Entity-relationship modeling

The entity-relationship (ER) model and its accompanying ER diagrams are widely used for database design and systems analysis. Many books and articles just provide a definition of each modeling component and give examples of the pre-built ER diagrams. As a result, beginners in data modeling have a great deal of difficulty learning how to approach a given problem, what questions to ask in order to build a model, what rules to use while constructing an ER diagram, and why one diagram is better than another. The authors present step-by-step guidelines, a set of decision rules proven to be useful in building ER diagrams, and a case study problem with a preferred answer as well as a set of incorrect diagrams for the problem. These guidelines and decision rules have been successfully used in their beginning database management system course     

预测控制算法的统一格式及其在电加热炉的应用

本文根据常用的两类预测控制算法推出一种新型预测控制算法。并将其应用于一双输入/双输出的力学持久机电加热炉的温度控制系统上,获得了满意的结果:控温精度为±1.5℃/300℃,且适用于非最小相位系统。     

纳米陶瓷的制备

纳米陶瓷材料可显著降低材料的烧结致密化程度,节约能源;并可改善陶瓷材料的性能,提高其使用可靠性。主要介绍了纳米陶瓷的制备方法,包括纳米陶瓷粉体的制备、成型和烧结。     

Electrochemical determination of estradiol using a poly(l-serine) film-modified electrode

A thin film of poly(l-serine) was prepared via electropolymerization for the determination of trace levels of estradiol. In pH 5.0 phosphate buffer, l-serine was oxidized during the cyclic potential sweeps between −0.60 and 2.0 V, forming a thin film at the electrode surface. The electrochemical behavior of estradiol was investigated. The oxidation peak potential of estradiol shifts negatively at the poly(l-serine) film-coated glassy carbon electrode (GCE) compared with that at the bare GCE. Otherwise, the oxidation peak current greatly increases at the poly(l-serine) film-modified GCE. These phenomena suggest that the poly(l-serine) film exhibits catalytic activity towards the electrochemical oxidation of estradiol. Based on this, a sensitive, rapid and simple electrochemical method was proposed for the determination of estradiol. The limit of detection is evaluated to be 2.0 × 10⁻⁸ mol L⁻¹. Finally, this method was successfully used to determine estradiol in blood serum.     

Synthesis and structural characterization of methacrylic acid/octadecyl acrylate‐graft‐poly(methylhydrosiloxane) by hydrosilylation

Methylmethacrylate (MMA) and octadecyl acrylate (OA) were grafted to poly(methylhydrosiloxane) (PMHS) by hydrosilylation, respectively, with hexachloroplatinic acid as catalyst, and the former was further hydrolyzed to prepare methacrylic acid (MAA)‐graft‐PMHS under the alkaline condition. Through orthogonal experiment, main factors affecting the graft reaction between OA and PMHS were discussed and arranged in a decreasing order according to their abilities of the effect on the hydrosilylation of OA with PMHS: catalyst dosage, reaction temperature, reaction time, material ratio, and solvent dosage. It was found that the hydrosilylation of OA with PMHS was easier to that of MMA with PMHS. Under optimal conditions, the grafting ratios of MMA with PMHS and OA with PMHS reached about 90 and 95%, respectively. FTIR and ¹H NMR spectra indicated that the hydrosilylation reactions followed the Markovnikov's rule and played a strong preference toward β‐1,2‐addition. The test of contact angle indicated that surface energy of a system was mainly dependent on the polar groups. The surface energy of OA‐graft‐PMHS (35.07 mN/m) was similar to those of PMHS (35.62 mN/m) and polyoctadecyl acrylate (36.57 mN/m), and lower than that of MAA‐graft‐PMHS (43.50 mN/m). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

离心压缩机可倾轴瓦油封漏油问题的解决

本文全面分析了DH80—16型离心压缩机可倾轴瓦油封漏油的原因,并介绍了可倾轴瓦油封漏油问题的解决及具体实施方案。     

热焊弯管用钢板工艺探讨

在统计分析、正交多项式回归和模拟试验的基础上，建立了高精度的屈强比预报模型，并运用多元函数极值原理，求导极值点及相应的工艺参数，为优化工艺制度，提高热焊弯管用钢(L360-WG系列)性能合格率提供了定量依据。     

中国古代金的分析技术

归纳总结了中国古代金分析技术的主要成果和与其相关的重要事件，对于认识金的分析技术的起源有一定的参考意义。