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41.
废旧电池中有价金属回收利用探讨   总被引:1,自引:0,他引:1  
王犇 《无机盐工业》2007,39(11):50-52
随着中国经济的稳步发展和投资环境的不断优化,中国已成为电池的制造和消费大国,每年产生数亿只废旧电池。对废旧电池的回收利用已成为全社会关注的问题。介绍了废旧电池中有价金属的回收利用方法,着重介绍了锂离子二次电池正极材料有价金属的回收利用方法。指出,中国商品化的正极材料只有钴酸锂(LiCoO2),这种正极材料钴含量高,且钴价值高,并且回收工艺可行,因此,从钴酸锂正极材料中回收钴等有价金属,对发展中国的循环经济具有重要意义。同时介绍了锂离子二次电池正极材料的研究现状。  相似文献   
42.
采用改进的Mergen A.方案,用氧化锌、三氧化二铋、三氧化二锑为原料,氨水、草酸铵和碳酸铵分别为沉淀剂,盐酸为溶剂,用共沉淀法成功制备了亚微米级颗粒、高活性的铋基Bi1.5ZnSb1.5O7(BZS)焦绿石型介电陶瓷粉体。探讨了用不同的沉淀剂、在不同的烧结温度所得产物的形态。结果表明氨水做沉淀剂在570℃就可生成纯的焦绿石结构。与Mergen A方法相比成本大大降低,可以使瓷片组织的均匀性提高,电性能得到改善,电压梯度下降。  相似文献   
43.
A nonlinear control scheme is proposed for the trajectory tracking problem of a small scale helicopter’s longitudinal dynamics. The control scheme is based on a control design procedure that constructs static feedback regulators for nonlinear systems which are linearizable by dynamic feedback. Besides, the flatness characteristics of the helicopter’s longitudinal dynamics are used to design the desired trajectory. The controller proposed is based on the longitudinal model of the small scale helicopter including the main rotor and stabilizer bar dynamics. Sufficient conditions are given to guarantee asymptotic convergence to zero of the tracking error and to keep the main rotor thrust always negative assuming that all the helicopter’s parameters are known and that all helicopter’s states are measured. Numerical simulations are given to show the performance of the controller in the presence of the main rotor and stabilizer bar dynamics.  相似文献   
44.
李萍  陆明亮  华贲 《现代化工》2005,25(6):58-61
针对过程企业,基于并行工程的思想,提出了过程企业运作管理的新思想--并行企业运作,并采用IDEFO(ICAM Defintion)功能建模方法,建立了集成并行的业务过程模型,在每个业务过程内部采用"监控-决策-执行"的实时信息反馈系统,以实现企业各业务过程之间的信息交互与资源共享.  相似文献   
45.
Dehydrofreezing process involves water partial removal before freezing. This treatment has been proposed in order to reduce the negative impacts of conventional or even accelerated freezing, especially on the textural quality of high water content fruits and vegetables. Indeed, in such cases, freezing and thawing processes result in severe damage of the integrity of product’s cell structure due to the formation of ice crystals. For this purpose, quince fruits (7?g H2O/g db) were subjected to convective air drying of 40?°C and 3m/s to reach different water content levels of 2, 1, and 0.3?g H2O/g db. Freezing profiles obtained at various freezing rates (V1, V2, and V3) for different water contents allowed the main freezing characteristics such as the Initial Freezing Temperature (IFT), the Practical Freezing time (PFt), and the Specific Freezing time (SFt) to be assessed. The impact of freezing rate was important on PFt and SFt, and more pronounced for high water contents (W between 7 and 2?g H2O/g db (dry basis)). Furthermore, IFT decreased sharply when initial sample water content decreased. Indeed, it started at ?0.8?°C for W?=?7g H2O/g db, while it reached a value of ?8.2?°C for samples of W?=?1g H2O/g db. Since convective air drying normally triggers shrinkage which causes a detrimental deformation of fruit structures, instant controlled pressure drop (DIC) treatment was used to improve the texture and enhance the whole dehydrofreezing performance and the final frozen-thawed product quality. Moreover, DIC implied a slight increase of PFt compared to untreated ones. On the other hand, quality attributes were estimated through the assessment of thawed water exudate (TWE g H2O/100?g db), color and texture (maximum puncture force as index of firmness): freezing rate and water content had great impacts on TWE. Hence, the lower the water content, the weaker the TWE. Furthermore, the TWE of the pre-dried quince (0.3?g H2O/g db) had higher value for DIC-textured samples than for the un-treated ones. Indeed, DIC-texturing leads to a well-controlled structure expansion of the cell wall. These textural changes resulted in more lixiviation of residual water. Consequently, water becomes more available, hence more releasable after thawing. Finally, the partial removal of water by air drying before freezing remarkably reduced the negative impact of freezing/thawing processes on final quince color. Decisively, the firmness of quince fruit increased with the decrease of water content level.

Abbreviations: DMC: Dry Matter Concentration (%); DIC: Instant controlled pressure drop; W: Water content dry basis (g H2O/g db); IFT: Initial Freezing Temperature (°C); PFt: Practical Freezing time (min); SFt: Specific Freezing time (min); TWE: Thawed Water Exudate (g H2O/100?g db); L, a, and b: Color coordinates; (L): The degrees of lightness; (a) and (–a): The redness (a) or greenness (?a), respectively; (b) and (?b): The yellowness (b) or blueness (?b), respectively; ΔE*ab: Total color difference; L0, a0, and b0: Color coordinates of fresh or dried quince samples; SD: Standard Deviation; ANOVA: Analysis of variances; LSD: Least Significant Differences; cp: Specific Heat of the product depending on composition (dry material and water content)(KJ/kg K); cpd: Specific Heat of the dry material (KJ/kg K); cpW: Specific Heat of water (KJ/kg K); V1: Freezing rate without insulation; V2: Freezing rate with a food stretch film insulation with thickness e2?=?3?mm and thermal conductivity λ2?=?0.17 W/m K; V3: Freezing rate with a versatile flexible insulation (Armacell) with thickness e3?=?13mm and weak thermal conductivity λ3?=?0.036 W/m K; vd: Volume of dry material of quince sample (mm3); vH2O: Volume of quince sample water (mm3); vt: Total volume of quince sample (mm3); e0: Quince sample thickness (mm); e2: Insulation thickness in the case V2; = 3?mm; ; e3: Insulation thickness in the case V3; = 13?mm; ; λ0: Quince sample conductivity (W/m K); λ2: Insulation conductivity in the case V2;?=?0.17 W/m K; ; λ3: Insulation conductivity in the case V3;?=?0.036 W/m K; λd: Conductivity of quince sample dry material (W/m K); λH2O: Conductivity of water (W/m K); λequiv: Equivalent conductivity of quince sample versus water content (W/m K); mi and mf: Weights of the frozen and thawed samples, respectively  相似文献   

46.
聚乙二醇-400催化合成橙花醚的研究   总被引:3,自引:0,他引:3  
研究了利用多种相转移催化剂在不同条件下合成橙花醚。结果表明:采用聚乙二醇 400(PEG 400)为催化剂,当β 萘酚:溴乙烷:催化剂=1:12:007(摩尔比)、温度为76℃、反应7h时,产率可高达981%。  相似文献   
47.
The positive temperature coefficient of resistivity (PTCR) behavior of semiconductive BaTiO3 is well explained by the Heywang model, which predicts the resistivity behavior above the Curie point based on the acceptor state density at the grain boundaries, the charge carrier density, and the energy gap, E s, between the conduction band and the acceptor levels. However, the relationship between these parameters and the production parameters (sintering time, composition, and cooling rate) is not well understood. Recently, the present authors have found that E s can be increased by thorough oxidation. This increase is attributed to a change in the oxidation state of the acceptor. Based on this finding and results from the literature, a phenomenological PTCR model and an accompanying PTCR chart for acceptor–donor-codoped BaTiO3 are proposed to clarify this relationship. The PTCR chart clarifies that acceptor dopant concentrations, oxidation time, and oxygen partial pressure during oxidation or cooling can be optimized simultaneously to obtain optical PTCR properties.  相似文献   
48.
49.
八碳烯分离工艺的研究   总被引:1,自引:2,他引:1  
从能量综合集成的角度提出了八碳烯精馏分离工艺 ,对所提流程进行了优化模拟计算及分析 ,为八碳烯分离工艺的施工设计提供了充分的依据。投产情况表明 ,该研究改变了八碳烯的生产现状 ,使得八碳烯生产的经济效益显著提高  相似文献   
50.
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