含氮、磷有机配体对(CdSe)_2量子点结构和电子性质的影响

使用密度泛函理论方法研究了量子点(CdSe)2与配体L(L=PH3、PH2Me、PHMe2、PMe3、NH3、NH2Me、NHMe2、NMe3)之间的相互作用及其产物的结构和性质。配体中的P或N原子与Cd原子上分别形成较强的Cd—P和Cd—N配位键,从而影响(CdSe)2的结构和电子性质。配体作用下,(CdSe)2的几何结构、电荷分布、轨道能级、吸收光谱等均发生变化,但2类配体的影响,尤其是甲基数目的影响,存在较大差异。     

家长式领导风格对组织变革影响研究

领导风格理论受到越来越多国内外学者的关注,家长式领导风格理论受到本土学者的认可和华人企业的重视,本文在基于学者对家长式领导风格理论研究的基础上,通过问卷调查的形式,实证研究了家长式领导风格对组织变革的影响,最终得出结论：家长式风格中的权威领导对文化多样性具有显著的负向预测效果;仁慈领导对风险创新性、动态整合性和文化多样性具有显著的正向预测效果。这一结论可在实践中为中国企业进行组织变革提供管理咨询的建议。     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

金属材料屈服强度的应变率效应和热激活理论

对４种金属材料进行了应变率为１０＾－４－１０＾３ｓ＾－１的拉伸试验，结果表明，屈服中度随应变率的升高分两阶段线性升高，提出了位错线热振动对加载频率的响应的热激活作用机理，依据该机理计算所得Ⅰ，Ⅱ区临界应变εｃ与实测值相符，并在此基础上将应变率对掘强度影响的机制图重新划分为：Ｉ区，富热激活区；Ⅱ区，贫热激活区。     

医用钴基合金的组织结构及耐腐蚀性能

以锻造CoNiCrMo，CoCrMo和CoCrMoC台会为研究对象，通过金相观察，XRD分析和耐腐蚀试验，研究了3组合金在不同热处理条件下的显微结构，相成分及在Hi同溶液中的耐腐蚀性能。结果表明：2组锻造合金的再结晶温度都是1000℃，且晶粒尺寸随着固溶温度升高和时效时间延长而逐渐变大。3组试样在NaCl溶液中为钴基合金典型的阳极极化曲线；在Hanks’溶液中均有一个二次钝化行为，且锻造CoNiCrMo合金的二次钝化区域较窄，而其他2组合金则较宽；在含柠檬酸三钠的溶液中过钝化电位降低，柠檬酸盐的存在降低了含金的耐腐蚀性能。热处理对合金的耐腐蚀性能影响不大。     

Formation and thermal stability of amorphous Ni-Mo-P alloys

The experimental researches on the chemical deposition of Ni-Mo-P amorphous alloys were carried out by adding Na2 MoO4 into acidic solutions. The optimum technology conditions were obtained by orthogonal design experiments. The structures and the relationship between compositions and their thermal stability were studied by energy spectrum (EC), scanning electron micrograph and X-ray diffraction spectrum. Compared with Ni-P amorphous alloys, the Ni-Mo-P amorphous alloys have high crystallization temperature and thermal stability, and the hardness reaches its peak when the annealing temperature is 500 ℃. With the increase of the heat treatment temperature, the surface morphology of the alloys changes.     

简单断面孔型计算机绘图系统简介

介绍了简单断面孔型计算机绘图系统的编制方法、使用范围 ,计算机绘图的步骤及特点     

椭圆弧数控代码的自动生成方法

提出了一种基于计算机辅助制造的数控加工代码自动生成的方法，着重阐述了该方法针对椭圆弧的数控代码自动生成过程。该方法通过分析加工图形的dxf文件，提取图形的坐标信息，再经过数据拟和，自动生成该图形的数控代码。该方法由VC＋＋6．0实现相应的功能，经实际运行表明，能满足加工精度要求。该方法摆脱了传统数控机床从加工图形到形成数控加工代码时间长且精度不高的缺点，极大她提高了工作效率。     

一种新型气硬冷芯盒树脂砂工艺试验及其在生产中的应用

原砂加入2．5％水溶性酚醛树脂，固化剂为甲酸甲脂，加入量占树脂的30％～40％。先把甲酸甲脂在气体发生器中气化，然后再与40％的压缩空气混合，吹气硬化制芯，最高抗拉强度1．2MPa，抗压强度0．32MPa，发气量12mL／g。生产浇注试验表明：砂芯表面光洁，轮廓清晰，尺寸精确，铸件缺陷少，无毒或低毒，和一般冷硬树脂砂比较，成本降低30％。     

混凝土尿素池的腐蚀及防腐蚀措施

本文对混凝土尿素池的腐蚀原因、规律及影响因素进行了阐述，提出了混凝土尿素池的腐蚀及防腐蚀措施，延长了设备的寿命，保证了尿素生产的正常运转。