Province (Grant No. BK2005403)     

Synthesis and photoconductivity study of phthalocyanine polymers. I. PAA–CuPc(NO2)2

Cu–dinitro–diamino phthalocyanine was synthesized and converted to the diazonium salt. Polyacrylamide bonded CuPc(NO₂)₂ [PAA–CuPc(NO₂)₂] (I) was synthesized by hot polymerization of acrylamide and this diazonium salt. Polymer(I) is water soluble and contains about 7 mol % CuPc(NO₂)₂ rings, which are covalently bonded to PAA. Polymer(I) shows good photoconductivity, which is much better than that of the corresponding phthalocyanine monomers. By doping with iodine (I₂), the photosensitivity of polymer(I) is increased, which through fluorescence analysis is explained by the fact that a charge–transfer complex (CTC) of polymer(I) with I₂ is formed. The influence of interface layer (IFL) and charge–transportation material (CTM) on the photoconductivity of polymer(I) were also studied.     

层间接触状态和横向力大小对车辙贡献率的影响

车辙贡献率是反映沥青路面各结构层车辙病害程度的一个主要参数,可用于指导沥青路面的设计和施工.利用三维有限元计算软件建立三维有限元模型用于理论分析,将有限元计算结果与理论解进行对比,验证了该三维有限元模型的可靠性.采用实测的轮胎接地压力,考虑不同层间接触状态和横向力大小,结合有限元计算的数据,分析了沥青路面结构层的车辙贡献率.结果表明:在层间完全连续状态下,横向力大小的选取不能简单地选取最大垂直轮胎接地压力的一定比例,而是要根据所研究的具体情况具体分析.在对沥青路面车辙贡献率的研究中,可以忽略层间接触状态,即假定层间完全连续.     

Acquisition algorithm assisted by AGC control voltage for DSSS signals

An appropriate acquisition configuration in terms of signal quality can optimize the acquisition performance. In view of this, a new approach of acquisition assisted by the control voltage of automatic gain control(AGC) is proposed. This approach judges the signal power according to the AGC control voltage and switches the working modes correspondingly and adaptively. Non-coherent accumulation times and the detection threshold are reconfigured according to the working mode. Theoretical derivation and verification by simulation in typical situations are provided, and the algorithm is shown to be superior in terms of the mean acquisition time, especially in strong signal scenarios compared with the conventional algorithm.     

大型尿素造粒塔新型的腐蚀防护

详细阐述了尿素造粒塔的腐蚀机理，就其中的内外侧的防腐蚀形态进行了总结，并就此针对性的进行了防腐蚀材料的推荐及设计，尤其是玻璃鳞片胶泥。