In situ emulsion polymerization and characterization of PVAc nanocomposites including colloidal silica nanoparticles for wood specimens bonding

Polyvinyl acetate (PVAc) nanocomposites for wood adhesives containing different amounts of colloidal silica nanoparticles (CSNs) were synthesized via in situ one-step emulsion polymerization. The adhesion strength of wood specimens bonded by PVAc nanocomposites was investigated by the tensile test. Thermal properties of PVAc nanocomposites were also characterized by differential scanning calorimetry and thermogravimetric analysis. Rheological and morphological properties of the PVAc nanocomposites were investigated using rheometric mechanical spectrometry and field emission scanning electron microscopy (FESEM), respectively. The obtaining results showed that the shear strength of PVAc nanocomposite including 1 wt. % CSNs has the highest shear and tensile strength about 4.7 and 3.2 MPa, respectively. A small increment of T_g (~3 °C) and considerable increment of the ash content proved the enhancement of PVAc thermal characterization in the presence of CSNs. FESEM results showed uniform dispersion of nanoparticles throughout the PVAc matrix due to using the in situ emulsion polymerization process. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48570.     

Synthesis of MoSi2-TiC nanocomposite powder via mechanical alloying and subsequent annealing

MoSi₂-30 wt.% TiC nanocomposite powder was successfully synthesized by ball milling and following heat treatment. Effect of milling time and annealing temperature were investigated. The products synthesis and reactions progress were characterized by XRD. Morphology and microstructure of milled powders were monitored by SEM and TEM, respectively. Results showed that the synthesis of this composite begins after 10 h of milling and progresses gradually up to 30 h of milling. MoSi₂-TiC composite was completely synthesized after annealing of 30 h milled powder at 900 °C. On the basis of Reitveld refinement method, the mean grain size and microstrain of 13.2 nm and 0.44% were obtained, respectively for 30 h milled powder that is in consistent with TEM image. In the spite of grain growth and strain release, this nanocomposite powder maintained its nanostructure after annealing.     

Modelling carbon dioxide solubility in ionic liquids

Solubility information for CO₂ in different ionic liquids, ILs, in part can potentially be used to select a specific IL for the separation of CO₂ from hydrocarbon fluids. Unfortunately, not all CO₂–IL systems have been experimentally described at similar temperatures and pressures; therefore, a direct comparison of performance by process simulation is not always possible. In the extreme cases, the design of a CO₂ separation process may require predicting the CO₂–IL equilibria for which there are no available solubility data. To address the need for this information, a semi‐empirical correlation was developed to estimate the dissolution of CO₂ in CO₂–IL solvent systems. The theoretical COSMO–RS calculation method was used to calculate the chemical potential of CO₂ in a wide variety of ILs and the Soave–Redlich–Kwong equation was used to calculate the fugacity coefficient of the CO₂ vapour phase. The model was correlated with available literature data, yielding an average error of AAR = 23% and small bias. © 2012 Canadian Society for Chemical Engineering     

Experimental and numerical investigations of low velocity impact behavior of high-performance fiber-reinforced cement based composite

Fiber-reinforced concrete (FRC) has been used in structural applications in order to enhance the structural performance under dynamic loading and reduce cracking and spalling phenomena by increasing toughness, ductility, and tensile strength of the concrete. High-performance fiber-reinforced cement based composite (HPFRC) is a high-strength FRC with enhanced high-performance characteristics. Recent studies have shown that HPFRC has higher impact resistance than other types of concrete. Therefore, it has been widely considered as a promising material for the construction of important and strategic structures. HPFRC panels are tested by drop projectiles up to an impact at which failure occurs. Mechanical properties of HPFRC are obtained to define material parameters in the MAT_SOIL_CONCRETE model in LS-DYNA, which is used to simulate the behavior of HPFRC panel under impact loading and perform parametric studies. Predicted crack and failure patterns on both sides of the HPFRC panel based on finite element simulation are in good agreement with their corresponding experimental results.     

Incorporating Nano-silica as a Binder to Improve Corrosion Resistance of High Alumina Refractory Castables

In this study, four types of castables as calcium-aluminate cement (CAC)-bonded and nano-silica (NS)-bonded castables based on tabular-alumina and bauxite aggregates were prepared to investigate the replacement of the calcium-aluminate cement by NS. All samples were allowed to dry at 110 °C then fired at 800 and 1200 °C. Bulk density and apparent porosity of samples were measured. The molten aluminum static corrosion test (cup test) results showed that NS-bonded specimens had higher resistance to corrosion compared to CAC-bonded samples (based on the measured average aluminum penetration depth into the refractory texture). However no penetration was observed in bauxite NS-bonded samples. The results were consistent with dynamic corrosion test in aluminum melt carried out at 800 °C for 100 h. The small pore size in NS-bonded castables was found to be the main cause for high corrosion resistance as micro-pores prevented the melt to penetrate into the refractory.     

Information-theoretic investigation of impact of huggable communication medium on prefrontal brain activation*

This paper examines the effect of mediated hugs that are achieved with a huggable communication medium on the brain activities of users during conversations. We measured their brain activities with functional near-infrared spectroscopy (NIRS) and evaluated them with two information theoretic measures: permutation entropy, an indicator of relaxation, and multiscale entropy, which captures complexity in brain activation at multiple time scales. We first verify the influence of lip movements on brain activities during conversation and then compare brain activities during tele-conversation through a huggable communication medium with a mobile phone. Our analysis of NIRS signals shows that mediated hugs decrease permutation entropy and increase multiscale entropy. These results suggest that touch interaction through a mediated hug induces a relaxed state in our brain but increases complex patterns of brain activation.     

On Confinement of the Initial Location of an Intruder in a Multi-robot Pursuit Game

Research in multi-robot pursuit-evasion demonstrates that three pursuers are sufficient to capture an intruder in a polygonal environment. However, this result requires the confined of the initial location of the intruder within the convex hull of the locations of the pursuers. In this study, we extend this result to alleviate this convexity through the application of a set of virtual goals that are independent of the locations of the pursuers. These virtual goals are solely calculated using the location information of the intruder such that whose locations confine the intruder within their convex hull at every execution cycle. We propose two strategies to coordinate the pursuers. They are the agents votes maximization and the profile matrix permutations strategies. We consider the time, the energy expended, and the distance traveled by the pursuers as metrics to analyze the performance of these strategies in contrast to three different allocation strategies. They are the probabilistic, the leader-follower, and the prioritization coordination strategies.     

No-wait two stage hybrid flow shop scheduling with genetic and adaptive imperialist competitive algorithms

This article studies a no-wait two-stage flexible flow shop scheduling problem with setup times aiming to minimize the total completion time. The problem is solved using an adaptive imperialist competitive algorithm (AICA) and genetic algorithm (GA). To test the performance of the proposed AICA and GA, the algorithms are compared with ant colony optimisation, known as an effective algorithm in the literature. The performance of the algorithms are evaluated by solving both small and large-scale problems. Their performance is evaluated in terms of relative percentage deviation. Finally the results of the study are discussed and conclusions and potential areas for further study are highlighted.     

A goal programming-TOPSIS approach to multiple response optimization using the concepts of non-dominated solutions and prediction intervals

Multiple response problems include three stages: data gathering, modeling and optimization. Most approaches to multiple response optimization ignore the effects of the modeling stage; the model is taken as given and subjected to multi-objective optimization. Moreover, these approaches use subjective methods for the trade off between responses to obtain one or more solutions. In contradistinction, in this paper we use the Prediction Intervals (PIs) from the model building stage to trade off between responses in an objective manner. Our new method combines concepts from the goal programming approach with normalization based on negative and positive ideal solutions as well as the use of prediction intervals for obtaining a set of non-dominated and efficient solutions. Then, the non-dominated solutions (alternatives) are ranked by the TOPSIS (Technique for Order Preference by Similarity to the Ideal Solution) approach. Since some suggested settings of the input variables may not be possible in practice or may lead to unstable operating conditions, this ranking can be extremely helpful to Decision Makers (DMs). The consideration of statistical results together with the selection of the preferred solution among the efficient solutions by Multiple Attribute Decision Making (MADM) distinguishes our approach from others in the literature. We also show, through a numerical example, how the solutions of other methods can be obtained by modifying the relevant approach according to the DM’s requirements.