Versatile cold atom target apparatus

We report on a compact and transportable apparatus that consists of a cold atomic target at the center of a high resolution recoil ion momentum spectrometer. Cold rubidium atoms serve as a target which can be operated in three different modes: in continuous mode, consisting of a cold atom beam generated by a two-dimensional magneto-optical trap, in normal mode in which the atoms from the beam are trapped in a three-dimensional magneto-optical trap (3D MOT), and in high density mode in which the 3D MOT is operated in dark spontaneous optical trap configuration. The targets are characterized using photoionization.     

Instrumental Texture Analysis Parameters as Winegrapes Varietal Markers and Ripeness Predictors

The texture parameters of three red grape varieties (Mencía, Brancellao, and Merenzao) cultivated in Galician vineyards (North-West Spain) were determined. Different ripening stages (A: 176 ± 8 g/l reducing sugars; B: 193 ± 8 g/l reducing sugars; C: 210 ± 8 g/l reducing sugars; D: 227 ± 8 g/l reducing sugars) were also considered. Principal component analysis was performed for a better understanding of the differences found among grapes according to variety and ripening stage based on the skin and berry texture parameters. The parameters differentiating varieties were the skin break force and energy measured on the lateral side, whereas ripening stages can be classified on the basis of berry cohesiveness. The hardest berry skin was associated with the Merenzao variety with skin break force values comprised between 0.752–0.811 N and skin break energy between 0.715–0.790 mJ for A and B ripening stages, respectively. Instead, Brancellao variety presented the softest skin with skin break force values ranging from 0.521 to 0.562 N and skin break energy from 0.407 to 0.475 mJ for A and B ripening stages, respectively. Ripeness grade increased with the berry cohesiveness for all the varieties studied.     

Optimizing Single‐Walled‐Carbon‐Nanotube‐Based Saturable Absorbers for Ultrafast Lasers

The application of single‐walled carbon nanotubes (SWCNTs) as saturable absorbers (SA) in a Nd:glass femtosecond laser is verified as a promising alternative to traditional semiconductor saturable‐absorber mirrors (SESAMs). The shortest laser pulses achieved with a SWCNT‐SA fabricated by the slow‐evaporation method are reported herein. Nearly Fourier‐limited 288 fs pulses are obtained with negative‐dispersion soliton mode‐locking. The importance of the properties of the starting material, such as the degree of purity and the chirality, and the successive slow‐evaporation deposition method is proven by using a multitechnique approach based on X‐ray diffractometry, scanning electron microscopy, and μ‐Raman spectroscopy. The high degree of nanotube alignment on the glass substrate and also the slight metallic character due to electron transfer between the glass matrix and the nanotubes themselves are identified as the main features responsible for the good laser response.     

Phantom model of physiologic intracranial pressure and cerebrospinal fluid dynamics

We describe herein a novel life-size phantom model of the intracranial cavity and its validation. The cerebrospinal fluid (CSF) domains including ventricular, cysternal, and subarachnoid spaces were derived via magnetic resonance imaging. Brain mechanical properties and cranio-spinal compliance were set based on published data. Both bulk and pulsatile physiologic CSF flow were modeled. Model validation was carried out by comparisons of flow and pressure measurements in the phantom with published in vivo data of healthy subjects. Physiologic intracranial pressure with 10 mmHg mean and 0.4 mmHg peak pulse amplitude was recorded in the ventricles. Peak CSF flow rates of 0.2 and 2 ml/s were measured in the cerebral aqueduct and subarachnoid space, respectively. The phantom constitutes a first-of-its-kind approach to modeling physiologic intracranial dynamics in vitro. Herein, we describe the phantom design and manufacturing, definition and implementation of its operating parameters, as well as the validation of the modeled dynamics.     

Long-term changes in CO(2) emissions in Austria and Czechoslovakia-Identifying the drivers of environmental pressures

This study presents fossil-fuel related CO(2) emissions in Austria and Czechoslovakia (current Czech Republic and Slovakia) for 1830-2000. The drivers of CO(2) emissions are discussed by investigating the variables of the standard Kaya identity for 1920-2000 and conducting a comparative Index Decomposition Analysis. Proxy data on industrial production and household consumption are analysed to understand the role of the economic structure. CO(2) emissions increased in both countries in the long run. Czechoslovakia was a stronger emitter of CO(2) throughout the time period, but per-capita emissions significantly differed only after World War I, when Czechoslovakia and Austria became independent. The difference in CO(2) emissions increased until the mid-1980s (the period of communism in Czechoslovakia), explained by the energy intensity and the composition effects, and higher industrial production in Czechoslovakia. Counterbalancing factors were the income effect and household consumption. After the Velvet revolution in 1990, Czechoslovak CO(2) emissions decreased, and the energy composition effect (and industrial production) lost importance. Despite their different political and economic development, Austria and Czechoslovakia reached similar levels of per-capita CO(2) emissions in the late 20th century. Neither Austrian "eco-efficiency" nor Czechoslovak restructuring have been effective in reducing CO(2) emissions to a sustainable level.     

Solar energy demand (SED) of commodity life cycles

The solar energy demand (SED) of the extraction of 232 atmospheric, biotic, fossil, land, metal, mineral, nuclear, and water resources was quantified and compared with other energy- and exergy-based indicators. SED represents the direct and indirect solar energy required by a product or service during its life cycle. SED scores were calculated for 3865 processes, as implemented in the Ecoinvent database, version 2.1. The results showed that nonrenewable resources, and in particular minerals, formed the dominant contribution to SED. This large share is due to the indirect solar energy required to produce these resource inputs. Compared with other energy- and exergy-based indicators, SED assigns higher impact factors to minerals and metals and smaller impact factors to fossil energetic resources, land use, and nuclear energy. The highest differences were observed for biobased and renewable energy generation processes, whose relative contribution of renewable resources such as water, biomass, and land occupation was much lower in SED than in energy- and exergy-based indicators.     

High-temperature (>500°c) wall thickness monitoring using dry-coupled ultrasonic waveguide transducers

Conventional ultrasonic transducers cannot withstand high temperatures for two main reasons: the piezoelectric elements within them depolarize, and differential thermal expansion of the different materials within a transducer causes them to fail. In this paper, the design of a high-temperature ultrasonic thickness gauge that bypasses these problems is described. The system uses a waveguide to isolate the vulnerable transducer and piezoelectric elements from the high-temperature measurement zone. Use of thin and long waveguides of rectangular cross section allows large temperature gradients to be sustained over short distances without the need for additional cooling equipment. The main problems that had to be addressed were the transmission and reception of ultrasonic waves into and from the testpiece that the waveguides are coupled to, and optimization of the wave propagation along the waveguide itself. It was found that anti-plane shear loading performs best at transmitting and receiving from the surface of a component that is to be inspected. Therefore, a nondispersive guided wave mode in large-aspect-ratio rectangular strips was employed to transmit the anti-plane shear loading from the transducer to the measurement zone. Different joining methods to attach the waveguides to the component were investigated and experiments showed that clamping the waveguides to the component surface gave the best results. The thickness of different plate samples was consistently measured to within less than 0.1 mm. Performance at high temperatures was tested in a furnace at 730°C for 4 weeks without signal degradation. Thicknesses in the range of 3 to 25 mm could be monitored using Hanning windowed tonebursts with 2 MHz center frequency.     

Integration of organic semiconductor lasers and single-mode passive waveguides into a PMMA substrate

Efficiently combining active and passive elements in integrated optics is a key ingredient for their successful employment. Here, we present the fabrication of an optimized PMMA substrate structure for improved coupling of laser light generated by organic semiconductor distributed feedback lasers into single-mode deep ultraviolet induced waveguides. For production, electron beam lithography on an oxidized silicon wafer and subsequent reactive ion etching is used to form the feedback grating of the laser. Afterwards, an aligned second electron beam lithography step on top of the grating allows the fabrication of a topographical step of 1.67 μm on the edges of the grating area. Metal is evaporated on this resulting master structure serving as a plating base for electroforming of a Ni tool. The tool is then used for hot embossing of the structure into PMMA bulk material. On a length of 500 μm the imprinted grating lines, having a period of 200 nm, are 100 nm wide and 60 nm high. Aligned deep ultraviolet exposure to induce a passive single- or multi-mode waveguide and co-evaporation of the active material Alq₃:DCM finish the coupling region. This structure optimizes the coupling of laser light generated in the laser structure into the passive waveguide. In combination with microfluidic channels, the laser light can be considered for sensing applications on a PMMA lab-on-chip system.     

Electronic and Optical Properties of MgxZn1?xO and BexZn1?xO Quantum Wells

As a preparatory step toward establishing reliable numerical design tools for ZnO-based optoelectronic devices, we have reassessed the available information on material parameters relevant for the simulation of light-emitting diodes (LEDs) with active regions including ZnO, MgZnO, and BeZnO layers. The impact of different approximations for the electronic structure and the interface polarization charge on the optical properties of bulk ZnO and ZnO/MgZnO quantum wells has been evaluated, and a consistent set of parameters has been used not only for systematic comparison of ZnO/MgZnO and ZnO/BeZnO single quantum well structures but also for the first simulation of a realistic ZnO/BeZnO multiple quantum well LED.     

Pervaporation separation of methanol/methyl tert‐butyl ether with poly(lactic acid) membranes

Poly(lactic acid), as a natural source polymer, was used to prepare pervaporation dense membranes. The performance of these membranes for the separation of the methanol (MeOH)/methyl tert‐butyl ether (MTBE) mixtures was investigated. The effects of different operating conditions, including the feed concentration of MeOH, temperature, and flow rate, were examined. Several characterization tests were performed as well. The swelling results, scanning electron microscopy images, contact angles, and mechanical strength measurements are presented. These membranes were found to be selective to MeOH, particularly for traces of MeOH in MTBE with a separation factor of more than 30. There was a small decrease in the separation factor when the feed temperature was increased; meanwhile, the total flux increased to some extent. This could be explained with respect to the thermal motions of the polymer chains and the permeating molecules. With an increase in the feed flow rate, both the selectivity and total flux increased because the concentration and temperature polarizations decreased. At higher flow rates, the feed components were homogeneously distributed over the membrane surface, whereas there may have been a concentration or temperature gradient at lower flow rates. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010