全文获取类型
收费全文 | 205877篇 |
免费 | 16183篇 |
国内免费 | 7837篇 |
专业分类
电工技术 | 11260篇 |
技术理论 | 14篇 |
综合类 | 11289篇 |
化学工业 | 35884篇 |
金属工艺 | 10593篇 |
机械仪表 | 12047篇 |
建筑科学 | 16442篇 |
矿业工程 | 4979篇 |
能源动力 | 5872篇 |
轻工业 | 12768篇 |
水利工程 | 3241篇 |
石油天然气 | 11188篇 |
武器工业 | 1355篇 |
无线电 | 25557篇 |
一般工业技术 | 26750篇 |
冶金工业 | 10960篇 |
原子能技术 | 2140篇 |
自动化技术 | 27558篇 |
出版年
2024年 | 884篇 |
2023年 | 3272篇 |
2022年 | 5858篇 |
2021年 | 7910篇 |
2020年 | 5822篇 |
2019年 | 5028篇 |
2018年 | 5444篇 |
2017年 | 6229篇 |
2016年 | 5713篇 |
2015年 | 7323篇 |
2014年 | 9570篇 |
2013年 | 12307篇 |
2012年 | 12295篇 |
2011年 | 13928篇 |
2010年 | 11667篇 |
2009年 | 11516篇 |
2008年 | 10917篇 |
2007年 | 10501篇 |
2006年 | 10889篇 |
2005年 | 9664篇 |
2004年 | 6599篇 |
2003年 | 5805篇 |
2002年 | 5275篇 |
2001年 | 4752篇 |
2000年 | 4903篇 |
1999年 | 5674篇 |
1998年 | 5306篇 |
1997年 | 4374篇 |
1996年 | 3983篇 |
1995年 | 3324篇 |
1994年 | 2778篇 |
1993年 | 2197篇 |
1992年 | 1708篇 |
1991年 | 1282篇 |
1990年 | 1023篇 |
1989年 | 886篇 |
1988年 | 681篇 |
1987年 | 498篇 |
1986年 | 394篇 |
1985年 | 336篇 |
1984年 | 213篇 |
1983年 | 198篇 |
1982年 | 163篇 |
1981年 | 146篇 |
1980年 | 131篇 |
1979年 | 97篇 |
1978年 | 63篇 |
1977年 | 63篇 |
1976年 | 77篇 |
1975年 | 38篇 |
排序方式: 共有10000条查询结果,搜索用时 12 毫秒
991.
Branched polyacrylonitrile (PAN) was prepared through a self‐condensing vinyl copolymerization of acrylonitrile and 2‐(2‐bromopropionyloxy)ethyl acrylate (BPEA). The branched architecture of the product was confirmed by NMR spectra and the average degree of branching (DB ) was estimated. Through a comparison of the intrinsic viscosity of the product with that of its linear analogue, the contraction factor g′ was calculated. It was found that the viscosity of the branched PAN was obviously lower that that of linear PAN. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
992.
If a low weight percentage of crude fine fillers can improve properties of polymer materials directly without complicated chemical treatment process involved, it will be significant for many industrial applications. Our previous study indicated that a kind of Cancun natural sand could be an effective filler material for polymer composites. In this current work, the epoxy composites reinforced by this kind of natural sand particles were prepared and thermal and mechanical properties of the composites containing up to 5 wt % of the sand particles were characterized. Results showed that the highest flexural strength appears in the epoxy composite containing 1 wt % sand particles. A damage model was used to interpret the flexural properties, which showed an acceptable agreement with the experimental results. The glass transition temperature, high temperature storage modulus, and dimensional stability of the sand/epoxy composites monotonically increased with the addition of the sand particles. The sand particle/epoxy composites also displayed a noticeable enhancement in thermal conductivity. Theoretical analysis showed that in addition to conduction, other heat transport mechanisms played roles in the improved heat transmission through the composites. As a natural porous micron-scale material, Cancun sand has the potential for applications in cost-effective composites with enhanced mechanical and thermal properties. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
993.
Peichun Li Amar Zerroukhi Jianding Chen Yvan Chalamet Thomas Jeanmaire Zhean Xia 《应用聚合物科学杂志》2008,110(6):3990-3998
Chemical shrinkage was used for the in situ measurement of the progressing chemical stabilization reactions and the influence of ozone during the stabilization of polyacrylonitrile. A method for evaluating the activation energy through the sensitivity temperature is presented. The calculated results show that the activation energies were 161.57 kJ/mol in air and 181.23 kJ/mol in ozone-enriched air. Therefore, the chemical reactions were postponed during stabilization in ozone-enriched air. Ozone seemed to act in three ways: first, ozone promoted the formation of the serious skin–core structure. Second, ozone accelerated the chemical reactions and shortened the stabilization time at lower heating rates. Third, ozone postponed the chemical reactions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
994.
Degumming of hemp fiber by high temperature alkali cooking was investigated, and the effect of temperature and dosage of alkali on the constituents, structure, and thermal degradation of hemp fiber was also discussed in this work. The morphology, structure, and thermal degradation of hemp fiber after high temperature cooking were investigated through SEM, FTIR, WAXD, and TG analysis. The results indicated that the high temperature cooking process was effective for removing hemicelluloses and lignin and could also improve the thermal stability of cellulose. Crystallinity index of the treated hemp fiber was increased, which was related to the cooking temperature and NaOH dosage. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
995.
The phase structures and transition behaviors of a series of side-chain liquid crystalline (LC) polymethacrylates based on p-methoxyazobenzene (PMnAzs, n = 6, 8, 10, 12) were studied using differential scanning calorimetry, one- and two-dimensional (1D and 2D) wide-angle X-ray diffraction, and Fourier transform infrared spectroscopic experiments. The LC phase transition of PMnAz follows the sequence of smectic A (SmA) ? nematic (N) ? isotropic (I). For PM10Az and PM12Az, the transition of SmA-to-N is not complete upon heating. In the low-temperature SmA phase, the polymers adopt a fully interdigitated side-chain packing with the smectic layer period almost identical to the side-chain length. For all the four samples, the first-order diffraction of the SmA structure only renders when the temperature approaches the transition of SmA ? N, with the intensity much lower than that of the second-order diffraction. The absence of the first-order diffraction at low temperatures is ascribed to the possible matching of the electron densities between the center portion of the side-chain sublayer and the main-chain sublayer of the SmA structure. Since only the mesogens from the same main-chain sublayer can stack parallel together, the distribution of the azobenzene domains may cause some sort of density undulation within the smectic layer. Among the samples, PM6Az presents the strongest undulation with some additional orders. We also examined the annealing effect on the H-aggregation of PMnAzs. It is found that isothermal annealing at a temperature slightly higher than the Tg of PM8Az and PM10Az can significantly enhance the UV absorption at 326 nm, indicating a further development of H-aggregation. However, for PM6Az and PM12Az, the UV–vis spectrum of the annealed sample is nearly identical to that without annealing. 相似文献
996.
Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
997.
Han‐Lang Wu Chen‐Chi M. Ma Chun‐Chieh Lin Yie‐Chan Chiu Chih‐Yuan Chen Chin‐Lung Chiang 《应用聚合物科学杂志》2008,107(5):3236-3243
Poly(arylene ether benzonitrile) (PAEBN) was synthesized with 2,6‐dichlorobenzonitrile and biphenol. PAEBNs with various molecular weights (MWs), 1,640,000 and 185,000 g/mol, were synthesized by control of the stoichiometry of the monomers and were blended with sulfonated poly(ether ether ketone) (SPEEK). The effects of MW on the water uptake, swelling, methanol permeability, and proton conductivity of the SPEEK/PAEBN blend membranes were investigated. The molecular mobility of the SPEEK/PAEBN blends was also examined in this study. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
998.
Effect of Li+ ions on structure,properties, and actuation of cellulose electro‐active paper actuator
We have reported an electro‐active paper actuator from regenerated cellulose. After dissolving cellulose fibers with a solution of lithium chloride in N,N‐dimethylacetamide, cellulose was regenerated by combining distillation of cellulose solution along with washing with the mixture of deionized water, isopropyl alcohol, and running water. However, the effect of Li+ ions on structure, properties, and the actuation behavior of the actuator was not studied. This article describes the changes in these parameters when the Li+ ions are removed by subjecting it to different running water exposure time. The structure and properties of cellulose electro‐active paper and its actuation behavior were studied. As Li+ ions content reduced from 4354.17 to 10.26 ppm by increasing the exposure time of running water, crystallinity, Young's modulus, and bending displacement decreased. Details about the investigation have been explained. This elimination of ions is important to increase the piezoelectric effect in EAPap by decreasing the ion migration effect. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
999.
1000.